Proceedings of the PSK Conference (대한약학회:학술대회논문집)
- 2003.04a
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- Pages.240.2-240.2
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- 2003
A Model Study toward the Synthesis of Xestoquinone and Halenaquinone
- Ahn, Chan-Mug (Dept. of Basic Sciences, Institute of Basic Medical Science, Yonsei University Wonju College of Medicine) ;
- Woo, Ho-Bum (Dept. of Basic Sciences, Institute of Basic Medical Science, Yonsei University Wonju College of Medicine)
- Published : 2003.04.01
Abstract
A strategy for synthesis of the furan-fused tetracyclic core of xestoquinone and halenaquinone was explored through a model study. Methyl 8-oxo-4-methyl-4-phenyl-2,7-nonadiynoate was prepared from hydratroponitrile and 3-butyn-1-ol as starting materials. The intramolecular cycloaddition of this intermediate as a key step will be involved.
Keywords