Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Platinum(II) Complexes Containing Glycine and Styrene

글리신 및 스티렌의 백금(Ⅱ) 착물

  • Jun Moo Jin (Department of Applied Chemistry, Kyungpook National University) ;
  • Peter P. Fu (Department of Applied Chemistry, Kyungpook National University)
  • 전무진 (경북대학교 공과대학 응용화학과) ;
  • 피터후 (경북대학교 공과대학 응용화학과)
  • Published : 1977.06.30
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Abstract

Several Pt(II) complexes containing glycine (or glycino anion) and styrene have been prepared, and their structures have been confirmed by infrared spectroscopy. The results confirm the structure of chloro(glycino)(styrene)platinum(II) in which the nitrogen atom of the chelated glycino anion is coordinated to the platinum in the trans position to styrene (N-trans isomer).

Glycine (또는 glycino 음이온)과 styrene을 리간드로 하는 백금(II) 착물이 합성되었다. 적외선 분광법에 의하면 N-트란스 이성체에서는 킬레이트를 이루는 glycine음이온의 질소원자가 styrene에 대하여 트란스 위치에 있음이 확인되었다.

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References

  1. J. Inorg. Nucl. Chem. v.30 J. A. Kieft;K. Nakamoto
  2. Inorg. Chem. v.9 J. Fujita;K. Konya;K. Nakamoto
  3. Inorg. Syn. v.5 J. Chatt;M.L. Stearle
  4. J. Chem. soc. J. S. Anderson
  5. J. Inorg. Nucl. Chem. v.29 J. A. Kieft;K. Nakamoto
  6. J. Amer. Chem. Soc. v.88 M. J. Grogan;K. Nakamoto
  7. Ph. D. Thesis, Ⅲ. Inst. Tech.(U.S.A.) G. T. Behnke
  8. Ph. D. Thesis, Ⅲ. Inst. Tech.(U.S.A.) M. J. Grogan
  9. Acta Chem. Scand. v.20 J. W. Moore
  10. Iza. Alad. SSSR, Ser. Khim. no.1 A. A. Grinberg;C.M. Volshtein
  11. J. Amer. Chem. Soc. v.77 D. N. Sen;S. Mizushima;C. Curran;J. V. Quagliano
  12. J. Amer. Chem. Soc. v.80 A. Sarceno;I. Nakagawa;S. Mizushima;C. Curran;J.V. Quagliano
  13. Acta. Chem. Scand v.10 A. Rosenberg
  14. Spectrochim. Acta v.20 J. T. Lane;J.A. Durkin;R. J. Hooper
  15. Zh. Neorg. Khim. v.8 Yu S. Varshauskii;E. N. Inkova;A. A. Grinberg
  16. J. Chem. Soc., (A) R.G. Denning;F.R. Hartley;L.M. Venanzi
  17. J. Chem. Soc. J. Chatt;G.A. Gamlen;L.E. Orgel
  18. J. Chem. Phys. v.42 P. Day;A.F. Orchard;A.J. Thomdosn;R.J.P. Williams