Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Analysis of Toxic-PCBs in Sediment by Isotope Dilution HRGC/HRMS

Isotope Dilution HRGC/HRMS 방법을 이용한 저니토중 Toxic-PCBs 분석

  • Received : 1999.05.27
  • Published : 1999.12.25
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Abstract

This Analysis was conducted for 13 toxic-PCBs having TEF value among 209 PCBs isomers in sediment by isotope dilution HRGC/HRMS method. From the result, the recovery of surrogate standard was in the range of 71~99%. The concentration range for 13 toxic-PCBs in sediment was found to be 0.84~2.49 ng/g, among them the concentration levels of 2,2',3,3',4,4',5-HpCB(IUPAC No. 170) and 2,2',3,4,4',5,5'-HpCB(IUPAC No. 180) represented almost 50% of total concentrarion and that of 2,3,4,4,5-PeCB(IUPAC No. 114) showed over 10%. The TEQ concentration levelwas in the range of 0.38~2.63 pg-TEQ/g and 3,3',4,4',5-PeCB(IUPAC No. 126) concentration represented over 50% of total TEQ concentration.

본 연구에서는 209종의 PCBs 이성체중 독성등가계수(Toxic Equivalance Factor, TEF)가 제시된 13종의 toxic-PCBs에 대하여 Isotope dilution HRCC/HRMS 방법으로 저니토중의 toxic-PCBs를 분석하였다. 분석결과 surrogate 표준물질의 회수율은 71~99%로 양호하였다. 13종의 toxic-PCBs 농도는 0.84~2.49 ng/g 범위이었으며, 이중 2,2',3,3',4,4',5-HpCB(IUPAC No. 170) 및 2,2',3,4,4',5,5'-HpCB(IUPAC No. 180) 농도가 전체 농도의 50% 정도를 나타내었으며, 2,3,4,4,5-PeCB(IUPAC No. 114)도 10% 정도를 나타내었다. 독성등가계수로 환산한 농도는 0.38~2.63 pg-TEQ/g 범위이었으며, 3,3',4,4',5-PeCB(lUPAC No. 126)가 전체의 50%를 나타내었다.

Keywords

References

  1. Toxic Substance Control Act Inventory
  2. European Inventory of Existing Commercial Chemical Substances
  3. Guide to Current ENCS Listed Chemical
  4. 기존화학물질목록 환경부
  5. 해양오염감시망 구축 및 오염실태 변화에 대한 연구(Ⅲ) 국립환경연구원
  6. Chemosphere v.17 no.10 J. N. Huckins;T. R. Schwartz
  7. Toxicol v.24 no.2 Critical Rev. S. H. Safe
  8. Our Stolen Future(1st ed.) T. Colborn;D. Dumanoski;J. P. Myers
  9. 환경부고시 제 91-97호 폐기물공정시험방법
  10. 환경부 고시 제 1998-16호 토양오염공정시험방법
  11. USEPA 1668 Method
  12. 호소, 하천 퇴적물의 조사 국립 환경 연구원