Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

The “Trivial” Mechanism for the Photo-Fries Reaction of Phenyl Acetate and Biphenylyl Acetates

  • Published : 20000900
Download PDF
⟨ Previous Next ⟩

Abstract

The mechanism for the photo-Fries rearrangement of phenyl acetate andbiphenylyl acetates were reinvestigat-ed in phenol (or phenol derivatives) containing media. The results showed that the phenol (or phenol deriva-tives) which is the most common by-product of Fries reaction reacts with acyl radical togive Fries-product. These phenol (or phenol derivatives) contributions to the Fries-products were suggested as the Trivial mecha-nism for the photo-Fries reaction.

Keywords

References

  1. Organic Photochemistry and Photobiology Horspool, W. M.;Song, P. S.
  2. Bull. Korean Chem. Soc. v.19 Ko, S. H.;Chae, W. K.
  3. Pharmacology & Toxicology v.68 Ito, T.;Minura, Y.;Kadokawa, T.;Hori, S.;Shimada, J.;Miyahara, T.
  4. Pharmacology & Toxicology v.73 Zhi, J.;Nightingale, C. H.
  5. J. Photochem. Phtobiol.A : Chem. v.77 Das, S.;Muneer, M.;Gopidas, K. R.
  6. J. Chem. Soc., Chem. Commun. Jimenz, M. C.;Leal, P.;Miranda, M. A.;Tormors, R.
  7. J. Org. Preparations and Procedures, International v.24 Khanna, R. N.;Singh, K. P.;Sharma,
  8. J. Am. Chem. Soc. v.117 Arai, T.;Tobita, S.;Shizuka, H.