Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Kinetics of the Solvolysis of Benzyl Bromides in Alcohols

브롬화벤젠의 알코올에 의한 용매분해에 관한 반응속도론적 연구

  • Yong-Jin Lim (Department of Chemistry, Kyungpook National University) ;
  • Soo-Dong Yoh (Department of Chemistry, Kyungpook National University) ;
  • Soon-Yung Hong (Department of Chemistry, Kyungpook National University)
  • Published : 1971.10.30
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Abstract

The kinetics of the solvolysis of benzyl and p-or m-substituted benzyl bromides in various alcohols have been determined by an electric conductivity method. From these reactions, a curved Hammett plot is obtained and a mechanism is proposed to account for the nonlinear behavior observed. In addition, effects of solvent polarity on the activation parameters for the solvolysis of benzyl bromides are discussed.

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References

  1. J. Chem. Soc. J. W. Baker
  2. J. Am. Chem. Soc. v.70 C. G. Swain;R. W. Eddy
  3. J. Am. Chem. Soc. v.73 S. Winstein;E. Grunwald;H. Walter Jones
  4. J. Am. Chem. Soc. v.77 C. G. Swain;R. B. MoseIy;D. E. Bown
  5. J. Am. Chem. Soc. v.77 C. G. Swain;D. C. Dittmer;L. E. Kaiser
  6. J. Am. Chem. Soc. v.84 J. W. Hill;A. Fry
  7. J. Am. Chem. Soc. v.84 J. B. Hyne;R. Wills;R. E. Wonkka
  8. J. Am. Chem. Soc. v.84 B. L. Murr, Jr.;V. J. Shiner, Jr.
  9. Nature v.171 C. W. L. Bevan;E. D. Hughes;C. K. Ingold
  10. This Journal v.9 I. Lee
  11. University Journal, Pusan National University v.10 E. S. Lee;S. K. Lee
  12. Physical Organic Chemistry L. P. Hammett
  13. J. Am. Chem. Soc. v.73 C. G. Swain;W. P. Langsdorf, Jr.
  14. J. Am. Chem. Soc. v.81 R. Fuchs;A. Nisbet.
  15. J. Am. Chem. Soc. v.85 R. Fuchs;D. M. Carlton
  16. Bull. Soc. Chim. France v.4 R. Quelet;J. Allard
  17. This Journal v.13 S. D. Yoh;D. S. Lee;S. Y. Hong
  18. Phil. Mag. v.I E. A. Guggenheim
  19. Can. J. Chem. v.33 R. E. Robertson
  20. Progress in Phys. Org. Chem. v.2 C. D. Ritchie;W. F. Sager
  21. Solvolysis Mechanism E. R. Thornton
  22. J. Chem. Educ. v.48 J. O. Schreck
  23. J. Am. Chem. Soc. v.72 J. W. Hackett;H. C Thomas
  24. Mechanism and Structure in Organic Chemistry E. S. Gould
  25. Kinetics and Mechanism A. A. Frost;R. G. Pearson