Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Separation and Elution Behavior of Cations Based on Distribution Coefficients

분포계수를 토대로한 양이온의 용리현상 및 분리

  • Dong Won Kim (Department of Chemistry, Chungbuk National University) ;
  • Song Reck Park (Department of Chemistry, Kongju National Teacher's College) ;
  • Yong Whan Kang (Department of Chemistry, Kongju National Teacher's College) ;
  • Nam Kee Rhee (Department of Chemistry, Teacher's College, Chungbuk National University)
  • 김동원 (충북대학교 자연과학대학 화학과) ;
  • 박성록 (공주사범대학 화학과) ;
  • 강용환 (공주사범대학 화학과) ;
  • 이남기 (충북대학교 사범대학 화학과)
  • Published : 1980.10.30
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Abstract

Distribution coefficients of various elements with the strong acidic caion-exchanger, Dowex 50W-x8, 100∼200 mesh were investigated in various concentrations of succinic, hydrochloic acid and it's mixture. Based on these distribution coefficients,the experimental condition for their quantitative separation of those elements is established in 0.9 M hydrochloric acid as eluent, several examples of successful separations are described and the dependence of distribution coefficients on ionic radius is also discussed.

용리액으로 염산과 숙신산 및 그들의 혼합액을 사용하고, 강산성 양이온 교환수지, Dowex 50W-x8, 100∼200 mesh 를 사용하여 금속, Mg(Ⅱ), Ca(Ⅱ), Sr(Ⅱ), Ba(Ⅱ), Cr(Ⅲ), Mn(Ⅱ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), Cd(Ⅱ), Hg(Ⅱ) 및 Pb(Ⅱ)의 이온들에 대한 분포계수를 측정하였다. 분리도와 양이온의 전하와의 관계를 고찰하였고, 이온반지름에 따른 분포계수를 비교하였다. 특히 0.9M 염산용액에서 Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ)의 완전분리가 가능하였다.

Keywords

References

  1. Anal. Chim. Acta. v.36 R. Christova;A. Kruschevska
  2. Z. Anal. Chem. v.219 K. H. Lieser;H. Bernhard
  3. Anal. Chem. v.34 J. S. Fritz;B. B. Garralda
  4. Anal. Chem. v.37 J. Korkisch;F. Feik
  5. Anal. Chem. v.37 J. S. Fritz;J. E. Abbink
  6. J. of Chromatography v.108 J. M. Peters;G. Del Fiore
  7. Anal. Chem. v.34 J. S. Fritz;T. A. Retting
  8. J. Chromatog. v.25 F. Nelson;D. C. Michelson
  9. Talanta v.14 J. Korkisch;S. S. Ahluwalia
  10. Talanta v.15 J. Korkisch;A. Huber
  11. Progress in Chem. and Chemical Industry v.17 D. W. Kim
  12. J. of Kongju Nat. Teacher's College v.15 D. W. Kim
  13. J. of Kongju Nat. Teacher's College v.16 D. W. Kim
  14. Quantitative Analytical, Chemistry M. Y. Lee(et al.)
  15. Quantitative Analytical Chemistry K. C. Park
  16. Problems and Experiments in Industrial Analysis E. Clifton(et al.)
  17. Die Komplexometrisch Titration, Ferdinand Enke Verlag v.Bd. 45 G. Schwarzenbach;H. Flaschka
  18. Analytical Chemistry C. R. Joo
  19. キレ―ト滴定法 上野景平
  20. Anal. Chem. v.43 F. W. E. Strelow;A. H. Victor;C. R. Van Zyl;Cythia Eloff
  21. Dissertation Univ. Innsbruck D. W. Kim
  22. Analytical Chemistry D. A. Skoog;D. M. West
  23. Coordination Chemistry F. Basolo;R. Johnson;S. J. Kim(tr.)
  24. Inorganic Chemistry T. Moeller
  25. Electron Theory and chemical Reaction M. T. Shim;K. S. Lee
  26. Inorganic Chemistry T. Moeller
  27. Analytical Chemistry D. A. Skoog;D. M. West
  28. Inorganic Chemistry T. T. Moeller
  29. Encyclopedia of Physics & Chemistry Chang Won Sa
  30. Advanced Inorganic Chemistry F. A. Cotton;G. Wilkinson
  31. The Nature of The Chemical Bond L. Pauling