Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Self-Crosslinkable Side-Chain Copolymer for Nonlinear Optical Application

  • Published : 1998.11.20
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Abstract

2-Tetrahydropyranyl methacrylate with a self-crosslinkable moiety was copolymerized with methyl methacrylate and 4-[(2-methacryloxyethyl)methylamino]-4'-nitrostilbene or 4-[(2-methacryloxyethyl)ethylamino]-4'nitroazobenzene to provide second-order nonlinear optical property. Glass transition temperatures (Tg of the copolymers are around 140 ℃. The copolymers were soluble in common organic solvents such as tetrahydrofuran (THF), cyclohexanone, and N,N-dimethylformamide (DMF). Poling was carried out at 140 ℃ for 20 min and identified with UV-Vis spectroscopy. Electro-optic coefficient (r33) of copolymer was 62 pm/V for polymer 2 at 633 nm, and relaxation did not remarkably occur due to the formation of a crosslinked network at 200 ℃ for 15 min.

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References

  1. Introduction to Nonlinear Optical Effects in Molecules and Polymers Prasad, P. N.;Williams, D. J.
  2. Nanlinear Optical and Electroactive Polymers Prasad, P. N.;Ulrich, D. R.
  3. Macromolecules v.21 Hampsh, H. L.;Yang, J.;Wongand, G. K.;Torkelson, J. M.
  4. Nonlinear Optical Properites of Organic and Polymeric Materials; ACS Sym. ER. Williams, D. J.
  5. Nonlinear ptical Properties of Organic molecules and Crystals Chemla, D. S.;Zyss, J.
  6. Chem. Mater. v.6 Becker, M. W.;Sapochak, L. S.;Ghosen, R.;Xu, C.;Dalton, L. R.
  7. Advances in Polymer Science Morgan, R. J.
  8. SPIE Proc. Nonlinear Opt. Mat. v.971 Hubbard, M. A.;Minami, N.;Ye, C. T.;Marks, J.;Yang, J.;Wong, G. K.
  9. USP 4,808,332
  10. Appl. Phys. Lett. v.56 Teng, C. C.;Mann, H. T.