Korean Journal of Crystallography (한국결정학회지)
- Volume 11 Issue 2
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- Pages.80-83
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- 2000
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- 1229-8700(pISSN)
$[Ni(dppe)_2]$ 의 합성 및 구조
Synthesis and Structure of $[Ni(dppe)_2] (dppe=Ph_2PCH_2CH_2PPh_2)$
- Kim, Wan -Sung (Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746) ;
- Lee, Ji-Hwa (Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746) ;
- Lee, Soon W. (Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746)
- Published : 2000.06.01
Abstract
Compound [Ni(P(OEt)3)4] (1) reacted with bis(diphenylphosphino)ethane (Ph2PCH2CH2Ph2, dppe) to give bis(bis(diphenylphosphine)ethane)nickel(0), [Ni(dppe)2] (2). Compound 2 was characterized by spectroscopy (1H-and 31P{1H}-NMR) and X-ray crystallography. Crystallographic data for 2: monoclinic space group P21/n, a=9.826(1)Å, b=21.167(2)Å, c=21.425(2)Å, β=91.957(9)°, Z=4, R(wR2)=0.0377(0.0882).
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