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A Study on the High Resolution Infrared Spectra of an Asymmetric Top Molecule $CF_2Cl_2$

  • Published : 1988.10.20

Abstract

The high resolution IR spectra of freon-12($CF_2Cl_2$) for the bands of 671cm$^{-1},\;922cm^{-1},\;1102cm^{-1},\;and\;1160cm^{-1}$ were taken and the rotational vibrational analysis has been carried out. The band types of $671cm^{-1}\;and\;1102cm^{-1}$ were confirmed to be A and those of $922cm^{-1}\;and\;1160cm^{-1}$ were confirmed to be B. The theoretically synthesized spectra were matched with the experimentally obtained spectra to get some informations of the molecular rotational behavior as well as the overall band shape of the spectra.

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References

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  1. The structure of solid dichlorodifluoromethane CF2Cl2by powder neutron diffraction vol.197, pp.1, 1988, https://doi.org/10.1524/zkri.1991.197.1-2.121
  2. High-resolution FTIR–jet spectroscopy of CCl2F2 vol.90, pp.8, 1988, https://doi.org/10.1039/ft9949001055