Effect of Added Sugars on the Generation of Polyhydroxyalkylpyrazines during Toasting of Burley Tobacco Leaves

버어리엽의 열처리 과정에서 Polyhydroxyalkylpyrazine류 생성에 대한 당류 첨가의 영향

  • Published : 1997.12.01

Abstract

Nonvolatile polyhydroxyalkylpyrazines(PHAPs) are known to degrade volatile pyrazine compounds having positive aroma and sensory attributes during cigarette smoking. In this paper, the content of PHAPs in burley tobacco leaves toasted to different levels as temperature and time study were determined by high performance liquid chromatography, and was also investigated effects of added sugars, sucrose, glucose or fructose, on the generation of PHAPs during toasting. The addition of glucose or fructose as casing sauce in burley tobacco leaves resulted in significant increases, especially 2,6-deoxyfructosaBine from glucose added leaves and 2,5-deoxyfructosazint from fructose added leaves, in generation of PHAPs during toasting, while control and sucrose added leaves did not observed in generation of PHAPS. Formation rates of PHAPs in glucose or fructose added tobacco leaves, but not sucrose, showed a strong dependence on both toasting temperature and time.

Keywords

References

  1. 29th TCRC Analytical method for determination of pyrazine and alkyl pyrazines in shredded tobacco Bright, M. N.;T. M. Larson;C. I. Lewis
  2. J. Anal. Appl. pyrolysis v.13 Curie-point pyrolysis-capillary gas chromatography-mass spectrometry of polyhydroxyalkylpyrazines Hardt, R.;W. Baltes
  3. Rec. Adv. Tob. Sci. v.7 The role of tobacco leaf precursors in cigarette flavor Heckman, R. A.;M. F. Dube;D. Lynm;J. M. Rivers
  4. Koryo v.128 Tobacco leaf components and tobacco flavoring Kaneko, H.
  5. Rec. Adv. Tob. Sci. v.2 Nitrogen compounds of leaf and their relationship to smoking quality and aroma Leffinglell, J. C.
  6. J. Agric. Food Chem. v.44 Effect of roasting time and temperature on the generation of nonvolatile (polyhydroxyalkyl) pyrazine compounds in peanuts, as determined by high performance liquid chromatography Magaletta, R. L.;C. t. Ho
  7. TJI v.5 The casing and flavoring of cigarettes Samfield, M.
  8. Koryo v.170 no.6 Tobacco Sasaki, N.
  9. Agric. Biol. Chem. v.41 Thermal degradation products of several Amadori compounds Shigematsu, H.;S. Shibata;T. Kurata;H. Kato;M. Fujimaki
  10. Sci. Papers Cent. Res. Inst. Japan Tobacco & Salt Publ. Corp. v.120 Identification of polyhydroxypyrazines in tobacco leaves and tobacco flavor prepared by sugar-amine reasction Shigematsu, H.;H. Kitami
  11. Agric. Biol chem. v.37 Formation of deoxyfructosazine and its 6-isomer on the browning reaction between glucose and ammonia in weak acidic medium Tsuchida H.;M. Komoto;H. Kato;M. Fujimaki
  12. Agric. Biol Chem. v.39 Isolation of deoxyfructosazine and its 6-isomer from the nondialyzable melanoidin hydrolyzate Tsuchida H.;M. Komoto;H. Kato;M. Fujimaki
  13. Agric. Biol. Chem. v.40 Formation of deoxyfructosazine and its 6-isomer by the browning reaction between fructose and ammonium formate Tsuchida H.;S. Tachibana;K. Kitamura;M. Komoto
  14. Carbohydr. Res. v.67 Gas liquid chromatography and mass spectrometry of trimethylsilyl ethers and butaneboronate-trimethylsilyl derivatives of polyhydroxyalkyl-pyrazines Tsuchida, H.;K. Kitamura;M. Komoto