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Korean Chemical Society (대한화학회)
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Synthesis and Electrochemical Characteristics of Li0.7[Ni0.05Mn0.95]O2 as a Positive Material for Rechargeable Lithium Batteries

  • Published : 2002.05.20
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Abstract

Layered Na0.7[Ni0.05Mn0.95]O2 compounds have been synthesized by a sol-gel method, using glycolic acid as a chelating agent. Na0.7[Ni0.05Mn0.95]O2 precursors w ere used to prepare layered lithium manganese oxides by ion exchange for Na by Li, using LiBr in hexanol. Powder X-ray diffraction shows the layered Na0.7[Ni0.05Mn0.95]O2 has an O3 type structure, which exhibits a large reversible capacity of approximately 190 mA h g-1 in the 2.4-4.5 V range. Na0.7[Ni0.05Mn0.95]O2 powders undergo transformation to spinel during cycling.

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References

  1. Thackeray, M. M.; David, P. G.; Bruce, P. G.; Goodenough, J. B.Mat. Res. Bull. 1983, 18, 461. https://doi.org/10.1016/0025-5408(83)90138-1
  2. Ohzuka, T.; Kitagawa, M.; Hirai, T. J. Electrochem. Soc. 1990,137, 769. https://doi.org/10.1149/1.2086552
  3. Guyomard, D.; Tarascon, J.-M. Solid State Ionics 1994, 69, 222. https://doi.org/10.1016/0167-2738(94)90412-X
  4. Gummow, R. J. de Kock, A.; Thackeray, M. M. Solid State Ionics1994, 69, 59. https://doi.org/10.1016/0167-2738(94)90450-2
  5. Amine, K.; Tukamoto, H.; Yasuda, H.; Fujita, Y. J. Electrochem.Soc. 1996, 143, 1607. https://doi.org/10.1149/1.1836686
  6. Amatucci, G. G.; Schmutz, C. N.; Bylr, A.; Siala, C.; Gozdz,A. S.; Larcher, D.; Tarascon, J.-M. J. Power Sources 1997, 69,11. https://doi.org/10.1016/S0378-7753(97)02542-1
  7. Xia, Y.; Zhou, Y.; Yoshio, M. J. Electrochem. Soc. 1997, 144,2593. https://doi.org/10.1149/1.1837870
  8. Huang, H.; Vincent, C. A.; Bruce, P. G. J. Electrochem. Soc. 1999,146, 481. https://doi.org/10.1149/1.1391632
  9. Sun, Y.-K. Electrochemistry Communications 2001, 3, 199. https://doi.org/10.1016/S1388-2481(01)00141-2
  10. Armstrong, A. R.; Bruce, P. G. Nature 1996, 381, 499. https://doi.org/10.1038/381499a0
  11. Vitins, G.; West, K. J. Electrochem. Soc. 1997, 144, 2587. https://doi.org/10.1149/1.1837869
  12. Tabuchi, M.; Ado, K.; Kobayashi, H.; Kageyama, H.; Masquelier,C.; Kondo, A.; Kanno, R. J. Electrochem. Soc. 1998, 145,L49. https://doi.org/10.1149/1.1838411
  13. Parant, J. P.; Olazcuaga, R.; Devalette, M.; Fouassier, C.;Hagenmuller, P. J. Solid State Chem. 1971, 3, 1. https://doi.org/10.1016/0022-4596(71)90001-6
  14. Paulsen, J. M.; Thomas, C. L.; Dahn, J. R. J. Electrochem. Soc.1999, 146, 3560. https://doi.org/10.1149/1.1392514
  15. Paulsen, J. M.; Thomas, C. L.; Dahn, J. R. J. Electrochem. Soc.2000, 147, 861. https://doi.org/10.1149/1.1393283
  16. Paulsen, J. M.; Dahn, J. R. J. Electrochem. Soc. 2000, 147,2478. https://doi.org/10.1149/1.1393556
  17. Prerre, A. C. In Introduction to Sol-Gel Processing; KluwerAcademic Publishers: 1998; p 6.
  18. Jeffery, G. H.; Bassett, J.; Mendham, J.; Denney, R. C. In Vogel's Textbook of Quantitative Chemical Analysis, 4th ed.; Longman Scientific & Technical: New York, 1978; p 584.
  19. Ohzuku, T.; Ueda, A.; Kouguchi, M. J. Electrochem. Soc. 1995,142, 4033. https://doi.org/10.1149/1.2048458
  20. Shao-Horn, Y.; Hackney, S. A.; Armstrong, A. R.; Bruce, P. G.;Gitzendanner, R.; Johnson, C. S.; Thackeray, M. M. J.Electrochem. Soc. 1999, 146, 2404. https://doi.org/10.1149/1.1391949
  21. Ammundsen, B.; Desilvestro, J.; Groutso, T.; Hassell, D.; Metson,J. B.; Regan, E.; Steiner, R.; Pickering, P. J. J. Electrochem. Soc.2000, 147, 4078. https://doi.org/10.1149/1.1394022
  22. Armstrong, A. R.; Robertson, A. D.; Bruce, P. G. ElectrochimicaActa 1999, 45, 285. https://doi.org/10.1016/S0013-4686(99)00211-X
  23. Quine, T. E.; Duncan, M. J.; Armstrong, A. R.; Robertson, A. D.;Bruce, P. G. J. Mater. Chem. 2000, 10, 2838. https://doi.org/10.1039/b007429m

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