Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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(Part 2) 2-Chloro-1-Propanol

(第2報) 2-Chloro-1-Propanol 에 關하여

  • Kim, Ho-Jing (Dept. of Chemistry, The Johns Hopkins Univ.) ;
  • Kim, Shoon-Kyung (Department of Chemistry, College of Liberal Arts and Science, Seoul National University)
  • Published : 19610700
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Abstract

Assuming an intramolecular hydrogen-bonding, computation has been made on the optical rotatory power of 2-Chloro-1-Propanol. The magnitude of the calculated rotation is in fair agreement with the measured value of Lucas (calculated value: 21.6. measured value: 17.39). The agreement supports the validity of the assumption concerning the hydrogen-bonding between O atom and Cl atom. The agreement in sign confirms the validity the Fischer projection formula given by Lucas.

Keywords

References

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