• Title/Summary/Keyword: zero properties

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Removal of Pb(II) and Cd(II) From Aqueous solution Using Oxidized Activated Carbons Developed From Pecan Shells.

  • Youssef, A.M.;EL-Khouly, Sahar M.;El-Nabarawy, Th.
    • Carbon letters
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    • v.9 no.1
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    • pp.8-16
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    • 2008
  • Oxidized activated carbons were prepared by reacting steam-activated carbon developed from pecan shells with nitric acid of varying strength (15, 30, 45 and 60%). The textural properties and the chemistry of the surface of the non-oxidized and of the oxidized carbons were determined from nitrogen adsorption and base neutralization capacities. The uptake of Pb(II) and Cd(II) from aqueous solution by these carbons was determined by kinetic and equilibrium experiments as well as by the column method. Treatment with nitric acid brought about drastic decrease in surface area and remarkable increase in the pore size of the carbon with these changes depending on the strength of nitric acid. Nitric acid increased the surface acidity by developing new surface oxygen functional groups of acidic nature. $HNO_3$-oxidized carbons exhibited high adsorption capacities for Pb(II) and Cd(II). The adsorption of these ions increased with the decrease of the surface pH of the carbon and with the increase of the solution pH from 2.5 to 6 and 7. The amount adsorbed from lead and cadmium was also related to the amount of surface acidity, the pH of the point of zero charge and on some metal ion parameters. Cadmium and lead uptake by the investigated carbons followed pseudo-second order model and the equilibrium sorption data fitted Langmuir adsorption model.

Microwave Dielectric Properties of the MST Ceramics with Addition of Ce (Ce첨가에 따른 MST 세라믹스의 마이크로파 유전특성)

  • 최의선;박인길;배선기;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.430-433
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    • 2001
  • The 0.96MgTiO$_3$-0.04SrTiO$_3$+xCe(x=0∼1.6 wt%) ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 1300$^{\circ}C$, 2hr., respectively. From the X-ray diffraction patterns, it was found that the perovskite SrTiO$_3$ and ilmenite MgTiO$_3$ structures were coexisted in the 0.96MgTiO$_3$-0.04SrTiO$_3$+xCe(x=0∼1.6 wt%) ceramics. The dielectric constant($\varepsilon$$\sub$r/) was increased with addition of Ce. The temperature coefficient of resonant frequency($\tau$$\sub$f/) was gradually varied from positive value to the negative value with increasing the Ce. The temperature coefficient of resonant frequency of the 0.96MgTiO$_3$-0.04SrTiO$_3$+0.2Ce ceramics was near zero, where the dielectric constant, quality factor, and $\tau$$\sub$f/ were 20.68, 50, 272 and -0.5pm/$^{\circ}C$, respectively.

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The Summary of Researches on ADS in China

  • Haihong Xia;Zhixiang Zhao;Jigen Li;Yongqian Shi;Yinlu Han;Shengyun Zhu;Yongli Xu;Xialing Guan;Shinian Fu;Baoqun Cui
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.76-85
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    • 2005
  • The conceptual study of Accelerator Driven System (ADS) had lasted for about five years and ended in 1999 in China. As one project of 'the major state basic research program (973)' in energy domain, which is sponsored by the China Ministry of Science and Technology (MOST), a five years program of basic research for ADS physics and related technology has been launched since 2000 and passed national review last month. CIAE (China Institute of Atomic Energy), IHEP (Institute of High Energy Physics), PKU-IHIP (Institute of Heavy Ion Physics in Peking University) and other institutions are jointly carrying on the research. The research activities are focused on HPPA physics and technology, reactor physics of external source driven sub-critical assembly, nuclear data base and material study. For HPPA, a high current injector consisting of an ECR ion source, LEBT and a RFQ accelerating structure of 3.5MeV has been built. In reactor physics study, a series of neutron multiplication experimental study has been carried out and is being carrying on. The VENUS facility has been constructed as the basic experimental platform for the neutronics study in ADS blanket. It's a zero power sub-critical neutron multiplying assembly driven by external neutron produced by a pulsed neutron generator. The theoretical, experimental and simulation study on nuclear data, material properties and nuclear fuel circulation related to ADS is carrying on to provide the database for ADS system analysis. The main results on ADS related researches will be reported.

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Change in rheological properties of radish during salting (염 절임동안에 일어나는 무조직의 유변학적인 변화)

  • Kim, Byung-Yong;Cho, Jae-Sun
    • Applied Biological Chemistry
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    • v.35 no.5
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    • pp.399-403
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    • 1992
  • The amounts of salt diffused into radish after immersing in various concentrations of salt solution at different temperatures were measured and the changes of radish texture by the salt diffusion were estimatedwith the viscoelastic constants of a 3 element solid model determined by a stress relaxation test. While the amount of salt diffused throught radish was increased with increasing the salt concentration and soaking temperature, the istantaneous stress, equilibrium elastic solid and viscoelastic constants of radish were decreased. Also the degree of stress relaxation and equilibrium elastic solid approached the same or zero values, as salt concentration was further increased. Viscoelstic constants as well as salt diffusion were more influenced by lower salt concentration with increased temperatures.

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Characteristics of tantalum nitride thin film resistors deposited on $SiO_2/Si$ substrate using D.C-magnetron sputtering

  • Cuong, Nguyen Duy;Phuong, Nguyen Mai;Kim, Dong-Jin;Kang, Byoung-Don;Kim, Chang-Soo;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.64-65
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    • 2005
  • The structural and electrical properties of the films are investigated as a function of nitrogen/argon ratio at room temperature and at various deposition temperatures. The phase changes as $Ta_2N$ or TaN in the films were observed as nitrogen/argon ratio increases from 3% to 25%. The phase changes were associated with a change in the resistivity and TCR (temperature coefficient of resistance) of the films. TCR values of the films deposited at room temperature and different nitrogen contents were negative, and strongly decreased with the increase in nitrogen/argon ratio. The Ta2N films deposited at nitrogen/argon ratio of 3% show improved TCR values and thermal stability with increasing deposition temperature. The $Ta_2N$ films grown at nitrogen/argon ratio of 3% and the temperature of $200^{\circ}C$ showed a TCR value of -47 $ppm/^{\circ}C$, which is close to near-zero TCR in the range of deposition temperature.

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A Evaluation of Environmental Resistance for Bio-Polymer Concretes (바이오 폴리머 콘크리트의 환경 저항성 평가 연구)

  • Kim, Je Won;Kim, Tae Woo;Park, Hee Mun;Kim, Bu Il
    • International Journal of Highway Engineering
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    • v.15 no.5
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    • pp.75-79
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    • 2013
  • PURPOSES : The objective of this study is to evaluate the environmental resistance of bio-polymer concrete for use of pavement materials developed for reducing the carbon-dioxide. METHODS : The compression, tension, and bending strength tests were conducted on the bio-polymer concrete specimens with and without environmental conditioning. The specimens were conditioned using the freezing-thaw and accelerated weathering process for long period of time. To assess the resistance against chloride, the chloride ion penetration resistance tests were carried out on the bio-polymer concrete specimens. RESULTS : Test results show that the maximum difference in strength between specimens with and without conditioning is about 2.6MPa indicating that the effect of environmental conditioning on specimen strength is negligible. Based on the chloride ion penetration resistance test, the penetration quantity of electric charge of the specimens is zero and there is no ion penetration within the bio-polymer concrete. CONCLUSIONS : It is found from this study that there is slight change in strength of bio-polymer concretes before and after environmental conditioning process and no chloride ion penetration observed in these specimens. Therefore, the developed bio-polymer concretes can be applied effectively as pavement materials due to the small change of physical properties with environment change.

Spatial mapping of screened electrostatic potential and superconductivity by scanning tunneling microscopy/spectroscopy

  • Hasegawa, Yukio;Ono, Masanori;Nishio, Takahiro;Eguchi, Toyoaki
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.12-12
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    • 2010
  • By using scanning tunneling microscopy/spectroscopy (STM/S), we can make images of various physical properties in nanometer-scale spatial resolutions. Here, I demonstrate imaging of two electron-correlated subjects; screening and superconductivity by STM/S. The electrostatic potential around a charge is described with the Coulomb potential. When the charge is located in a metal, the potential is modified because of the free electrons in the host. The potential modification, called screening, is one of the fundamental phenomena in the condensed matter physics. Using low-temperature STM we have developed a method to measure electrostatic potential in high spatial and energy resolutions, and observed the potential around external charges screened by two-dimensional surface electronic states. Characteristic potential decay and the Friedel oscillation were clearly observed around the charges [1]. Superconductivity of nano-size materials, whose dimensions are comparable with the coherence length, is quite different from their bulk. We investigated superconductivity of ultra-thin Pb islands by directly measuring the superconducting gaps using STM. The obtained tunneling spectra exhibit a variation of zero bias conductance (ZBC) with a magnetic field, and spatial mappings of ZBC revealed the vortex formation [2]. Size dependence of the vortex formation will be discussed at the presentation.

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Research for Measurement and Modeling on Blocked Force of Electroactive Paper (생체 모방 종이 작동기 힘의 측정 및 모델링에 관한 연구)

  • Kang, Yu-Keun;Kim, Jae-Hwan;Jung, Woo-Chul;Song, Chun-Suk
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.731-734
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    • 2005
  • Generally, characteristics of electromechanical actuators are coupled with the mechanical and the electrical properties. Important mechanical parameters of these actuators are the achievable force and displacement in the presence of electric field. These mechanical parameters are related to the stress and strain of the materials and the actuator geometry. This paper presents how to measure the blocked force by using the micro-balance. The blocked force is defined as the force produced by the transducer under an applied voltage when the tip is constrained to zero motion. Also, a theoretical force by using the cantilever beam model is calculated under elastic domain. From the sample of 4 cm $\times$ 1 cm $\times$ 20 $\mu$m, the blocked farce measured from the equipment is 20.3 $\mu$N at 8 V$_{DC}$. By comparing it with the theoretical value, 24.9 $\mu$N, the blocked force measurement is acceptable. The furce measurement is also investigated with different AC electric fields and the frequency.

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A Study on the Weight Minimization of an Automobile Engine Block by the Optimum Structural Modification (최적구조변경법에 의한 자동차 엔진 블록의 중량최소화에 관한 연구)

  • 김영군;박석주;김성우
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1997.10a
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    • pp.326-332
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    • 1997
  • Recently to develop an automobile with better prosperities, many researches and investments have been executed. In this paper we intend to improve the automobile properties by reducing the weights of the engine without changing the dynamic characteristics. At first we perform the vibration analysis by the Substructure Synthesis Method and execute the exciting test for the engine model, and observe the coincidences of two results to confirm the reliability of the analyzing tools used. The weight minimization is performed by the Sensitivities of the Natural frequencies of the engine block. To decrease the engine weight ideally, the parts of the sensitivity zero are to be cut mainly, and the changing quantity of natural frequency by the cut is to be recovered by the structural modification for the parts with the good sensitivity. But, as actually the mathematical solution for the homogeneous problem(i.e. 0 object function) do not exist, we hereby redesign the block with much thinner thickness and recover the natural frequencies and natural modes to original structure's by the sensitivity analysis. And the Frequency Response Functions(FRF) are to be observed for the interesting points. In this analysis, the original thickness of the engine model has 8 mm of thickness, and the thickness redesigned is 5 mm and 6 mm. And we are to try to recover the 1, 2, 4, and 5 lower natural frequencies interested.

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Hydrothermal Growth and Characteristics of ZnO Nanorods on R-plane Sapphire Substrates

  • Kim, Min-Su;Kim, So-A-Ram;Nam, Gi-Ung;Park, Hyeong-Gil;Yun, Hyeon-Sik;Im, Jae-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.236-237
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    • 2012
  • ZnO nanorods were grown on R-plane sapphire substrates with the seed layers annealed at different temperature. The effects of annealing temperature for the seed layers on the properties of the ZnO nanorods were investigated by scanning electron microscopy, X-ray diffraction, UV-visible spectroscopy, and photoluminescence. For the as-prepared seed layers, the ZnO nanorods and the ZnO nanosheets were observed. Only the ZnO nanorods were grown as the annealing temperature was above $700^{\circ}C$. The optical transmittance in the UV region was almost zero while that in the visible region was gradually increased as the annealing temperature increased to $700^{\circ}C$. The optical band gap of the ZnO nanorods was increased as the annealing temperature increased to $700^{\circ}C$. In the visible region, the refractive index was decreased with increasing the wavelength, and the extinction coefficient was decreased as the annealing temperature increased to $700^{\circ}C$. The non-linear exciton radiative life time of the FX emission peak was established by cubic equation. The values of Varshni's empirical equation fitting parameters were ${\alpha}=4{\times}10^{-3}eV/K$, ${\beta}=1{\times}10^4K$, and $E_g(0)=3.335eV$ and the activation energy was found to be about 94.6 meV.

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