Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Ruthenium Catalyzed Synthesis of 1-Substituted Perhydroazocines from Primary Amines and 1,7-Heptanediol

  • Shim, Sang-Chul (Department of Industrial Chemistry, Kyungpook National University) ;
  • Doh, Chil-Hoon (Department of Industrial Chemistry, Kyungpook National University) ;
  • Yoon, Jeum-Ho (Department of Industrial Chemistry, Kyungpook National University) ;
  • Lee, Dong-Yub (Department of Industrial Chemistry, Kyungpook National University) ;
  • Youn, Young-Zoo (Department of Industrial Chemistry, Kyungpook National University)
  • Published : 1991.12.20
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Abstract

The reaction of primary aromatic amines with 1,7-heptanediol in the presence of a catalytic amount of ruthenium complex in dioxane at $180^{\circ}C$ for 24 hours gave the corresponding 1-substituted perhydroazocines in moderate yield.

Keywords

References

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Cited by

  1. ChemInform Abstract: Ruthenium-Catalyzed Synthesis of 1-Substituted Perhydroazocines from Primary Amines and 1,7-Heptanediol. vol.23, pp.22, 1991, https://doi.org/10.1002/chin.199222201
  2. Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles vol.110, pp.3, 2010, https://doi.org/10.1021/cr9002159