Changes of chemical constituents in extract of Lycii fructus by various heat treatment

가열처리(加熱處理)에 따른 구기자(枸杞子) 추출물(抽出物)의 성분변화(成分變化)

Fundamental data for new type of product development from Lycii fructus was experimentally determined. The chemical composition, and Hunter value changes, optimum extraction, volatile components of extract under different extraction conditions and heat treatment were mainly studied. Results are summarized as follows. The proximate compositions of dried Lycii fructus were water 21.8%, total sugar 27.6%, reducing sugar 15.2%, crude protein 14.29%, crude fat 5.65%, crude fiber 7.48%, and ash 7.98% in percent stale, respectively. Extracted yield on the basic of solid extract was getting increased when more solvent was used for extraction. The most recommendable extraction was 1 to 10 part of sample to solvent ratio. When water was employed as extraction solvent, the highest amount of solid extract was obtained. Extract of Lycii fructus in terms of yields and color was most acceptable when raw sample was treated 8 minute roasting at $180^{\circ}C$ and 60 minute heating at $120^{\circ}C$, respectively. Major volatile components of fresh Lycii fructus were to hexadecanoic acid, methyl linoleate, benzyl alcohol, dimetane benzene by GC/MS. By the roasting of raw sample, the compounds of 2-methyl-2buthenal, 1,4-dimethyl benzene, and benzyl alcohol were reduced. Wheras, methyl thiopropanol, benzene acetaldehyde and ethyl linoleate were slightly increased.

구기자 음료의 풍미 개선을 위하여 구기자를 가열 및 볶음 처리하여 추출물을 제조하고, 추출물의 성분, 색도, 향기성분을 분석하여 다음과 같은 결과를 얻었다. 1. 건조구기자의 성분은 수분 21.8%, 전당 27.6%, 환원당 15.2% 조단백질 14.3% 조지방 5.7%, 조섬유 7.5%, 회분 8.0% 이었다. 2. 추출물의 고형물을 기준으로 추출수율은 건조 구기자와 용매비를 높임에 따라 증가하였다. 3. 건조구기자 추출물 제조에 있어 고형물은 물추출이 가장 높았고, ethanol의 농도를 높임에 따라 감소하였다. 4. 구기자는 $140^{\circ}C$에서 8분간 볶음처리하고 $120^{\circ}C$에서 1시간 가열 처리 하였을 때 수율, 색도 등에 있어서 가장 양호 하였다. 5. 생구기자의 향기성분은 hexadecanoic acid, methyl linoleate, benzyl alcohol, dimethal benzene 이었으며 가열 및 볶음처리에 의하여 2-methyl-2-butenal, 1.4-dimethyl-benzene, benzyl alcohol 등은 감소 하였고 methyl thiopropanol, benzene acetaldehyde, ethyl linoleate는 증가 하였다.