Dielectric Properties of Non-reducible X7R Dielectric Materials in $BaTiO_3$-$Er_2$$O_3$--MgO

$BaTiO_3$-$Er_2$$O_3$-MgO 첨가계를 이용한 내환원성 X7R 재질의 유전특성에 관한 연구

  • 한영호 (성균관대학교 재료공학과) ;
  • 최상근 (성균관대학교 재료공학과) ;
  • 황진현 (성균관대학교 재료공학과)
  • Published : 2001.07.01

Abstract

E $r_2$ $O_3$-MgO 복합 첨가가 BaTi $O_3$계 내환원성 X7R 재질의 유전특성에 미치는 영향에 대하여 환원성 분위기에서 연구하였다. (B $a_{1-x}$ E $r_{x}$)( $Ti_{1-y}$M $g_{y}$ ) $O_3$첨가계에서 1.0 mol% 이상 MgO의 복합첨가로 E $r_{Ba}$ 도너 불순물과 $Mg_{Ti}$ 억셉터 불순물이 전기적으로 보상되어, 환원성분위기 소결 후에도 $10^{10}$Ωcm 이상의 높은 절연저항을 나타내었다. E $r_2$ $O_3$가 첨가된 시편에서 MgO가 2.0 mol% 이상 첨가될 경우, 유전율의 온도안정성이 향상되어 X7R 규격을 만족시켰으며 1.0$mu extrm{m}$ 이하의 작고 균일한 입자가 관찰되었다. 한편, E $r_2$ $O_3$의 첨가량이 3.0 mol%로 증가함에 따라 유전율의 온도안정성이 향상되었으나 상대적으로 상온 유전상수값이 현저히 감소하였다.였다.다.

Keywords

References

  1. Ceram. Bull. v.57 no.6 Ceramic Disk Capacitors with Base-metal Electrodes I. Burn
  2. Jpn. J. Appl. Phys. v.30 X7R Multilayer Ceramic Capacitors with Nickel Electrodes H. Saito;H. Chazono;H. Kishi;N. Yamaoka
  3. Ferroelectrics v.133 New Barium Titanate Based Material For MLCs with Ni Electrode Y. Sakabe;Y. Hamaji;T. Nishiyama
  4. Jpn. J. Appl. Phys. v.33 Dielectric Properties of Rare-earth-oxide-doped BaTiO₃Ceramics Fired in Reducing Atmosphere Y. Okino;H. Shizuno;S. Kusumi;H. Kishi
  5. Jpn. J. Appl. Phys. v.36 The Effect of MgO and Rare-earth Oxide on Formation Behavior of Core-shell Structure in BaTiO₃ H. Kishi;Y. Okino;M. Honda;Y. Iguchi;M. Imaeda;Y. Takahashi;H. Ohsato;T. Okuda
  6. Jpn. J. Appl. Phys. v.37 Influence of the Microstructure Evolution on Electrical Properties of Multilayer Capacitor with Ni Electrode Y. Mizuno;Y. Okino;N. Kohzu;H. Chazono;H. Kishi
  7. J. Eur. Ceram. Soc. v.19 The Effect of Rare-earth (La, Sm, Dy, Ho and Er)and Mg on the Microstructure in BaTiO₃ H. Kishi;N. Kohzu;J. Sugino;H. Ohsato;Y. Iguchi;T. Okuda
  8. Jpn. J. Appl. Phys. v.38 Effect of Occupational Sites of Rare-earth Elements on the Microstructure in BaTiO₃ H. Kishi;N. Kohzu;Y. Mizuno;Y. Iguchi;J. Sugino;H. Ohsato;T. Okuda
  9. Jpn. J. Appl. Phys. v.38 BaTiO₃-based Non-reducible Low-loss Dielectric Ceramics T. Nakamura;H. Sano;T. Konoike;K. Tomono
  10. Jpn. J. Appl. Phys. no.SUP.26-2 Equilibrium Conductivity for Er Doped BaTiO₃ K. Takada;H. Ichimura;D. M. Smyth
  11. J. Am. Ceram. Soc. v.83 no.1 Effect of MgO Doping on the Phase Transformation of BaTiO₃ T. Nagai;K. Iijima;H. J. Hwang;M. Sando;T. Sekino;K. Nihara
  12. Advances in Ceramics v.19 Rare Earth Additions to BaTiO₃ K. Takada;E. Chang;D. M. Smyth;J. B. Blum(ed.);W. R. Cannon(ed.)
  13. Mat. Sci. Engi. v.B1 The Influence of Ionic Radii on the Incorporation of Trivalent Dopants into BaTiO₃ L.A. Xue;Y. Chen;R. J. Brook
  14. Solid State Ion. v.140 no.1-2 Defect Chemistry of Er-doped BaTiO₃ J. H. Hwang;Y. H. Han
  15. J. Am. Ceram. Soc. v.81 no.7 Novel Doping Mechanism for Very-high-permeability Barium Titanate Ceramics F.D. Morrison;D. C. Sinclair;J. M. S. Skakle;A. R. West
  16. J. Eur. Ceram. Soc. v.13 High-permittivity Dielectric Ceramics with High Endurance D.F.K. Hennings;B. Schreinemacher;H. Schreinemacher
  17. J. Am. Ceram. Soc. v.69 no.9 Defect Structure and Dielectric Properties of Nd₂O₃-modified BaTiO₃ A. S. Shaikh;R. W. Vest
  18. Am. Ceram. Bull. v.79 Effect of Rare Earth Doping onTemperature-capacitance Characteristics for MLCCs with Ni Electrode S. Sato;Y. Fujikawa;T. Nomura
  19. J. Am. Ceram. Soc. v.77 no.6 Thickness of Cubic Surface Phase on Barium Titanate Single-crystalline Grains T. Takeuchi;K. Ado;T. Asai;H. Kageyama;Y. Saito;C. Masquelier;O, Nakamura
  20. J. Am. Ceram. Soc. v.82 no.10 Sintering Characteristics in BaTiO₃-Nb₂$O_5$-Co₃O₄Ternary System : I, Electrical Properties and Microstructure H. Chazono; H. Kishi
  21. J. Am. Ceram. Soc v.83 no.1 Sintering Characteristics in BaTiO₃-Nb$O_5$-Co₃O₄Ternary System : II, Stability of Socalled Core-shell Structure H. Chazono;H. Kishi
  22. J. Am. Ceram. Soc. v.73 no.5 Influence of Coreshell Grains on the Internal Stress State and Permittivitiy Response of Zirconia-modified Barium Titanate T. R. Armstrong;R. C. Buchanan
  23. Jpn. J. Appl. Phys. v.40 Dielectric Properties of Erbium Doped Barium Titanate J. H. Hwang;Y. H. Han
  24. J. Am. Ceram. Soc. v.69 no.12 Effect of Powder Purity and Second Phases on the Dielectric Properties of Lead Magnesium Niobate Ceramics J. Chen;A. Gorton;H. M. Chen;M. P. Harmer
  25. Ceram. Bull. v.66 Phase Relations and Dielectric Properties of Ceramics in the System Pb($Zn_{1/3}Nb_{2/3}$)O₃-SrTiO₃-PbTiO₃ J. R. Belsick;A. Halliyal;U. Kumar;R. E. Newnham