• Title/Summary/Keyword: yield force

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Carbonylation of 1-Bromo-2,6-bis(bromomethyl)benzene Catalyzed by Cobalt Carbonyl

  • Sang Chul Shim;Shin Ae Chae;Dong Yeob Lee;Young Zoo Youn;Jae Goo Shim;Chil Hoon Doh
    • Bulletin of the Korean Chemical Society
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    • v.14 no.4
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    • pp.481-485
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    • 1993
  • Dialkyl 1-bromobenzene-2,6-diacetates were easily prepared by the carbonylation of the moiety of benzylic bromide in 1-bromo-2,6-bis(bromomethyl)benzene with alcohol in the presence of NaOAc< TEX>${\cdot}$3H$_2$O and a catalytic amount of Co$_2$(CO)$_8$under the atmospheric pressure of carbon monoxide at room temperature in excellent yield. Alkyl 2,6-bis(alkoxymethyl)benzoates were obtained by the carbonylation of the moiety of aryl bromide in 1-bromo-2,6-bis(alkoxymethyl)-benzene, which derived from 1-bromo-2,6-bis(bromomethyl)benzene, alcohol, NaOR, and CH$_3$I under the same conditions. Alkyl 2,6-bis(carboxymethyl)benzoate was also obtained in a trace amount for 24 hrs at room temperature.

A co-rotational 8-node assumed strain element for large displacement elasto-plastic analysis of plates and shells

  • Kim, K.D.
    • Structural Engineering and Mechanics
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    • v.15 no.2
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    • pp.199-223
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    • 2003
  • The formulation of a non-linear shear deformable shell element is presented for the solution of stability problems of stiffened plates and shells. The formulation of the geometrical stiffness presented here is exactly defined on the midsurface and is efficient for analyzing stability problems of thick plates and shells by incorporating bending moment and transverse shear resultant force. As a result of the explicit integration of the tangent stiffness matrix, this formulation is computationally very efficient in incremental nonlinear analysis. The element is free of both membrane and shear locking behaviour by using the assumed strain method such that the element performs very well in the thin shells. By using six degrees of freedom per node, the present element can model stiffened plate and shell structures. The formulation includes large displacement effects and elasto-plastic material behaviour. The material is assumed to be isotropic and elasto-plastic obeying Von Mises's yield condition and its associated flow rules. The results showed good agreement with references and computational efficiency.

Development of UML Tool using WPF Framework and Forced-Directionality Graph Algorithm

  • Utama, Ahmad Zulfiana;Jang, Duk-Sung
    • Journal of Korea Multimedia Society
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    • v.22 no.6
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    • pp.706-715
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    • 2019
  • This research implemented grammatical rules for relationship extraction from class diagram candidate. The problem statement is generated by our algorithm to yield class diagram and candidate relationship candidates. The relationships of class diagrams are extracted automatically from the problem statement by using Natural Language Processing (NLP). The extraction used the grammatical rules that obtained from various sources and translated into our algorithm. The performance evaluation of the extraction algorithm used ATM problem statements. The application captures the problem statement and draws automatically the relations of class diagrams using Forced-Directionality Graph algorithm. The performance evaluations show refining methods for class diagram and relationships extraction improve recall score.

Determination of shear stiffness for headed-stud shear connectors using energy balance approach

  • Ye, Huawen;Huang, Ruosen;Tang, Shiqing;Zhou, Yu;Liu, Jilin
    • Steel and Composite Structures
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    • v.42 no.4
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    • pp.477-487
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    • 2022
  • The shear stiffness of headed-stud shear connectors has no unified definition due to the nonlinear characteristics of its load-slip relationship. A unified framework was firstly adopted to develop a general expression of shear load-slip equation for headed-stud shear connectors varying in a large parameter range based on both force and energy balance. The pre- and post-yield shear stiffness were then determined through bilinear idealization of proposed shear load-slip equation. An updated and carefully selected push-out test database of 157 stud shear connectors, conducting on studs 13~30mm in diameter and on concretes 30~180 MPa in cubic compressive strength, was used for model regression and sensitivity analysis of shear stiffness. An empirical calculation model was also established for the stud shear stiffness. Compared with the previous models through statistical analysis, the proposed model demonstrates a better performance to predict the shear load-slip response and stiffness of the stud shear connectors.

Performance Evaluation of Rcentering Smart Damper by Pre-Compression of Polyurethane (폴리우레탄 선압축량에 따른 자동복원 스마트 감쇠장치의 일축반복하중에 대한 성능 평가)

  • Jang, Heemyung
    • Journal of Urban Science
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    • v.11 no.1
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    • pp.1-8
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    • 2022
  • As the magnitude and frequency of earthquakes increase in Korea, interest in earthquake damage reduction technology has increased. Therefore, research on vibration damping devices that directly respond to seismic loads is being actively researched. After an earthquake, damage or destruction of the device occurs due to the yield of materials, and thus it takes considerable cost and time for restoration and replacement. To supplement the problems of the existing earthquake damage reduction technology, a study was conducted on the recentering smart damper that can be used continuously after an earthquake. In this study, the recentering smart damper that can be restored to its original shape after load removal was developed using superelastic shape memory alloy, pre-compressed polyurethane. General steel was commonly applied to verify the seismic performance of the superelastic shape memory alloy, and the performance of the smart damper was verified according to the amount of polyurethane pre-compressed

Experimental Evaluation of the Seismic Performance and Engineering Damage State of Reinforced Concrete Columns (철근콘크리트 기둥의 내진성능 및 공학적 손상상태에 대한 실험적 평가)

  • Lee, Do Hyung
    • Journal of the Earthquake Engineering Society of Korea
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    • v.27 no.2
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    • pp.119-127
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    • 2023
  • In this paper, seismic performance evaluation was carried out for eight circular reinforced concrete columns designed seismically by KRTA[1]and KCI[8]. Primary design parameters for such columns included many longitudinal reinforcements, yield strength of reinforcements, the vertical spacing of spirals, aspect ratio, and axial force ratio. The test results showed that all the columns exhibited stable hysteretic and inelastic responses. Based on the test results, drift ratios corresponding to each damage state, such as initial yielding, initial cover spalling, initial core concrete crushing, buckling, and fracture of longitudinal reinforcement and final spalled region, were evaluated. Then, those ratios were compared with widely accepted damage limit states. The comparison revealed that the existing damage states were considerably conservative. This implies that additional research is required for the damage limit states of such columns designed seismically by current Korean design codes.

Enhanced generalized modeling method for compliant mechanisms: Multi-Compliant-Body matrix method

  • Lim, Hyunho;Choi, Young-Man
    • Structural Engineering and Mechanics
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    • v.82 no.4
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    • pp.503-515
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    • 2022
  • The multi-rigid-body matrix method (MRBMM) is a generalized modeling method for obtaining the displacements, forces, and dynamic characteristics of a compliant mechanism without performing inner-force analysis. The method discretizes a compliant mechanism of any type into flexure hinges and rigid bodies by implementing a multi-body mass-spring model using coordinate transformations in a matrix form. However, in this method, the deformations of bodies that are assumed to be rigid are inherently omitted. Consequently, it may yield erroneous results in certain mechanisms. In this paper, we present a multi-compliant-body matrix-method (MCBMM) that considers a rigid body as a compliant element, while retaining the generalized framework of the MRBMM. In the MCBMM, a rigid body in the MRBMM is segmented into a certain number of body nodes and flexure hinges. The proposed method was verified using two examples: the first (an XY positioning stage) demonstrated that the MCBMM outperforms the MRBMM in estimating the static deformation and dynamic mode. In the second example (a bridge-type displacement amplification mechanism), the MCBMM estimated the displacement amplification ratio more accurately than several previously proposed modeling methods.

Effects of Climatic Condition on Stability and Efficiency of Crop Production (농업 기상특성과 작물생산의 효율 및 안전성)

  • Robert H. Shaw
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.27 no.4
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    • pp.296-313
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    • 1982
  • At a time when world population and food supply are in a delicate balance, it is essential that we look at factors to improve this balance. We can alter the environment to better fit the plant's needs, or we can alter the plant to better fit the environment. Improved technology has allowed us to increase the yield level. For moderately detrimental weather events technology has generally decreased the yield variation, yet for major weather disasters the variation has increased. We have raised the upper level, but zero is still the bottom level. As we concentrate the production of particular crops into limited areas where the environment is closest to optimum, we may be increasing the risk of a major weather related disaster. We need to evaluate the degree of variability of different crops, and how weather and technology can interact to affect it. The natural limits of crop production are imposed by important ecological factors. Production is a function of the climate, the soil, and the crop and all activities related to them. In looking at the environment of a crop we must recognize these are individuals, populations and ecosystems. Under intensive agriculture we try to limit the competition to one desired species. The environment is made up of a complex of factors; radiation, moisture, temperature and wind, among others. Plant response to the environment is due to the interaction of all of these factors, yet in attempting to understand them we often examine each factor individually. Variation in crop yields is primarily a function of limiting environmental parameters. Various weather parameters will be discussed, with emphasis placed on how they impact on crop production. Although solar radiation is a driving force in crop production, it often shows little relationship to yield variation. Water may enter into crop production as both a limiting and excessive factor. The effects of moisture deficiency have received much more attention than moisture excess. In many areas of the world, a very significant portion of yield variation is due to variation in the moisture factor. Temperature imposes limits on where crops can be grown, and the type of crop that can be grown in an area. High temperature effects are often combined with deficient moisture effects. Cool temperatures determine the limits in which crops can be grown. Growing degree units, or heat accumulations, have often been used as a means of explaining many temperature effects. Methods for explaining chilling effects are more limited.

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Behavior of Columns Due to Variation of Performance Influencing Factors Based on Performance Based Design (성능기반설계에 기초한 성능영향인자 변화에 따른 기둥의 거동분석)

  • Yun, Sung-Hwan;Choi, Min-Choul;Kang, Yoon-Sig;Park, Tae-Hyo
    • Journal of the Korea Concrete Institute
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    • v.22 no.4
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    • pp.489-498
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    • 2010
  • The performance evaluation of reinforcement concrete structure is carried out as a function of the following performance influencing factors: (1) the strength of concrete, (2) longitudinal reinforcement, (3) transverse reinforcement, (4) aspect ratio, and (5) axial force. With various values of the five parameters, eigenvalue analysis and non-linear static analysis were performed to investigate the structural yield displacement, yield basis shear force, and static performance of ductility ratio. In addition, the performance evaluation is carried out according to the modified capacity spectrum method (FEMA-440) using the results of non-linear static analysis, and the effect of each parameter on performance point is analyzed. Based on the result of eigenvalue analysis and non-linear static analysis indicates, that the natural period and the ductility ratio are affected more by the structural properties than the material properties. In case of the analysis of the criterion of performance points, the effect of section shape is one of the important factors together with natural period and ductility ratio.

Parametric Study of Dynamic Soil-pile-structure Interaction in Dry Sand by 3D Numerical Model (3차원 수치 모델을 이용한 건조사질토 지반-말뚝-구조물 동적 상호작용의 매개변수 연구)

  • Kwon, Sun-Yong;Yoo, Min-Taek
    • Journal of the Korean Geotechnical Society
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    • v.32 no.9
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    • pp.51-62
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    • 2016
  • Parametric studies for various site conditions by using 3d numerical model were carried out in order to estimate dynamic behavior of soil-pile-structure system in dry soil deposits. Proposed model was analyzed in time domain using FLAC3D which is commercial finite difference code to properly simulate nonlinear response of soil under strong earthquake. Mohr-Coulomb criterion was adopted as soil constitutive model. Soil nonlinearity was considered by adopting the hysteretic damping model, and an interface model which can simulate separation and slip between soil and pile was adopted. Simplified continuum modeling was used as boundary condition to reduce analysis time. Also, initial shear modulus and yield depth were appropriately determined for accurate simulation of system's nonlinear behavior. Parametric study was performed by varying weight of superstructure, pile length, pile head fixity, soil relative density with proposed numerical model. From the results of parametric study, it is identified that inertial force induced by superstructure is dominant on dynamic behavior of soil-pile-structure system and effect of kinematic force induced by soil movement was relatively small. Difference in dynamic behavior according to the pile length and pile head fixity was also numerically investigated.