An Experimental Study on the Reduction of Nitric Oxides from the Diesel Engine Exhaust Gas with Metal Supported Oxides Catalysts

디젤엔진 배기가스중 질소산화물 저감을 위한 금속 산화물 촉매를 이용한 실험적 연구

  • Published : 2001.05.01

Abstract

In this paper, a number of supported metal oxides and perovskite type catalysts were investigated for the NOx reduction from the diesel engine exhaust gas. All catalysts were made into pellets type with diameter of 3-4 mm alumina(Al$_2$O$_3$) as a supporter. These samples were tested by real diesel exhaust gas which contains CO, hydrocarbons and soot in the temperature range of 150~55$0^{\circ}C$ with the $3300h^{-1}$ space velocity (SV). Among the results, several promising catalysts showed NOx conversion above 50% in the temperature range of 150-35$0^{\circ}C$. From these results supported metal oxides catalysts and perovskite type could be recommended for the practical application to the automobile exhaust treatments.

Keywords

References

  1. J. of Catalyst. v.161 no.1 Reactivity of V205 catalyst for SCR of NO by NH3 M.D.Amirids;I.E.Wachs;G.Deo
  2. Applied catalyst B v.6 no.L Reaction mechanism for the reduction of NO by hydrocarbons on Cu-ZSM5 and related catalyst Y.Iwasawa;R.H.H.Smite
  3. Applied catalyst B v.8 Silver-promoted catalyst for removal of nitrogen oxides from emission of diesel engine K.Masuda;K.Tsujimura
  4. Catalysis today v.46 Catalytic removal of NO V.I.Parvulescu(et al.)
  5. Catalysis today v.36 The effect of pretreatments on different copper exchanged ZSM5 for decomposition T.Curtin;P.Grange
  6. Catalysis today v.42 Mechanistic consideration for the reduction of NOx over Pt/AI203 catalyst under lean burn conditions R.Burch;J.A.Sullivan
  7. Catalysis today v.53 Role of lamthanide elements on the catalytic behavior of supported Pd catalyst in the reduction of NO with methane J.Mitome
  8. Bulletin chemistry Society of Japan v.72 Identification of active crystalline phase in La-K-Cu-V mixed oxide for the simultaneous removal of nitrogen oxides and diesel soot Y.Teraoka
  9. Applied catalyst B v.6 no.2 Reduction of NOx in Diesel exhaust with methanol over alumina catalyst H.Hamada;T.Ito;Y.Kintaichi
  10. SAE 902110 Catalyst consideration for diesel converters D.J.Bell;R.G.Stack
  11. Catalyst today v.38 Reduction of nitrogen oxides with hydrocarbons catalyzed by bifunctional catalysts M.Misono;Y.Hirao;C.Yokoyama
  12. Catal. today v.42 Selective catalytic reduction of Nitric oxide from stationary diesel sources by methanol over promoted alumina catalyst S.G.Master;D.Chadwick