Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Radical Polymerization of Methyl Methacrylate with Tricaprylmethylammonium Chloride

Tricaprylmethylammonium Chloride에 의한 Methyl Methacrylate의 라디칼 중합

  • Park, Sang-Wook (Dept. of Chem. Eng., College of Eng., Pusan National University) ;
  • Moon, Jin-Bok (Dept. of Chem. Eng., College of Eng., Pusan National University) ;
  • Ha, Yoo-Su (Dept. of Chem. Eng., College of Eng., Pusan National University) ;
  • Kim, Jong-Hyeon (Dept. of Chem. Eng., Dong Sae College of Eng.)
  • 박상욱 (부산대학교 공과대학 화학공학과) ;
  • 문진복 (부산대학교 공과대학 화학공학과) ;
  • 하유수 (부산대학교 공과대학 화학공학과) ;
  • 김종현 (동서공과대학 화학공학과)
  • Received : 1992.11.21
  • Accepted : 1993.03.15
  • Published : 1993.05.01
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Abstract

The phase-transfer polymerization of methyl methacrylate with tricaprylmethylammonium chloride-$Na_2S_2O_4-CCl_4$ initiator system was investigated in an aqueous-organic two-phase system. The observed rates of polymerization were compared with those obtained from the polymerization mechanism proposed with a cyclic phase-transfer initiation step. The rate of polymerization was found to be proportional to the concentration of $Q^+$ and square root of ${S_2O_4}^{-2}$ in the aqueous solution and the feed quantity of $CCl_4$ and MMA.

$Na_2S_2O_4$ 수용액과 $CCl_4$-toluene 용액의 2상에서 유기상에 용해하는 tricaprylmethylammonium chloride 상이동 촉매를 사용하여 methyl methacrylate의 라디칼 중합속도를 측정하여, 액-액 불균일계 접촉계면을 통한 라디칼 중합반응기구를 해석하였다. MMA의 중합속도는 수용액상에 존재하는 $Q^+$ 이온의 농도와 ${S_2O_4}^{-2}$ 이온의 농도의 제곱근에 정비례하고 $CCl_4$와 MMA의 농도에 각각 정비례하였다.

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Acknowledgement

Supported by : 한국과학재단