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Study of the Optimization and the Depth Profile Using a Flat Type Ion Source in Glow Discharge Mass Spectrometry

  • Woo Jin Chun (Inorganic Analytical Chemistry Lab., Korea Research Institute of Standards and Science) ;
  • Kim, Hyo Jin (Department of Pharmacy, Dong Duck Women's University) ;
  • Lim Heoung Bin (Inorganic Analytical Chemistry Lab., Korea Research Institute of Standards and Science) ;
  • Moon Dae Won (Inorganic Analytical Chemistry Lab., Korea Research Institute of Standards and Science) ;
  • Lee Kwang Woo (Inorganic Analytical Chemistry Lab., Korea Research Institute of Standards and Science)
  • Published : 1992.12.20

Abstract

The analytical performance of glow discharge mass spectrometer (GD-MS), using a flat type ion source is discussed. The efficiency of ion extraction was maximized at the distance between anode and cathode of 6 mm. At the operation condition of 4 mA, -1000 volt, and 1 mbar for the source, the optimum voltages for sampler and skimmer were40 volt and -280 volt, respectively. The intensities of Cu, Zn, and Mn were increased as a function of square root of current approximately. Korea standard reference materials (KSRM) were tested for an application study. The detection limits of most elements were obtained in the range of several ppm at the optimized operating condition. The peaks of aluminum and chromium were interfered by those of residual gases. The depth profile of nickel coated copper specimens (3, 5, 10 ${\mu}m$ thickness) were obtained by plotting time versus intensities of Ni and Cr after checking the thickness of nickel coated using a scanning electron microscope (SEM). At this moment, the sputtering rate of 0.2 ${\mu}m/min$ at the optimum operating condition was determined from the slope of the plot of time to the coating thickness. The roughness spectra of specimen's crater after 16 min, discharge were obtained using a Talysuf5m-120 roughness tester as well.

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