Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Synthesis and Characterization of the New Functional Polymer ―Synthesis of Polymer Containing Phosphorus―

새로운 기능성 고분자의 합성 및 그 특성에 관한 연구(I) ―인 함유 고분자의 합성―

  • Moon, Byeong Hwa (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea) ;
  • Son, Tae Won (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea) ;
  • Lim, Sang Kyn (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea) ;
  • Koo, Kang (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea)
  • Published : 1996.11.01
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Abstract

Poly(4-morphonylphosphonate of bisphenol A) (PMPB) was synthesized by the interfacial polymerization of phosphonic dichloride, 4-morphonyl (PDCM) and bisphenol A in an aqueous-organic biphasic system. Synthesized polymer was found to be PMPB by using EA, FT-IR and $^{1}$H-NMR. Prepared PMPB had different values of molecular weight depending on the solubility in the organic phase: the higher the solubility, the higher the molecular weight. PMPB is amorphous and its thermal decomposition temperature is about 35$0^{\circ}C$. PMPB is congenial to application to polypropylene by blending because of no reaction with polypropylene.

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References

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