Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Palladium-Catalyzed Cross-Coupling Reaction of (E)-1-Alkenyl-1,3,2-benzo-dioxaboroles with Allylic Phenoxides. A Simple Route 1,4-Alkadienes from Alkynes via Hydroboration$^\dag$

  • Sasaya Fumihito (Department of Applied Chemistry, Faculty of Engineering) ;
  • Norio Miyaura (Department of Applied Chemistry, Faculty of Engineering) ;
  • Akira Suzuki (Department of Applied Chemistry, Faculty of Engineering)
  • Published : 1987.08.20
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Abstract

The reaction of (E)-1-alkenyl-1,3,2-benzodioxaboroles with a variety of allylic phenoxides in the presence of a catalytic amount of Pd$(PPh_3)_4$ is described. The reaction affords a general and simple procedure for the preparation of 1,4-alkadienes from alkynes via hydroboration.

Keywords

References

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