산업기술연구 (Journal of Industrial Technology)
- 제18권
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- Pages.277-287
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- 1998
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- 1229-9588(pISSN)
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- 1598-1371(eISSN)
연속열역학을 이용한 랜덤공중합체 용액의 상분리
Phase Separations in Random Copolymer Solutions by Continuous Thermodynamics
- 발행 : 1998.12.31
초록
In this work continuous thermodynamics was adopted for describing the influence of copolymer polydispersity on phase separations in random copolymer solutions. Continuous themodynamic frameworks were formulated using the Flory-Huggin's excess Gibbs free energy model in which the concentration- and temperature-depentent terms of interaction parameter x were modified. Cloud-point curves and coexistence curves of poly(ethylene-vinylactate)/methylacetate solutions and poly(ehtylene-vinylacetate)/ethylacetate solutions were measured, and experimental data were fitted with theoretical relations formulated in this work. Calculated could-point curves were more good ageeable with experimental data than the modified Flory-Huggins's relations. Coexistence curves which were evaluated by using parameters of x estimated from experimental cloud-point curves, were found to coincide with experimental data.
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