Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
권호 표지
DOI QR코드

DOI QR Code

Effect of PMMA Particle Characteristics on Optical Diffusion Films

PMMA 입자특성과 광확산필름의 광특성과의 상관관계에 관한 실험적 연구

  • Wu, Jong-Pyo (Department of Chemical Engineering, Myongji University) ;
  • Hong, Jin-Ho (Department of Chemical Engineering, Myongji University) ;
  • Ahn, Chi-Hee (Department of Chemical Engineering, Myongji University) ;
  • Kim, Yoon-Jae (Department of Chemical Engineering, Myongji University)
  • 우종표 (명지대학교 공과대학 화학공학과) ;
  • 홍진호 (명지대학교 공과대학 화학공학과) ;
  • 안치희 (명지대학교 공과대학 화학공학과) ;
  • 김윤재 (명지대학교 공과대학 화학공학과)
  • Published : 2003.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

Crosslinked poly(methyl methacrylate) particles from 2.4 to $8.1{\mu}m$ in diameter were prepared by homogenized suspension polymerization. The effect of polymerization parameters such as homogenizing speed, homogenizing time and stabilizer concentration on the particle size were examined. Optical diffusion films were prepared with the crosslinked poly(methyl methacrylate) particles. The effect of film thickness, particle size, and particle size distribution on transmittance and haze of optical diffusion film was examined. Transmittance of optical diffusion film increased with increasing particle size and decreasing film thickness. Haze increased with increasing film thickness and decreasing particle size. We also found the existence of an optimum ratio for optical performance when the mixture of small particle and large particle was used.

Keywords

References

  1. B. J. Chang, I. S. Oh, J. I. Kim, and H. J. Joo, Polymer(Korea), 23, 204 (1999)
  2. S. G. Hong and M. S. Park, Korea Polym J., 8, 247 (2000)
  3. R. Arshady, Colloid Polym. Sci., 270, 717 (1992) https://doi.org/10.1007/BF00776142
  4. J. Qiu, B. Charleux, and K. Matyjaszewski, Prog. Polym. Sci., 26, 2083 (2001) https://doi.org/10.1016/S0079-6700(01)00033-8
  5. H. G. Yuan, G. Kalfas, and W. H. Ray, JMS-REV. Macromol. Chem. Phys., C31, 215 (1991)
  6. G. Polacco, M. Palla, and D. Semino, Polymer International, 48, 392 (1999) https://doi.org/10.1002/(SICI)1097-0126(199905)48:5<392::AID-PI154>3.0.CO;2-I
  7. E. V. Lima, P. E. Wood, and A. E. Hamielec, Ind. Eng. Chem. Res., 36, 939 (1997) https://doi.org/10.1021/ie960361g
  8. H. Hopff, H. Lussi, and P. Gerspacher, Makromol. Chem., 78, 37 (1964) https://doi.org/10.1002/macp.1964.020780104
  9. T. Balakrishnan and W. T. Ford, J. Appl. Polym. Sci., 27, 133 (1982) https://doi.org/10.1002/app.1982.070270115
  10. J. R. Castellanos, E. Mendizabal, and J. E. Puig, J. Appl. Polym. Sci., 49, 91 (1991) https://doi.org/10.1002/app.1991.070490010
  11. P. J. Dowding and B. Vincent, Colloids and Surfaces A: Physicochemical and Engineering Aspects., 161, 259 (2000) https://doi.org/10.1016/S0927-7757(99)00375-1
  12. C. Jegat, L. Jacob, M. Camps, and A. Bois, Polymer Bulletin, 40, 75 (1998) https://doi.org/10.1007/s002890050226
  13. C. Jegat, A. Bois, and M. Camps, J. Polym. Sci., 39, 201 (2001) https://doi.org/10.1002/1099-0488(20010115)39:2<201::AID-POLB20>3.0.CO;2-O
  14. D. Maggioris, A. Goulas, A. H. Alexopoulos, E. G. Chatzi, and C. Kiparissides, Chemical Engineering Science, 55, 4611 (2000) https://doi.org/10.1016/S0009-2509(00)00100-7
  15. N. Lazrak, N. Le Bolay, and A. Ricard, Eur. Polym. J., 34, 1167 (1998)