Bulletin of the Korean Chemical Society

  • 제22권6호
  • /
  • Pages.611-615
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  • 2001
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Soluble Single-Molecule Magnet: Mn12-stearate.

  • 발행 : 20010600
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초록

A new polynuclear complex of manganese stearate has been prepared by substitution of acetate with stearic acid. The stearate ion with long alkyl chain was used to isolate molecular $Mn_{12}$ cluster from each other. The $Mn_{12}$-stearate compound prepared is soluble in most organic solvents and resistant against water catalyzed reduction. The $Mn_{12}$-stearate compound shows similar electrochemical, magnetic properties to the pristine $Mn_{12}$-acetate.

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피인용 문헌

  1. The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4] vol.38, pp.4, 2001, https://doi.org/10.1039/b811963e
  2. Investigation of the thermal and structural properties of single-molecule magnet/polymer nanocomposite films vol.44, pp.11, 2009, https://doi.org/10.1007/s10853-009-3369-z
  3. The Separation of the Mn 12 Single-Molecule Magnets onto Spherical Silica Nanoparticles vol.9, pp.5, 2001, https://doi.org/10.3390/nano9050764
  4. Mesoporous Silica-Based Materials for Electronics-Oriented Applications vol.24, pp.13, 2001, https://doi.org/10.3390/molecules24132395
  5. How to Control the Distribution of Anchored, Mn 12 –Stearate, Single-Molecule Magnets vol.9, pp.12, 2001, https://doi.org/10.3390/nano9121730
  6. Nanostructured Silica with Anchoring Units: The 2D Solid Solvent for Molecules and Metal Ions vol.21, pp.21, 2001, https://doi.org/10.3390/ijms21218137