• 한국산업보건학회지
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• 제27권4호
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• pp.291-301
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• 2017

Objectives: In order to improve the working environment and solve the complaints, many efforts have been made to remove the odor from the industrial process. There are many disposal methods to remove odor, but there are many disadvantages and inadequate applications. The Purpose of this study was to develop a bag-filer system for odor removal using powder adsorbent. Methods: The bag-filter system is composed of a shear bag filter, an absorbent spraying system and an absorbent circulation system. The spraying absorbent system was connected with the inlet duct of the shear bag filter for inputting adsorbent. And the absorbent circulation system can transport the collecting adsorbent from hoper to the inlet duct of the system. As a result, the adsorbent can remove odor with recycling in the system. Also affective factors like the powdered absorbent combination and injection method was researched for maximization of system efficiency. The study was conducted in two stages. The first step was testing equipment made and the second is to evaluate the efficiency of the odor control by connecting to the actual odor generation process. Results: Both experiment stages showed efficient odor control ability. The adsorption efficiency of the system is demonstrated and the odor was adsorbed well by the powder adsorbent. It is essential to accurately understand the characteristics of the odorous and use the appropriate adsorbent. Although the powder adsorbent was used in the experiment, the problem of scattering did not occur due to the high degree of system sealing. Also the system manufactured in this study was designed to recycle the adsorbent, so adsorbent reuse or batch processing is convenient. Conclusions: The applicability of the system has been proven through this research. Customized systems for industrial process and the appropriate adsorbent base on the characteristics of pollutant generation will show efficient odor collection ability.

• 신재생에너지
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• 제5권4호
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• pp.46-51
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• 2009

The purpose of this study is to investigate selective adsorption of $CO_2$ from LFG (Landfill gas) by using commercialized NaX-type zeolite adsorbent under the ambient temperature and pressure. The experiment of $CO_2$ adsorption was carried out by using simulated LFG. The $CO_2$ adsorption capacity and separation efficiency of NaX-type adsorbent were investigated by analyzing gas flow rate and gas composition at inlet and outlet of the adsorption reactor. The adsorbed $CO_2$ were desorbed under decompression condition which 0.5 Torr or by air purge. Through the result to use simulated LFG, when the method of VSA was used, 73.2~75.3 mg of $CO_2$ was adsorbed per 1 g commercial adsorbent, when the method of air purge was used, 78.4~83.2 mg of $CO_2$ was adsorbed per 1 g of commercial adsorbent.

• 환경위생공학
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• 제18권3호통권49호
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• pp.43-47
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• 2003

The desorption characteristics of NaY zeolite, of which Si/Al ratio is 2.36, was measured at 25${\circ}$C and 150${\circ}$C so as to be used practically as a adsorbent for separation of sulfur oxides from flue gas, for which adsorption and desorption cycles at 25${\circ}$C were repeated four times and that at 150${\circ}$C was done one time. As a result it took 30.8 at 150${\circ}$C and 164.1 minutes in average at 25${\circ}$C to reach equilibrium condition. It means that regeneration of the NaY zeolite can be done below 150${\circ}$C so that zeolite can be used for flue gas desulfurization.

• 한국환경농학회지
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• 제5권2호
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• pp.101-105
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• 1986

폐수중(廢水中) cadmium의 제거(除去)를 위한 목적(目的)으로 천연(天然) Zeolite의 이용가능성(利用可能性)을 조사(調査)한 결과(結果)는 다음과 같았다. Freundlich 흡착상수(吸着常數) $\frac{1}{n}$값이 $0.4{\sim}1.1$인 것으로 보아 천연(天然) zeolite는 효과적(效果的)인 흡착제(吸着劑)였다. 용액중(溶液中) cadmium의 농도(濃度)가 증가(增加)할수록 흡착량(吸着量)은 증가(增加)하였으며 포화(飽和)된 각(各) 양(陽) ion의 종류별(種類別) 흡착량(吸着量)은 Ca-<무처리(無處理)$-<H-{\leqq}Al-<Nazeolite$의 순(順)이었다. 또 천연(天然) Zeolite에 의한 cadmium의 흡착반응(吸着反應) 용액중(溶液中) 공존(共存)하는 Cu와 Zu에 의하여 저해(沮害)되었으며, pH $5{\sim}6$의 범위에서 흡착제거솔(吸着除去率)이 가장 좋았다. 흡착(吸着)된 cadmium을 4종(種)의 염용액(鹽溶液)으로 탈착(脫着)시켜본 결과(結果), 농도(濃度)가 높을수록 많은 양의 cadmium이 탈착(脫着)되었으며, 각(各) 염용액(鹽溶液)의 cadmium 탈착정도(脫着程度)는 $Nacl<CaCl_2<AlCl_3<HCl$의 순(順)이었다.

• 청정기술
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• 제7권1호
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• pp.51-63
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• 2001

화력발전소의 연소가스에서 고순도의 $CO_2$를 분리, 회수하는 것을 목적으로, 에너지 비용이 적게 드는 것으로 알려진 PSA(Pressure Swing Adsorption)공정을 이용하였다. 흡착제로서 활성탄 및 제올라이트를 사용하여 연소가스에서 $CO_2$를 회수할 수 있는 장치를 제작하고 이를 조업하는 조건을 확립하고자 하였다. $CO_2$ 회수용으로 적합하지 않다고 알려져 있는 활성탄을 이용하여도 세정단계의 변형을 통한 새로운 사이클을 이용하여 고순도의 $CO_2$를 생성물로 얻을 수 있었다. 또한 활성탄과 제올라이트 각 흡착제의 흡착특성을 이용하여 이들 두 흡착제의 장점을 최대로 이용할 수 있도록 흡착탑의 일부만을 제올라이트 13X를 채워 조업하는 2단 적층 흡착탑을 이용하여 회수율의 향상을 얻을 수 있었다. 흡착탑의 도입부 쪽에 활성탄을, 배출부 쪽에 제올라이트를 채움으로써 최대의 효과를 얻을 수 있었는데, $CO_2$ 농도 13%, 유량 10 SLPM, 흡착압력 2.2기압에서 제올라이트를 부피비로 25%만 사용하여도 40%의 회수율 향상을 얻을 수 있었으며 50%를 이용한 경우에는 회수율이 67%까지 증가하였는데 이는 제올라이트만을 이용한 경우의 회수율과 비슷한 결과였다.

• 공업화학
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• 제20권1호
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• pp.80-86
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• 2009

파라자일렌 분리용 흡착제로서 효과적인 결합제가 없는 제올라이트 BaX 성형체를 제조하는 방법에 대하여 검토하였다. 제올라이트 NaX 타입의 결정분말을 무기결합제인 colloidal silica sol (C.S.) 용액과 기공형성제인 microcrystalline cellulose 분말을 이용하여 구형화 한 후 소성, binderless 처리, 바륨 이온교환, 활성화 등의 단계를 거치면서 넓은 비표 면적과 우수한 강도 및 파라자일렌에 대한 선택도를 갖는 파라자일렌 분리용 흡착제를 제조하였다. 각 시료의 무기결합제$SiO_2$함량을 14.0 wt%, 18.0 wt%, 22.3 wt%로 조절하여, 무기결합제의 함량 증가에 따른 시료 강도의 변화에 대해 검토하였다. 구형화 시료의 무기결합제 함량이 증가 될수록 binderless 처리 후의 강도가 증가함을 확인할 수 있었다. 이렇게 제조된 시료에 무게비 1 : 1 : 1로 혼합된 혼합자일렌 용액으로 $90^{\circ}C$에서 회분식 흡착실험을 수행해본 결과, 본 연구에서 제조된 binderless zeolite BaX는 파라자일렌에 선택적인 흡착능을 보임을 확인하였다. 이렇게 제조된 흡착제는 충분한 강도(0.450 kgf)와 결정화도(98.53%), BET 비표면적$(647.57m^2/g)$을 가지면서, 파라자일렌을 선택적으로 흡착함을 확인할 수 있었다.

• 한국환경과학회지
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• 제21권6호
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• pp.687-694
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• 2012

Zeolite 4A was synthesized by fusion method from coal fly ash discharged at the thermal power plants. The synthesized zeolite(FAZ) was characterized through particle size analyzer, XRD, XRF and SEM. $N_2$ adsorption-desorption measurement was used to examine surface and pore structures. The adsorption experiments were carried out under dynamic conditions of trace $SO_2$ in $N_2$ to investigate $SO_2$ adsorption capacity of FAZ. The experiments were conducted to characterize the breakthrough characteristics of $SO_2$ in a fixed bed under different operating conditions including temperature(50-$125^{\circ}C$), concentration of $SO_2$(3000-10000 ppm) and FAZ with 4 kinds of commercial zeolite. The adsorption capacity of FAZ was 53.84 $mgSO_2/g$ adsorbent, larger than that of the same type commercial zeolite(WK4A).

• Nuclear Engineering and Technology
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• 제49권3호
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• pp.556-561
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• 2017

Serving as an excellent adsorbent and inorganic ion exchanger in the water purification field, zeolite 4A has in this work presented a strong capability for purifying radioactive waste, such as $Sr^{2+}$, $Cs^+$, and $Co^{2+}$ in water. During the processes of decontamination and decommissioning of suspended solids and organics in low-level radioactive wastewater, the purification performance of zeolite 4A has been studied. Under ambient temperature and neutral condition, zeolite 4A absorbed simulated radionuclides such as $Sr^{2+}$, $Cs^+$, and $Co^{2+}$ with an absorption rate of almost 90%. Additionally, in alkaline condition, the adsorption percentage even approached 98.7%. After conducting research on suspended solids and organics of zeolite 4A for the treatment of radionuclides, it was found that the suspended clay was conducive to absorption, whereas the absorption of organics in solution was determined by the species of radionuclides and organics. Therefore, zeolite 4A has considerable potential in the treatment of radioactive wastewater.

• 한국수처리학회지
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• 제26권6호
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• pp.125-132
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• 2018

We studied a simple approach for synthesis of mesoporous Y(M-Y) from commercial zeolite Y precursors by treating of NaOH with $CH_3(CH_2)_{15}N(Br)(CH_3)_3$ as template. The physicochemical properties of the mesoporous zeolites Y were then analyzed using XRD, nitrogen full-isotherms at 77 K, SEM and TEM. The nitrogen adsorption-desorption analysis showed that surface area and pore diameter of synthesized mesoporous zeolite Y(M-Y) were $1072m^2/g$ and ~3.3 nm, respectively. And M-Y was applied for the removal of $Mn^{2+}$ and $Fe^{2+}$ from aqueous solution. This material, which introduces mesoporosity with zeolite Y character, displayed a superior adsorption capacity than commercial zeolite Y when used as an adsorbent for the removal of $Mn^{2+}$ and $Fe^{2+}$.

• Korean Chemical Engineering Research
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• 제48권6호
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• pp.784-790
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• 2010

고정층 반응기에서 비산재로부터 합성한 제올라이트와 4종류의 활성탄을 사용하여 질소 기류에서 아세톤, 벤젠, 톨루엔, 에틸벤젠 증기의 파과곡선을 측정하였다. 흡착실험은 101.3 kPa, $40^{\circ}C$에서 혼합 가스의 유량 $70cm^3/min$, 흡착제의 공급량 5 g, 그리고 VOCs 증기의 농도는 포화조의 온도를 $30^{\circ}C$로 하여 행하였다. 실험으로부터 얻은 파과곡선의 비선형해석으로부터 VOCs의 흡착과 흡착제의 비활성화를 동시에 고려한 비활성모델의 흡착속도상수와 비활성속도상수를 구하여 문헌의 다른 흡착등온모델과 비교하였다. 검토한 모델 중 비활성모델이 실험결과와 가장 일치하였고 다음으로 Freundlich, DRK 모델 순으로 높은 상관관계를 나타내었다. 또한 파과곡선으로부터 구한 흡착제의 흡착용량은 VOC의 끓는점이 증가할수록 감소하였으며, 증기압이 증가할수록 증가하였다.