Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Nature of the Intrinsic Barrier in Methyl Transfer Reactions

  • 이익준 (인하대학교 이과대학 화학과) ;
  • 송창현 (인하대학교 이과대학 화학과)
  • Published : 1988.02.20
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Abstract

The intrinsic barrier in the methyl transfer reaction $X^- + CH_3X \rightleftharpoons XCH_3 + X^-$ has been shown to vary quadratically with the C-X distance d; linear dependence of the intrinsic barrier on the deformation energies or methyl cation affinities of the substrate, $CH_3X$, should therefore hold only approximately in a narrow range of structural variations in X.

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References

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