Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Catalysis by the Fe(Ⅲ) Complex of N-Dodecyl-3,4-dihydroxybenzamide in the Hydroxylation of Anisole with Hydrogen peroxide$^*$

  • Published : 1985.06.20
Download PDF
⟨ Previous Next ⟩

Abstract

Hydroxylation of anisole with $H_2O_2$ was investigated by employing Fe(III) ion and N-dodecyl-3,4-dihydroxybenzamide (DDHB) as a catalyst. The study was aimed at obtaining an insoluble catalyst with a long catalytic life, in view of the inactivation of the catechol portion of the catalyst during the reaction. The rate of decomposition of $H_2O_2$ under various conditions indicated that the reaction proceeds through the catalytic participation of $Fe(III){\cdot}DDHB$. Yield of the hydroxylation products under various conditions revealed that $Fe(III){\cdot}DDHB$ is not inactivated during the reaction.

Keywords

References

  1. J. Am. Chem. Soc. v.101 B. Siegal;J. Lanphear
  2. J. Am. Chem. Soc. v.88 G. A. Hamilton;J. P. Friedman;P. M. Patrick
  3. J. Am. Chem. Soc. v.88 G. A. Hamilton;J. W. Hanifin, Jr.;J. P. Friedman
  4. Mechanism of Homogeneous Catalysis from Protons to Proteins M. L. Bender
  5. Bull. Korean Chem. Soc. v.1 J. Suh;K. Y. Kim
  6. M. S. Thesis, Seoul National University K. Y. Kim
  7. J. Chem. Soc., (B) C. R. E. Jefcoate;J. R. L. Smith;R. O. C. Norman
  8. Colorimetric and Fluorimetric Analysis of Organic Compounds and Drugs M. Pesez;J. Bartos
  9. CA. v.75 M. Zemcikova