Bulletin of the Korean Chemical Society

  • 제24권12호
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  • Pages.1737-1741
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  • 2003
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis of Azo-functionalized Calix[4]arenes and Its Application to Chloride-selective Electrode as Ionophores

  • Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Yeo, Hee-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Park, Duck-Hee (vDepartment of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National University)
  • 발행 : 2003.12.20
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초록

Azo-functionalized calix[4]arenes as ionophores for chloride-selective electrode, 5,11,17,23-Tetra-tert-butyl-25,27-bis[(N,N-dimethyl-aniline-azo-phenylthioureido)ethyl]oxy-26,28-dihydroxycalix[4]arene (4a) and 5,11,17,23-Tetra-tert-butyl-25,27-bis[(N,N-dimethyl-aniline-azo-phenylthioureido)ethyl]oxy-26,28-dimethoxycalix[4]arene (4b) were synthesized. The PVC membrane electrode based on azo-functionalized calix[4]arene 4a with o-NPOE exhibits a linear stable response over a wide concentration range ($1.5{\times}10^{-4}-1.0{\times}10^{-1}$) with a slope of -52.0 mV/decade and a detection limit of log[$Cl^-$] = -4.02. This ionophore-based membrane exhibited improved selectivity for chloride anion compared with classical Hofmeister series.

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피인용 문헌

  1. Calixarene-based Anion Receptors vol.17, pp.6, 2005, https://doi.org/10.1080/10610270500127089
  2. Ion and Molecular Recognition by Lower Rim 1,3-Di-conjugates of Calix[4]arene as Receptors vol.111, pp.8, 2011, https://doi.org/10.1021/cr1004524
  3. Synthesis of Azo-Functionalized Calix[4]arenes and Its Application to Chloride-Selective Electrode as Ionophores. vol.35, pp.15, 2004, https://doi.org/10.1002/chin.200415065
  4. Macrocycles containing azo groups: recognition, assembly and application vol.92, pp.1-2, 2018, https://doi.org/10.1007/s10847-018-0819-8
  5. Synthesis of two new p-tert-butylcalix[4]arene β-ketoimin derivatives for extraction of dichromate anion vol.63, pp.3-4, 2009, https://doi.org/10.1007/s10847-008-9513-6
  6. Fluorescent Sensing of Tetrahedral Anions with a Pyrene Urea Derivative of Calix[4]arene Chemosensor vol.30, pp.7, 2003, https://doi.org/10.5012/bkcs.2009.30.7.1675
  7. Tetrahedral Anions Selective Fluorescent Calix[6]arene Receptor Containing Urea and Pyrene Moieties vol.31, pp.12, 2003, https://doi.org/10.5012/bkcs.2010.31.12.3809
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