Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Synthesis and Electronic Properties of Dicarbonyltetrakis(triphenylphosphine) Complexes of Molybdenum(0) and Tungsten(0)

디카르보닐테트라키스 몰리브데늄(0)과 텅스텐(0) 착물들에 대한 합성과 전자적 성질에 관한 연구

  • 최칠남 (조선대학교 자연과학대학 화학과) ;
  • 김선규 (조선대학교 자연과학대학 화학과)
  • Published : 20000600
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Abstract

The chemical behavior for Mo(0) and W(0) complexes, [M(CO)$_2$(PPh$_3$)$_4$] (M=Mo and W),has been investigated by UV-vis spectroscopic, magnetic, and electrochemical methods. Three absorption bands are observed in the UV-spectra. The crystal-field-splitti ng energy, spin-pairing energy, and bond strengths were deduced from the spectra. The metal d electrons in both complexes seemed to be delocalized in low-spin state.Metal ligand correlation appeared to strongly depend on bond strengths and diamagnetic properties. In electrochemical processes, both complexes exhibit an irreversible reduction wave.

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References

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