Adsorption of THMs and THM Precursors on Activated Carbon Fibers

섬유상활성탄에 의한 THMs 및 THMs 전구물질의 흡착특성

  • 한명호 (경북산업대학교 공과대학 공업화학과) ;
  • 이진식 (경북산업대학교 공과대학 공업화학과) ;
  • 윤이용 (관동대학교 공과대학 환경공학과)
  • Published : 1996.01.15

Abstract

Adsorption isotherms of three trihalomethanes(THMs: $CHCl_3$, $CHBrCl_2$ and $CHBr_2Cl$) and the other organics(p-chlorophenol and sucrose)on activated carbon fibers(ACFs) were measured. Adsorption capacities of the ACFs for these THMs were found to be comparable with or slightly larger than those of granular activated car bons(GACs) which have been widely used for trihalomethanes control in drinking water. Also, the breakthrough curve prediction was successfully carried out using a mathematical model on basis of the assumption that the adsorption equilibrium is instantaneously established when a THM solution contacts the ACF. In practice, THM removal from drinking water was investigated at water works using benchscale ACF adsorptJOn columns. The volume of water treated at a space velocity(SV) of about $100h^{-1}$ was approximately 40 l/g-ACF. The practical adsorption capacities of PCP and sucrose in column adsorption were in good agreement with those of theoretically calculated results using the batch adsorption measurments. And the saturation time model of these substrates in the columns was also agreed succesfully with practical measurments.

Keywords