Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Infrared Multiphoton Dissociation of ${CF_2}HCl$: Laser Fluence Dependence and the Effect of Intermolecular Collisions

  • Song, Nam-Woong (Department of Chemistry, Seoul National University) ;
  • Shin, Kook-Joe (Department of Chemistry, Seoul National University) ;
  • Lee, Sang-Youb (Department of Chemistry, Seoul National University) ;
  • Jung, Kyung-Hoon (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Choo, Kwang-Yul (Department of Chemistry, Seoul National University) ;
  • Kim, Seong-Keun (Department of Chemistry, Seoul National University)
  • Published : 1991.12.20
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Abstract

The effect of intermolecular collisions in the infrared multiphoton dissociation (IRMPD) of difluorochloromethane was investigated using He, Ar, and $N_2$ as buffer gases. The reaction probability for IRMPD of difluorochloromethane was measured as a function of laser fluence and the buffer gas pressure under unfocused beam geometry. It was observed that the reaction probability was initially enhanced with the increase of buffer gas pressure up to about 20 torr, but showed a decline at higher pressures. The reaction probability increases monotonically with the laser fluence, but the rate of increase diminishes at higher fluences. An attempt was made to simulate the experimental results by the method of energy grained master equation (EGME). From the parameters that fit the experimental data, the average energy loss per collision, $<{\Delta}E>_d$, was estimated for the He, Ar, and $N_2$ buffer gases.

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