• Title/Summary/Keyword: zeolite sheet

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Preparation of Pt Catalyst Supported on Zeolite Sheet and Its Performance of Toluene Combustion (제올라이트 쉬트 담지 백금촉매의 제조 및 톨루엔 연소 특성)

  • Kim, Jin-Bae;Im, Na Rae;Kim, Hong Soo;Yoo, Yoon Jong
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.323-327
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    • 2011
  • A zeolite sheet (ceramic paper containing zeolite) made in a cylindrical configuration can be applied to a honeycomb rotor for the effective VOC removal. In this study, the zeolite sheet containing ZSM-5 was used as a support for Pt-loading, and its catalytic activity for the toluene combustion reaction was compared with those of the other Pt catalysts loaded on ${\gamma}-Al_2O_3$ and cordierite honeycomb. Pt/zeolite sheet catalyst showed a higher activity for toluene combustion reaction than that of $Pt/{\gamma}-Al_2O_3$ or Pt/cordierite honeycomb. On the other hand, the dispersion of Pt particles loaded on the zeolite sheet was improved by the pretreatment with $NH_3-H_2O$ vapor at room temperature. Consequently, the pretreatment of Pt/zeolite sheet by $NH_3-H_2O$ vapor significantly enhanced the catalytic activation for toluene combustion reaction.

Preparation of NaX Zeolite Coated Honeycomb Adsorbents and It's Carbon Dioxide Adsorption Characteristics (NaX 제올라이트가 담지된 허니컴 흡착제의 제조 및 이의 이산화탄소 흡착특성)

  • Yoo, Yoon-Jong;Kim, Hong-Soo;Singh, Ranjeet;Xiao, Penny;Webley, Paul A.;Chaffee, Alan L.
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.663-669
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    • 2009
  • The honeycomb adsorbent was prepared for adsorbing and seadsorbent was prepared by using zeolite sheet, which contained zeolite as component. The steady-state adsorption properties and surface morphologies were analyzed and breakthrough characteristics were ananlyzed by providing 16% carbon dioxide mixed gas. By thermal regeneration, carbon dioxide concentration properties were analyzed, and the adsorptive separation process was compared between thermal swing adsorption and pressure swing adsorption after adsorbent temperature change during heating. The breakthrough results of the honeycomb showed possibility parating carbon dioxide from combustion exhaust gas, which had deep impact on climate change, and the characteristics of the adsorbent were studied. Na-X zeolite was coated on a honeycomb prepared with ceramic sheet or active carbon sheet so that the two honycomb can be used at high temperature. Third honeycomb of rotary adsorptive concentration process.

Zeolite Based Membrane for Removal of Ammonium: A Review (효소 고정화막의 응용에 대한 총설)

  • Lee, Joo Yeop;Patel, Rajkumar
    • Membrane Journal
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    • v.32 no.3
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    • pp.173-180
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    • 2022
  • Presence of ammonia in drinking water is very toxic to human health. Soluble ammonia contaminates ground water due to activities such as the use of fertilizer in crop, industrial effluents and burning of fossil fuel. Even low concentration of ammonia present in water will damage aqua environment such as marine organism. Membrane technology is an important process to remove ammonia from effectively from water. Flat sheet membrane, membrane contactor and membrane distillation are some of the methods used for water purification from ammonia. Membrane contractor is an efficient process in which ammonia is removed through liquid-gas or liquid-liquid mass transfer without change of phase unlike membrane distillation. However, the cost of ammonia removal in this method is high due to maintenance of very high pH. Zeolite has excellent ion exchange ability that enhances its ability to interact with ammonia and adsorb from wastewater. Mixed matrix membranes containing zeolite enhance the efficiency of ammonia adsorption and separation from wastewater. In this review the above discussed issues are summarized in detail.

Quantitative and Qualitative Analysis of Inorgainc Substances by Low Temperature Ashing (저온 회화법에 의한 무기물의 정량${\cdot}$정성분석)

  • 이종만;류정용;신종호;송봉근;오세균;신채호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.77-85
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    • 1999
  • A study on the thermal stability of commonly used six fillers, such as titanium dioxide, silica, ground calcium carbonate, zeolite, and, clay, showed that most fillers except titanium dioxide were strongly effected by heat treatment. Therefore, the present methods for determination of ash in paper give weight loss due to thermal decomposition of fillers. It was found that a paper ashing method at a temperature of 40$0^{\circ}C$ allows most fillers in their original and undecomposed from. Results presented in this paper also show that X-ray diffraction can be used for qualitative determination of mixed fillers and coating pigments in a paper sheet.

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Performance Test of Low Temperature Regeneration Polymeric Desiccant Rotor (고분자 제습로터의 저온재생 성능시험)

  • Lee, Jin-Kyo;Lee, Dae-Young;Oh, Myung-Do
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.629-632
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    • 2009
  • The polymeric desiccant rotor is made from the super absorbent polymer by ion modification. The moisture sorption capacity of the super desiccant polymer(SDP) is 4 to 5 times larger than those of common desiccant meterials such as silica gel or zeolite. It is also known that SDP can be regenerated even at the relatively low temperature. To fabricate the desiccant rotor, firstly the SDP was laminated by coating the SDP on polyethylene sheet. Then corrugated and rolled up into a rotor. The diameter, the depth, the dimensions of the corrugated channel, etc. were pre-determined from numerical simulation on the heat and mass transfer in the desiccant rotor. The dehumidification performance was tested in a climate chamber. The relevant tests were carried out at the process air inlet temperature of $32^{\circ}C$, the regeneration air inlet temperature of $60^{\circ}C$ and the inlet dew-point temperature of both the process air and the regeneration air of $18.5^{\circ}C$, when the rotation period is long, the moisture sorption is not effective. In the desiccant rotor developed in this study, the optimum rotation period is found about 350s at the regeneration temperature of $60^{\circ}C$. It was found from further experiments that the optimum rotation tends to decreases as the regeneration temperature increases. Meanwhile, the outlet temperature of the process air deceases monotonically as the rotation period increases.

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Mineralogical Properties and Paragenesis of H-smectite (H-스멕타이트의 광물학적 특성과 생성관계)

  • Noh, Jin-Hwan;Hong, Jin-Sung
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.377-393
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    • 2010
  • Pumiceous tuffs occurring in the Beomgockri Group are examined applied-mineralogical characteristics and their controling factors to evaluate their potentials as the adsorption-functional mineral resources. The pumiceous tuffs are diagenetically altered to low-grade zeolitcs and bentonites in the Janggi area. Compositional specialty due to the presence of pumice fragments induces the altered tuffs to exhibit the characteristic adsorption property combined with cation exchange capacity, specific surface area, and acidic pH. Unusual lower pH in the adsorption-functional mineral substances is turned out to be originated from the presence of H-smectite having $H^+$ in the interlayer site of the sheet structure. On account of disordered crystallinity resulting from the exchanged $H^+$ in the interlayer site, the smectite commonly forms crenulated edges in the planar crystal form and exhibits characteristic X-ray diffraction patterns showing comparatively lower intensities of basal spacings including (001) peak than conventional Ca-smectite. Based on the interpretation of paragenetic relations and precursor of the H-smectite, a genetic model of the peculiar clay mineral was proposed. The smectite formation may be facilitated resulting from the precipitation of opal-CT at decreasing pH condition caused by the release of H+ during diagenetic alteration of pumice fragments. Because of the acidic smectite, the low-grade mineral resources from the Beomgockri Group may be applicable to the adsorption industry as the raw materials of acid clays and bed-soil.