Periodicity in Chemical Shifts and Temperature Coefficients of $\alpha$-helix in TFE Solution

  • Suh, Jeong-Yong (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Choi, Byong-Seok (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1997.07.01

Abstract

Local conformation of helical peptides in TFE solution are studied by NMR spectroscopy. One is a helix containing proline and the other is its alanine derivative in which alanine is substituted for the proline. Chemical shift and temperature coefficient In NMR spectroscopy can be used preliminarily to determine secondary structure in proteins and peptides.(omitted)

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