Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Halogenation of Resorcinol Derivatives

  • 백승화 (원광대학교 자연과학대학 화학과)
  • Published : 1988.02.20
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Abstract

Several types of resocinols have been monobrominated in the ring in good yields with sodium bromide in the presence of 18-crown-6 on oxidation with m-chloroperbenzoic acid. Monoiodination takes place with 2'-(1-methylcyclohexen-3-yl)-5-(1,1-dimethylheptyl )-resocinol when sodium iodide is employed. This new reagent system, MX/18-crown-6/m-CPBA (M =$K^+, Na^+, X = Br^-, I^-X$ ), effects the regiospecific halogenation of activated aromatic ring over olefinic double bond.

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References

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Cited by

  1. ChemInform Abstract: Halogenation of Resorcinol Derivatives. vol.19, pp.35, 1988, https://doi.org/10.1002/chin.198835108