The Hydration of Hardenced Flyash-$Ca(OH)_2-CaSO_4$.$2H_2O$ System

Flyash-$Ca(OH)_2-CaSO_4$.$2H_2O$계의 수화반응

  • 김창은 (연세대학교 공과대학 요업공학과) ;
  • 이승헌 (연세대학교 공과대학 요업공학과) ;
  • 이상완 (연세대학교 공과대학 요업공학과) ;
  • 김원기 (연세대학교 공과대학 요업공학과)
  • Published : 1986.03.01

Abstract

The hydration of flyash-$Ca(OH)_2-CaSO_4$.$2H_2O$ system was stuedied with varing mixing ratio of flyahs $Ca(OH)_2$ and caSO4.2H2O The samples were steam-cured for 1-7 days at 9$0^{\circ}C$. The optimum mixing composition was flyash : Ca (OH)2=65:35 with 15% $CaSO_4$.42H_2O$ added which produced the hardened material having the best compressive strength (300kg/$cm^2$) Also the low specific gravity(1, 2) of the hardened paste suggests the possibility that it can be used as a light-weight building material. The added $CaSO_4$.42H_2O$ constituted calcium-sulfo-aluminate hydrates which activates the formation of C-S-H hy-drates. Both hydrates developed the strength of hardened paste. The amount of calcium-sulfo-aluminate hydrates was increased when the $CaSO_4$.42H_2O$ was added over 15% however the increased amount did not help the development of strength because of the individually grown calcium-sulfo-aluminate hydrates.

Keywords

References

  1. ASTM C593-769 Flyash and Other Pozzolans for Use with Lime
  2. Cem. Conc. Res. v.14 An Examination of the ASTM Lime Pozzolanic Activity Test for Class C Flyashes S. Schlorholtz;T. Demirel;J.M. Pitt
  3. Cem. Cone. Res. v.13 Low Temperatures Steam Curing Hydration of Lime-Flyash Compacts A. Marcialis;L. Massidda;U. Sanna
  4. Ceram. Bull. v.52 no.5 Pozzolanic Activity in Synthetic Flyashes R.C. Joshi;E.A. Rosauer
  5. Gypsum and Lime v.179 Steam and Autoclave Curing of Blast Furnace Slag- Gypsum-Slaked Lime Cement C. Tashiro;Y. Okubo
  6. Gypsum & Lime v.147 Compressive Strength and hardened Cement Paste of the System of Blast Furnace Slag-Gypsum Slaked Lime C. Tashro;Y. Okubo
  7. CAJ Review of the 37th General Meeting Strength and Surface Deterioration of Slag-Gypsum Cement Concrete T. Uomoto;T. Hoshino
  8. CAJ Review of the 36th General Meeting Hydration of Flyash in Presence of Gypsum M. Daimon;G.S. Seishi
  9. CAJ Review of the 37th General Meeting Hydrothermal Reaction and Hardening Properties of Flyash N. Inoue;S.T. sunematsu;W. Hara
  10. Zementcheme fur Bauingemeure(2nd edition) Wolfgang;Czernin
  11. The Chemistry of Cements(3rd printing) H.F.W. Taylor
  12. J. Amer. Ceram. Soc. v.58 no.3-4 Thermal study of the Effect of Additives on the Hydration of Tricalcium Silicate L. Bendor
  13. Gypsum & Lime v.186 Introduction to Experimental Solid State Chemistry M. Daimon;S. Ohsawa