Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Redistribution/Dehydrocoupling of Tertiary Alkylstannane $n-Bu_3 SnH$ Catalyzed by Group 4 and 6 transition Metal Complexes

  • Published : 1998.11.20
Download PDF
⟨ Previous Next ⟩

Abstract

The catalytic transformation of sterically bulky tertiary stannane n-Bu3SnH by the Cp2MCl2/Red-Al (M=Ti, Zr, Hf) and M(CO)6 (M=Cr, Mo, W) catalysts yielded two kinds of catenated products: one is a cross-linked polystannane as minor product, and the other is hexabutyldistannane (n-Bu3Sn)2 as major product. The distannane was produced by simple dehydrocoupling of n-Bu3SnH, whereas the cross-linked polystannane could be obtained via redistribution/dehydrocoupling combination process of n-Bu3SnH. The redistribution/dehydrocoupling combination process may initially produce a low-molecular-weight oligostannane with partial backbone Sn-H bonds which could then undergo an extensive cross-linking reaction of backbone Sn-H bonds, resulting in the formation of an insoluble polystannane.

Keywords

References

  1. Inorganic Polymers Mark, J. E.;Allcock, H. R.;West. R.
  2. Chem. Lett. Yajima, S.;Omori, M.;Hayashi, J.;Okamura, K.;Matsuzawa, T.;Liaw, C. F.
  3. J. Am. Chem. Soc. v.110 Bianconi, P. A.;Weidman, T. W.
  4. Polym. Eng. Sci. v.23 Griffing, B. F.;West, r.
  5. J. Am. Chem. Soc. v.103 West, R.;David, L. D.;Djurovich, P. I.;Stearley, K. S. V.;Srinivasan, H. Y.
  6. Chem. Rev. v.89 Miller, R. D.;Michl, J.
  7. J. Organomet. Chem. v.300 West, R.
  8. Organomentallics v.4 Trefonas, P., III;Damewood, J. R., Jr.;West, R.;Miller, R. D.
  9. Macromolecules v.20 Harrah, L. A.;Zeigler, J. M.
  10. Macromolecules v.25 Fujino, M.;Hisaki, T.;Fujiki, M.;Matsumoto, N.
  11. Macromolecules v.23 Sakamoto, K.;Yoshida, M.;Sakurai, H.
  12. Macromol. Sci.-Chem. v.A28 Matyjaszewski, K.;Cypryk, M.;Frey, H.;Hrkach, J.;Kim, H. K.;Moeller, M.;Ruehl , K.;White, M. J.
  13. Angew. Chem. Int. Ed. Engl. v.15 Hengge, E.;Litscher, G. K.
  14. Macromolecules v.28 Matyjaszewski, K.;Greszta, D.;Hrkach, J. S.;Kim, H. K.
  15. Organometallics v.14 Kimata, Y.;Suzuki, H.;Satoh, S.;Kuriyama, A.
  16. Can. J. Chem. v.65 Aitken, C.;Harrod, J. F.;Gill, U. S.
  17. Organometallics v.6 Harrod, J. F.;Yun, S. S.
  18. Organometallics v.8 Altken. C.;Barry, J. P.;Gauvin, F.;Harrod, J. F.;Malek, A.;Rosseau, D.
  19. Organometallics v.9 Harrod, J. F.;Ziegler, T.;Tschinke, V.
  20. Organometallics v.12 Woo, H.-G.;Harrod, J. F.;Henique, J.;Samuel, E.
  21. Organometallics v.12 Britten, J.;Mu, Y.;Harrd, J. F.;Polowin, J.;Baird, M. C.;Samuel, E.
  22. J. Am. Chem. Soc. v.119 Xin, S.;Woo, H.-G.;Harrod, J. F.;Samuel, E.;Lebuis, A,-M.
  23. J. Am. Chem. Soc. v.111 Woo, H.-G.;Tilley, T. D.
  24. J. Am. Chem. Soc. v.111 Woo, H.G.;Tilley, T.D.
  25. J. Am. Chem. Soc. v.114 Woo, H.-G.;Heyn, R. H.;Tilley, T. D.
  26. J. Am. Chem. Soc. v.114 Woo, H.G.;Walzer, J. F.;Tilley, T. D.
  27. Organometallics v.12 Banovetz, J. P.;Suzuki, H.;Waymouth, R. M.
  28. Macromolecules v.24 Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  29. Chem. Mater. v.5 Imori, T.;Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  30. NATO ASI Series E: Appl. Sci. no.141 Transformation of Organometallics into Common and Exotic Materials; Design and Activation Harrod, J. F.;Laine, R. M.(Ed.)
  31. Inorganic and Organometallic Polymers and Oligomers Mu, Y.;Harrod, J. F.;Harrod, J. F.(Ed.);Laine, R. M.(Ed.)
  32. Organometallics v.13 Dioumaev, V. K.;Harrod, J. F.
  33. Acc. Chem. Res. v.26 Tilley, T. D.
  34. Polyhedron v.13 Imori, T.;Tilley, T. D.
  35. Adv. Organomet. Chem. Gauvin, F.;Harrod, J. F.;Woo, H.-G.
  36. Organometallics v.14 Woo, H.-G.;Kim, S.-Y.;Han, M.-K.;Cho, E. J.;Jung, I. N.
  37. Polym. Prepr.(Ama. Chem. Soc. Div. Polym. Chem.) v.33 Zou, W. K.;Yang, N.-L.
  38. Silicon-containing Polymers Devylder, N.;Molloy, K. C.;Price, G. J.;Jones, R. G.(Ed.)
  39. Organometallics v.11 Sita, L. R.
  40. J. Chem. Soc., Chem. Commun. Imori, T.;Tilley, T. D.
  41. J. Am. Chem. Soc. v.117 Imori, T.;Lu, V.;Cai, H.;Tilley, T. D.
  42. Polym. Prepr. (Am. Chem. Soc., Div. Polym, Chem.) v.36 no.2 Ding, Y.;Corey, J. Y.
  43. Bull. Korean Chem. Soc. v.16 Woom H.-G.;Kim, S.-Y.;Kim, W.-G.;Cho, E. J.;Yeon, S. H.;Jung, I. N.
  44. Bull. Korean Chem. Soc. v.17 Woo, H.-G.;Song, S.-J.;You, H.;Cho, E. J.;Jung, I. N.
  45. Bull. Korean Chem. Soc. v.17 Woo, H.-G.;Song, S.-J.
  46. Bull. Korean Chem. Soc. v.18 Woo, H.-G.;J.-M. Park;Song, S.-J.;Yang, S.-Y.;Kim, I.-S.;Kim, W.-G.
  47. J. Am. Chem. Soc. v.74 Benkeser, R. A.;Landesman, H.;Foster, D. J.
  48. Chem. Ber. v.96 Amberger, E.
  49. Organometallics v.12 Corey, J. Y.;Huhmann, J. L.;Zhu, X.-H.
  50. Manuscript in preparation. Woo, H.-G.;Song, S.-J.;Harrod, J. F.
  51. Organometallics v.11 Woo, H.-G.;Freeman, W. P.;Tilley, T. D.
  52. J. Am. Chem. Soc. v.119 Newcomb, M.;Musa, O. M.;Martine, F. N.;Horner, J. H.
  53. J. Am. Chem. Soc. v.118 Fischer, J. M.;Piers, W. E.;Batchilder, S. D. P.;Zaworotko, M. J.
  54. Acc. Chem. Res. v.14 Walsh, R.
  55. J. Organomet. Chem. v.166 Jackson, R. A.
  56. Recl. Trav. Chim. Pays-Bas v.84 Creemers, H. M. J. C.
  57. J. Am. Chem. Soc. v.87 Sawyer, A. K.
  58. J. Organomet. Chem. v.369 Becker, B.;Corriu, R. J. P.;Guerin, C.;Henner, B. J. L.
  59. Polym. Perpr.(Am. Chem. Soc., Div. Polym. Chem.) v.28 no.1 Becker, B.;Corriu, R.;Guerin, C.;Henner, B.
  60. J. Organomet. Chem. v.400 Corriu, R. J. P.
  61. Bull. Korean Chem. Soc. v.17 Woo, H.-G.;Song, S.-J.;Cho, E. J.;Jung I. N.
  62. Ph.D. Thesis University of California at San Diego Woo, H.-G.
  63. J. Organomet. Chem. v.249 Aitken, C.;Harrod, J. F.
  64. Tetrahedron Letts. v.28 Curran, D. P.;Chang, C. T.
  65. J. Am. Chem. Soc. v.109 Curren, D. P.;Chen, M.-H.