Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Sorbent Extraction of Some Metal Ions on a Gas Chromatographic Stationary Phase Prior to Their Flame Atomic Absorption Determinations

  • Soylak, M. (Erciyes University, Faculty of Art and Science, Department of Chemistry) ;
  • Saracoglu, S. (Erciyes University, Faculty of Education) ;
  • Elci, L. (Pamukkale University, Faculty of Art-Science, Department of Chemistry)
  • Published : 2003.05.20
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Abstract

An enrichment/separation system for atomic absorption spectrometric determinations of Cu(Ⅱ), Fe(Ⅲ), Ni(Ⅱ) and Co(Ⅱ) has been established. The procedure is based on the adsorption of the analytes as calmagite chelates on Chromosorb-102. The effects of some parameters including pH, amount of ligand, salt matrix, flow rates of sample and eluent solutions were investigated. Under optimized conditions, the relative standard deviation of the combined method of sample treatment, preconcentration and determination with FAAS (N=5) is generally lower than 5%. The limit of detection (3σ) was between 6.0-112.9 ㎍/L. The results were used for preconcentration of analytes from some sodium and ammonium salt.

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References

  1. Keil, O.; Dahmen, J.; Volmer, D. A. Fresen. J. Anal. Chem. 1999, 364, 694. https://doi.org/10.1007/s002160051416
  2. Turkoglu, O.; Soylak, M. Asian J. Chem. 2002, 14, 1698.
  3. Mizuike, A. Enrichment Techniques for Inorganic Trace Analysis; Springer: Berlin, 1983; pp 1-18.
  4. Im, K. S.; Pak, Y. M. J. Korean Chem. Soc. 1999, 43, 644.
  5. Ivanova, E.; Benkhedda, K.; Adams, F. J. Anal. At. Spect. 1998, 13, 527. https://doi.org/10.1039/a709150h
  6. Torgov, V. G.; Demidova, M. G.; Saprykin, A. I.; Nikolaeva, I. V.; Us, T. V.; Chebykin, E. P. J. Anal. Chem. 2002, 57, 303. https://doi.org/10.1023/A:1014942112864
  7. Yamini, Y.; Chaloosi, M.; Ebrahimzadeh, H. Mikrochim. Acta 2002, 140, 195. https://doi.org/10.1007/s00604-002-0906-8
  8. Cyr, P. J.; Suri, R. P. S.; Helmig, E. D. Water Res. 2002, 36, 4725. https://doi.org/10.1016/S0043-1354(02)00214-2
  9. Moldovan, Z.; Neagu, E. A. J. Serb. Chem. Soc. 2002, 67, 669. https://doi.org/10.2298/JSC0210669M
  10. Bangash, F. K.; Alam, S.; Iqbal, M. J. Chem. Soc. Pakistan 2001, 23, 215.
  11. Wasey, A.; Bansal, R. K.; Puri, B. K.; Rao, A. L. J. Talanta 1984, 31, 205. https://doi.org/10.1016/0039-9140(84)80051-X
  12. Soylak, M.; Karatepe, A. U.; Elci, L.; Dogan, M. Turk. J. Chem. 2003, 27, 235.
  13. Cai, Y.; Jiang, G.; Liu, J. Talanta 2002, 57, 1173. https://doi.org/10.1016/S0039-9140(02)00194-7
  14. Saracoglu, S.; Elci, L. Anal. Chim. Acta 2002, 452, 77. https://doi.org/10.1016/S0003-2670(01)01425-8
  15. Cai, Y.; Jiang, G.; Liu, J. Analyst 2001, 126, 1678. https://doi.org/10.1039/b105866p
  16. Elci, L.; Arslan, Z.; Tyson, J. F. Spectrochim. Acta 2000, 55B, 1109.
  17. Cai, Y.; Jiang, G. B.; Liu, J. F.; Liang, X. Atom. Spectr. 2002, 23, 52.
  18. Saracoglu, S.; Divrikli, U.; Soylak, M.; Elci, L. J. Food Drug Anal. 2002, 10, 188.
  19. Cai, Y.; Jiang, G.; Liu, J.; He, B. Anal. Sci. 2002, 18, 705. https://doi.org/10.2116/analsci.18.705
  20. Karatepe, A. U.; Soylak, M.; Elci, L. Anal. Lett. 2002, 35, 1561. https://doi.org/10.1081/AL-120006731
  21. Saracoglu, S.; Soylak, M.; Elci, L.; Dogan, M. Anal. Lett. 2002, 35, 1519. https://doi.org/10.1081/AL-120006727
  22. Ferreira, S. L. C.; Lemos, V. A.; Moreira, B. C.; Costa, A. C. S.; Santelli, R. E. Anal. Chim. Acta 2000, 403, 259. https://doi.org/10.1016/S0003-2670(99)00632-7
  23. Ferreira, S. L. C.; Ferreira, J. R.; Dantas, A. F.; Lemos, V. A.; Araujo, N. M. L.; Costa, A. C. S. Talanta 2000, 50, 1253. https://doi.org/10.1016/S0039-9140(99)00230-1
  24. dos Dantos, H. C.; Korn, M. G. A.; Ferreira, S. L. C. Anal. Chim. Acta 2001, 426, 79. https://doi.org/10.1016/S0003-2670(00)01192-2
  25. Soylak, M.; Divrikli, U.; Elci, L.; Dogan, M. Talanta 2002, 56, 565. https://doi.org/10.1016/S0039-9140(01)00575-6
  26. Soylak, M.; Saracoglu, S.; Elci, L.; Dogan, M. Int. J. Environ. Anal. Ch. 2002, 82, 225. https://doi.org/10.1080/03067310290027794
  27. Berndt, H.; Jackwerth, E. Spectrochim. Acta 1975, 30B, 169.

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