Applied Biological Chemistry
- 제37권3호
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- Pages.189-193
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- 1994
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- 2468-0834(pISSN)
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- 2468-0842(eISSN)
항균성, N-[1-(benzotriazol-1-yl)benzyl]aniline의 가수분해 반응에 미치는 미셀 촉매효과
Micellar Catalysis on the Hydrolysis of the Fungicidal N-[1-(benzotriazol-1-yl)benzyl]aniline
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Sung, N.D.
(Department of Agricultural Chemistry, Chungnam National University) ;
- Park, C.K. (Department of Agricultural Chemistry, Chungnam National University) ;
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Lim, C.W.
(Department of Agricultural Chemistry, Chungnam National University)
- 발행 : 1994.06.30
초록
이온성 계면활성제인 sodium laurylsulfate(NaLs)와 cetyltrimethylammonium bromide(CTABr)의 존재하에서 항균성 N-[1-(benzotriazol-1-yl)benzyl]aniline(BBA)분자의 가수 분해 반응에 미치는 미셀효과를 검토한 바, NaLs가 존재하는 높은 pH에서 미셀 촉매효과가 나타났으며 결합상수(Ks)는
The hydrolysis of fungicidal N-[1-(benzotriazol-1-yl)benzyl]aniline (BBA) molecule in the presence of cationic cetyltrimethylammonium bromide (CTABr) and anionic sodium laurylsulfate (NaLs) micellar solutions has been studied kinetically. The Micellar catalysis effect shows that the rate is slightly accelerated by the addition of the anionic NaLs at high pH and the binding constant (Ks) is