HFC-32/143a와 HFC-143a/134a계의 기-액상평형 실험에 관한 연구

Investigation of vapor-liquid equilibrium of HFC-32/143a and HFC-143a/134a systems

Vapor-liquid equilibrium apparatus is designed and set up. The equilibrium data of two binary systems, HFC-32/143a and HFC-143a/134a, are measured. Fifteen equilibrium data for HFC-32/143a and HFC-143a/134a systems are measured over the temperature range 263.15~283.15K at 10K interval and the composition range 0.10~0.80, respectively. And vapor-liquid equilibrium data are calculated using equation of state and correlation of activity coefficient and compared with the present data. Equation of state is used CSD and RKS equations and correlation of activity coefficient is used Margules' and Van Ness and Abbott's correlations. Real behavior of HFC-32/143a system has very large deviation with Raoult's rule which is ideal behavior. But real behavior of HFC-143a/134a system is similar to ideal behavior. The calculated data from CSD equation are compared with the data in the open literatures and the calculated data from REFPROP. In the results for REFPROP, the relative deviations of bubble point pressure for HFC-32/143a system are within -2.16~0.84% for CSD equation and within -0.20~1.10% for RKS equation. And the relative deviations of bubble point pressure for HFC-143a/134a system are within -0.45~0.12% and -0.20~2.8% for CSD and RKS equations, respectively.