Alatemin, Cassiaside and Rubrofusarin gentiobioside, Radical Scavenging Priniciples from the Seeds of Cassia tora on 1,1-Diphenyl-2-picrylhydrazyl(DPPH) Radical

  • Choi, Jae-Sue (Dept. of Nutrition and Food Science, National Fisheries University of Pusan) ;
  • Lee, Hee-Jung (Dept. of Nutrition and Food Science, National Fisheries University of Pusan) ;
  • Kang, Sam-Sik (Natural Products Research Institute, Seoul National University)
  • Published : 1994.12.01

Abstract

Radical scavenging principles on 1, 1-diphenyl-2-picylhydrazyl(DPPH) radical were isolated from the seeds of Cassis tora L. Assignments of the^1H-{\;}and{\;}^{13}C-NMR$ data showed the active components to be an anthraquinone, alatemin nad two naphthopyrone glycosides, nor-rubro-fusarin-6-.betha.-D-glucoside(cassiaside) and rubrofusarin-6- -D-gentiobioside. Altemin showed more potent radical sacvenging effect than the others.

Keywords

References

  1. Nature v.181 Antioxidant determination by the use of a stable free radical Blois,M.S.
  2. Aust. J. Chem. v.19 Chemical constituents of Eriococcus confusus Maskell Ⅰ. The quinoid pigments Chan,A.W.K.;Crow,W.D.
  3. Kor. J. Pharmacogn. v.24 no.4 Screening for anitioxidant activity of plants and marine algae and its active principles from Prunus davidiana Choi,J.S.;Lee,J.H.;Park,H.J.;Kim,H.G.;Young,H.S.;Mun,S.I.
  4. Free Radicals in biology v.6 Antioxidants, aging, and longevity Cutler,R.C.;Pryor,W.A.(ed.)
  5. Magn. Reson. Chem. v.30 NMR study of some anthraquinones from Rhubarb Danielsen,K.;Aksnes,D.W.;Francis,G.W.
  6. Chem. Pharm. Bull. v.17 no.3 Chemical studies on the oriental plant drugs.XXI. The constituents of Cassia tora L(2). A glycoside of rubrofusarin Kaneda,M.;Morishita,E.;Shibata,S.
  7. Chem. Pharm. Bull. v.40 no.5 The mutagenic constituents of Rubia tinctorum Kawasaki,Y.;Goda,Y.;Yoshihira,K.
  8. Yakugaku Zasshi v.86 no.11 Studies on the constituents of the seeds of Cassia obtusifolia L. Ⅳ. The structure of new glucoside, cassiaside(nor-rubrofusarin-6-β-glucoside) Kimura,Y.;Takido,M.;Takahashi,S.
  9. Colored Illustrations of Wakan-Yaku v.1 Namba,T.
  10. Indian J. chemistry v.12 Chrysophanol-1-β-gentiobioside, a new anthraquinone glycoside from Cassia tora Linn Raghunathan,K.;Hariharan,V.;Rangaswami,S.
  11. Planta Medica v.42 A new investigation on the composition of Rhamni cathartici cortex(buckthorn bark). 1. Phytochemical investigation of anthraquinone aglycones Rauwald,H.W.;Just,H.D.
  12. Proc. Nutr. Soc. v.46 Slater,T.F.;Cheeseman,K.H.;Davies,M.J;Proudfoot,K.;Xin,W.
  13. Chem. Pharm. Bull. v.8 no.3 Studies on the constituents of the seeds of Cassia obtusifolia L. Ⅱ. The structure of obtusin, chryso-obtusin, and aurantio-obrusin Takido,M.
  14. JCS(Perkin Ⅰ) ¹³C Nuclear magnetic resonance spectra of glucobioses, glucotrioses, and glucans Ushi,T.;Yamaoka,N.;Matsuda,K.;Tuzimura,K.;Sugiyama,H.;Seto,S.
  15. Med. Sci. Res. v.15 Condensed tannins scavenge active oxygen free radicals Ushida,S.;Edamatsu,R.;Hinamatsu,M.;Mori,A.;Nonaak,G.;Nishioka,I.;Niwa,M.;Ozaki,M.
  16. Phytochemistry v.28 no.1 Anthraquinone glycosides from the seeds of Cassia tora Wong,S.M.;Wong,M.M.;Seligmann,O.;Wagner,H.
  17. Planta Medica v.55 New antihepatotoxic naphtho-pyrone glycosides from the seeds of Cassia tora Wong,S.M.;Wong,M.M.;Seligmann,O.;Wagner,H.
  18. Chem. Pharm. Bull. v.37 no.7 Studies on inhibition mechanism of antioxidation by tannis and flavonoids. V. Radical-scavenging effects of tannins and related polyphenols on 1,1-diphenyl-2-picrylhydrazyl radical Yoshida,T.;Mori,K.;Hatano,T.;Okumura,T.;Uehara,I.;Komagoe,K.;Fujita,Y.;Okuda,T.
  19. Kor. J. Pharmacogn. v.8 Plants with liver protective activities(Ⅰ) Yun,H.S.;Chang,I.M.