Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Highly Selective and Simple Zero and First Order Derivative Spectrophotometric Determination of Palladium by Using α-Benzilmonoxime in Triton X-100 Micellar Solution

  • Published : 2003.12.20
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Abstract

The reaction of ${\alpha}$-Benzilmonoxime with palladium(II) produces a green complex in triton X-100 micellar media. Palladium has been determined using zero and first derivative spectrophotometric methods. The absorbances of Pd(II)- ${\alpha}$--benzilmonoxime complex at 441.8 and 677.0 nm in 0.10 M perchloric acid solution were monitored and linear working ranges of 0.3-12.0 and 0.7-20 ${\mu}$g mL$^{-1}$ with detection limits of 0.07 and 0.10 ${\mu}$g $mL^-1$ were obtained, respectively. Also, recoveries in the range of 92.8 to 100.1% and relative standard deviations in the range of 0.4 to 7.1% were obtained. First derivative spectrophotometry has also been applied for palladium determination under the optimum condition. The linear dynamic range of 0.2-24.0 ${\mu}$g $mL^{-1}$ palladium with relative standard deviations of 0.6-6.9% and recoveries in the range of 94.9-102.5% has been obtained by first derivative spectrophotometry. The method shows high selectivity because of the high concentration of acid used, which prevents formation of complexes of ${\alpha}$--benzilmonoxime with the other cations. The palladium complex formed was stable at least one day. The method was successfully applied to the determination of palladium in some synthetic palladium alloys and palladium-charcoal powder.

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References

  1. Pyrzynska, K. Talanta 1998, 47, 841. https://doi.org/10.1016/S0039-9140(98)00158-1
  2. Caroli, S.; Alimonti, A.; Petrucci, F.; Bocca, B.; Krachler, M.; Forastiere, F.; Sacerdote, M. T.; Mallone, S. Spectrochimica Acta Part B 2001, 56, 1241. https://doi.org/10.1016/S0584-8547(01)00203-8
  3. Watanabe, K.; Hojiatie, M.; Nakamura, I.; Oaki, I. Anal. Chim. Acta 1989, 218, 111. https://doi.org/10.1016/S0003-2670(00)80288-3
  4. Gholivand, M. B.; Nozari, N. Talanta 2000, 52, 1055. https://doi.org/10.1016/S0039-9140(00)00476-8
  5. More, P. S.; Sawant, A. D. Anal. Lett. 1994, 27, 1737. https://doi.org/10.1080/00032719408007432
  6. Gordeeva, V. P.; Kochelaeva, G. A.; Tsizin, G. I.; Ivanov, V. M.; Zolotov, Y. A. J. Anal. Chem. 2002, 57, 688. https://doi.org/10.1023/A:1016817708070
  7. Igarashi, S.; Ide, N.; Takagai, Y. Anal. Chim. Acta 2000, 424, 263. https://doi.org/10.1016/S0003-2670(00)01082-5
  8. Sindhvani, S. K.; Shravah, K.; Sharma, R. K. Analyst 1987, 112, 175. https://doi.org/10.1039/an9871200175
  9. Puri, B. K.; Balani, S. Talanta 1992, 39, 815. https://doi.org/10.1016/0039-9140(92)80101-I
  10. Taher, M. A. Anal. Lett. 1998, 31, 2115. https://doi.org/10.1080/00032719808005289
  11. Rollins, O. W.; Oldham, M. M. Anal. Chem. 1971, 43, 262. https://doi.org/10.1021/ac60297a026
  12. Sakuraba, S.; Oguma, K.; Fres, J. Anal. Chem. 1994, 349, 523. https://doi.org/10.1007/BF00323986
  13. Lihong, W.; Fulong, T. Microchem. J. 1996, 53, 349. https://doi.org/10.1006/mchj.1996.0050
  14. Hanna, W. G. Talanta 1999, 50, 809. https://doi.org/10.1016/S0039-9140(99)00116-2
  15. Mori, I.; Kawakatsu, T.; Fujita, Y.; Matsuo, T. Talanta 1999, 48, 1039. https://doi.org/10.1016/S0039-9140(98)00309-9
  16. Ma, D.; Cui, F.; Xia, D.; Wang, Y. Anal. Lett. 2002, 35, 413. https://doi.org/10.1081/AL-120002539
  17. Elsayed, A. Y.; Rahem, M. A.; Omran, A. A. Anal. Sci. 1998, 14, 577. https://doi.org/10.2116/analsci.14.577
  18. Elsayed, A. Y.; Abushanab, F. A. Mikrochim. Acta 1998, 129, 225. https://doi.org/10.1007/BF01244745
  19. Gang, S.; Xingyuo, C.; Yunkun, Z.; Mancang, L.; Zhide, H. Anal. Chim. Acta 2000, 420, 123. https://doi.org/10.1016/S0003-2670(00)00977-6
  20. Anthemidis, A. N.; Themelis, D. G.; Stratis, J. A. Anal. Chim. Acta 2000, 412, 161. https://doi.org/10.1016/S0003-2670(00)00751-0
  21. Anthemidis, A. N.; Themelis, D. G.; Stratis, J. A. Talanta 2001, 54, 37. https://doi.org/10.1016/S0039-9140(00)00620-2
  22. Pourreza, N.; Rastegarzadeh, S. Anal. Chim. Acta 2001, 437, 273. https://doi.org/10.1016/S0003-2670(01)00988-6
  23. Paradkar, R. P.; Williams, R. R. Anal. Chem. 1994, 66, 2752. https://doi.org/10.1021/ac00089a024
  24. Gotlieb, I.; Bozzelli, J. W.; Gotlieb, E. Sep. Sci. Technol. 1993, 28, 793. https://doi.org/10.1080/01496399308019521
  25. Deitsch, J. J.; Smith, J. A. Environ. Sci. Technol. 1995, 29, 1069. https://doi.org/10.1021/es00004a029
  26. Safavi, A.; Abdollahi, H. Microchem. J. 2001, 69, 69. https://doi.org/10.1016/S0026-265X(01)00082-0
  27. Andres, M. P. S.; Marina, M. L.; Vera, S. Analyst 1995, 120, 225. https://doi.org/10.1039/an9952000225
  28. Vaidya, B.; Porter, M. D. Anal. Chem. 1997, 69, 2688. https://doi.org/10.1021/ac970157i
  29. Hayashi, K.; Sasaki, Y.; Tagashira, S.; Kosaka, E. Anal. Chem. 1986, 58, 1444. https://doi.org/10.1021/ac00298a038
  30. Tagashira, S.; Onoue, K.; Murakami, Y.; Sasaki, Y. Bull. Chem. Soc. Jpn. 1992, 65, 286. https://doi.org/10.1246/bcsj.65.286
  31. Ensafi, A. A.; Eskandari, H. Microchem. J. 1999, 63, 266. https://doi.org/10.1006/mchj.1999.1790
  32. Ensafi, A. A.; Abbasi, S. Microchem. J. 2000, 64, 195. https://doi.org/10.1016/S0026-265X(00)00004-7
  33. Eskandari, H.; Ghaziaskar, H. S.; Ensafi, A. A. Anal. Sci. 2001, 17, 327. https://doi.org/10.2116/analsci.17.327
  34. Eskandari, H.; Ghaziaskar, H. S.; Ensafi, A. A. Anal. Lett. 2001, 34, 2535. https://doi.org/10.1081/AL-100107534
  35. Bassett, J.; Denney, R. C.; Jeffery, G. H.; Mendham, J. Textbook of Quantitative Inorganic Analysis, 5th Ed.; Longman Group Limited: New York, U. S. A., 1989; p 474.
  36. Furniss, B. S.; Hannaford, A. J.; Rogers, V.; Smith, P. W. G.; Tatchall, A. R. Vogel's Textbook of Practical Organic Chemistry, 4th Ed.; Longman Group Limited: London, U. K., 1978; p 811.
  37. Choi, H. S.; Lee, S. K. Bull. Korean Chem. Soc. 2001, 22, 463.
  38. Lyman, T. Metals Handbook, 8th Ed.; American Society for Metals: New York, U. S. A., 1966; Vol. 1, pp 814-1195.

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