Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

The Structure of Ligand, N-benzylisonitrosoacetylacetone Imine

리간드 N-Benzylisonitrosoacetylacetone Imine의 구조

  • Byung Kyo Lee (Department of Materials Science and Engineering, Kyungpook National Universtiy) ;
  • Dae Sub O (Department of Chemistry, Kyungpook National University) ;
  • Heung Lark Lee (Department of Chemistry, Kyungpook National University)
  • Published : 1988.12.20
Download PDF
⟨ Previous Next ⟩

Abstract

In order to study the changes for the structure of N-benzylisonitrosoacetylacetone imine synthesized already in organic solution, nmr and carbon-13nmr DEPT spectra of the this reagent have been studied. Based on the present studies, it is suggested that this reagent is monoxime having syn- and anti-form isomers and has tautomers in solution respectively.

이미 합성된 N-benzylisonitrosoacetylacetone $imine^1$의 유기용매내에서의 구조변화를 측정하기 위하여 여러가지 유기용매에서의 핵자기공명스펙트럼 및 Carbon-13 핵자기공명 DEPT 스펙트럼 등의 분광학적인 자료를 이용하였다. 그 결과 이 시약은 monoxime의 일종으로 용매 중에서 syn- 형과 anti- 형의 기하이성질체가 공존하고 있으며 각각이 토우토메리 현상을 일으키고 있다.

Keywords

References

  1. J. Kor. Chem. Soc. v.30 no.2 B. K. Lee;D. S. O;H. L. Lee
  2. Ann. v.325 L. Wolff;P. Bock;G. Lorantz;P. Trappe
  3. Beilstein Handbuch der Organishe Chemie;Band Ⅰ
  4. Anal. Chem. v.38 U. B. Talwar;B. C. Haldar
  5. Chem. Ind. C. Djordjevic;J. Lewis;R. S. Nylholm
  6. Chem. Ind. C. Djordjevic;J. Lweis;R. S. Nylholm
  7. Tetrahedron Lett. K. G. Das;D. N. Sen;n. Thankaranjan
  8. Russ. J. Inorg. Chem. v.13 A. V. Ablov;V. N. Zubarev
  9. Aust. J. Chem. v.23 M. J. Lacey;C. C. Patel;J. S. Channon;P. J. Collin
  10. Inorg. Chem. v.12 K. S. Bose;B. C. Sharma;C. C. Patel
  11. Chem. Comm. M. J. Lacey;C. G. Macdonald
  12. J. Kor. Chem. Soc. v.22 M. H. Lee;D. S. O;K. W. Lee
  13. J. Kor. Chem. Soc. v.26 D. S. O;M. H. Lee;S. H. Kim;J. H. Park;H. W. Lee
  14. J. Am. Chem. Soc. v.77 P. J. MacCarthy;R. J. Hovey;K. Ueno;A. E. Martell
  15. J. Am. Chem. Soc. v.80 H. F. Holtzclaw, Jr.;J. P. Collman;P.M. Alire
  16. J. Am. Chem. Soc. v.81 R. J. Hovey;J. J. Oconnell;A. E. Martell
  17. J. Inorg. Nucl. Chem. v.40 H. J. Harries;G. P. Parry;J. Burgess
  18. J. Inorg. Chem. v.29 N. J. Patel;B. C. Haldar
  19. J. Inorg. Chem. v.32 U. B. Talwar;B. C. Haldar
  20. J. Ind. Chem. Soc. S. B. Khatavkar;B. C. Haldar
  21. Spect. Acta. v.26 no.A A. Bigotto;G. Costa;V. Galasso;G. DeAlti
  22. Spect. Acta. v.27 no.A A. Bigotto;V. Galasso;G. De Alti
  23. J. Am. Chem. Soc. v.83 H. H. Freeman
  24. J. Inorg. Nucl. Chem. v.43 M. M. Aly;F. A. El-SAID
  25. J. Am. Chem. Soc. v.78 B. Witkop
  26. J. Am. Chem. Soc. v.101 O. Yamaguchi;T. Saknrai;A. Nakahara
  27. J. Am. Chem. Soc. v.58 O. R. Wulf;U. Liddeland;S. B. Hendricks
  28. J. Chem. Soc. R. Blinc;D. Hadzi
  29. J. Iorg. Nucl. Chem. v.27 K. Bruger;I. Ruff;F. Ruff
  30. Carbon-13 NMR Spectroscopy G. C. Levy;R. L. Lichater;G. L. Nelson
  31. J. Am. Chem. Soc. v.84 G. J. Karabatsos;J. D. Graham;F. M. Vane
  32. J. Am. Chem. Soc. v.85 G. J. Karabatsos;R. A. Taller
  33. J. Am. Chem. Soc. v.79 C. E. Looney;W. D. Phylips;E. L. Railly
  34. Bull. Chem. Soc. Jap. v.49 H. Kuma;J. Yamada
  35. Bull. Chem. Soc. Jap. v.42 I. Masuda;M. Tamaki;K. Shinra
  36. J. Chem. Soc. R. J. W. Le Fevre;H. Welsch
  37. J. Chem. Soc. R. J. W. Le Fevre;H. Welsch
  38. J. Chem. Soc. R. J. W. Le Fevre;H. Welsch