• Title/Summary/Keyword: yield conditions

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Synthesis, Characterization and Application of Poly(4-Methyl Vinylpyridinium Hydroxide)/SBA-15 Composite as a Highly Active Heterogeneous Basic Catalyst for the Knoevenagel Reaction

  • Kalbasi, Roozbeh Javad;Kolahdoozan, Majid;Massah, Ahmadreza;Shahabian, Keinaz
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2618-2626
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    • 2010
  • In this paper poly (4-methyl vinylpyridinium hydroxide)/SBA-15 composite was prepared as a highly efficient heterogeneous basic catalyst by in situ polymerization method for the first time. It was characterized by XRD, FT-IR, BET, TGA, SEM and back titration using NaOH. This catalyst exhibited the excellent catalytic activities for the Knoevenagel condensation of various aldehydes with ethyl cyanoacetate. Over this catalyst, ${\alpha},{\beta}$-unsaturated carbonyl compounds were obtained in the reasonable yield at $95^{\circ}C$ in 10 - 30 min in $H_2O$ as a solvent with a 100% selectivity to the condensation products. Catalyst could be easily recycled after the reaction and it could be reused without the significant loss of activity/selectivity performance. No by-product formation, high yields, short reaction times, mild reaction conditions and operational simplicity with reusability of the catalyst were the salient features of the present synthetic protocol. Presence of $H_2O$ as a solvent was also recognized as a "green method".

A Study on the Establishing the Preparation Conditions for Pine Mushroom(Tricholoma matsutake Sing.) Granular Tea (송이버섯을 이용한 과립차 제조 조건 확립에 관한 연구)

  • Park, Mi-Lan;Choi, Soo-Keun;Byun, Gwang-In
    • Journal of the East Asian Society of Dietary Life
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    • v.17 no.5
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    • pp.689-695
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    • 2007
  • The pine mushroom is recognized as being a valuable functional food and is considered a prized mushroom. One of the product development plans for this mushroom is a granular tea. Thus, for this study, the physical properties and sensory qualities evaluation of such a this product were measured. First, we extracted pine mushrooms at various temperatures(50, 60, 70, 80 and $90^{\circ}C$) to make a pine mushroom granular tea. The extraction yield and free amino acid content were greatest in the $50^{\circ}C$ extraction. This extract that was acquired at $50^{\circ}C$ was lyophilized and pulverized to make the granule tea. According to the results, the granular tea made from 4% pine mushroom powder had the best taste, with a Brix value of 1.9% and a pH of 4.12. The L-value of chromaticity was 49.00, the a-value -0.85, and the b-value was 1.28.

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The Experimental Performance Comparison of a Water Type Glazed and Unglazed PV-Thermal Combined Modules (액체식 PVT 복합모듈의 유형별 성능 비교 분석)

  • Kim, Jin-Hee;Kang, Jun-Gu;Kim, Jun-Tae
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.792-797
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    • 2009
  • The excess heat that is generated from PV modules can be removed and converted into useful thermal energy. A photovoltaic-thermal(PVT) module is a combination of photovoltaic module with a solar thermal collector, forming one device that receives solar radiation and produces electricity and heat simultaneously. In general, two types of PVT can be classified: glass-covered PVT module, which produces high-temperature heat but has a slightly lower electrical yield, and uncovered PVT module, which produces relatively lower temperature heat but has a somewhat higher electrical performance. In this paper, the experimental performance of two types of the PVT combined module(water type), glazed(glass-covered) and unglazed, was analyzed. The electrical and thermal performance of the PVT combined modules were measured in outdoor conditions, and the results were compared.

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Production of ginsenoside F1 using commercial enzyme Cellulase KN

  • Wang, Yu;Choi, Kang-Duk;Yu, Hongshan;Jin, Fengxie;Im, Wan-Taek
    • Journal of Ginseng Research
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    • v.40 no.2
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    • pp.121-126
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    • 2016
  • Background: Ginsenoside F1, a pharmaceutical component of ginseng, is known to have antiaging, antioxidant, anticancer, and keratinocyte protective effects. However, the usage of ginsenoside F1 is restricted owing to the small amount found in Korean ginseng. Methods: To enhance the production of ginsenoside F1 as a 10 g unit with high specificity, yield, and purity, an enzymatic bioconversion method was developed to adopt the commercial enzyme Cellulase KN from Aspergillus niger with food grade, which has ginsenoside-transforming ability. The proposed optimum reaction conditions of Cellulase KN were pH 5.0 and $50^{\circ}C$. Results: Cellulase KN could effectively transform the ginsenosides Re and Rg1 into F1. A scaled-up biotransformation reaction was performed in a 10 L jar fermenter at pH 5.0 and $50^{\circ}C$ for 48 h with protopanaxatriol-type ginsenoside mixture (at a concentration of 10 mg/mL) from ginseng roots. Finally, 13.0 g of F1 was produced from 50 g of protopanaxatriol-type ginsenoside mixture with $91.5{\pm}1.1%$ chromatographic purity. Conclusion: The results suggest that this enzymatic method could be exploited usefully for the preparation of ginsenoside F1 to be used in cosmetic, functional food, and pharmaceutical industries.

Response of Leaf Water Potential and Growth Characteristics to Irrigation Treatment in Soybean

  • Lee, Jeong-Hwa;Seong, Rak-Chun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.2
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    • pp.81-88
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    • 2003
  • Soybeans [Glycine max (L.) Merr.] are frequently exposed to unfavorable environments during growing seasons and water is the most important factor limiting for the production system. The purpose of this study was to determine the leaf water potential changes by irrigation, and to evaluate the relationships of leaf water potential, growth and yield in soybeans. Three soybean cultivars, Hwangkeumkong, Shinpaldalkong 2, and Pungsannamulkong, were planted in growth chamber and field with irrigated treatments. Leaf water potential of three soybean cultivars was positively correlated with leaf water content during vegetative and reproductive growth stages in growth chamber and field experiments. Leaf water potentials measured for three soybean cultivars under growth chamber were higher than those of under field conditions. Higher leaf water potential with irrigated plots under field was observed compared to conventional plots during reproductive growth stages. Leaf water potentials of three soybean cultivars were continually decreased during reproductive growth stages under field and there was no significant difference among them. Number of leaves, leaf water content, pod dry weight, number of seeds and seed dry weight with irrigated plots were higher than those of conventional plots. The results of this study suggested that leaf water potential could be used as an important growth indicator during the growing season of soybean plants.

Review of Disease Incidence of Major Crops in 2003 (2003년 농작물 병해 발생개황)

  • Kim, Choong-Hoe
    • Research in Plant Disease
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    • v.10 no.1
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    • pp.1-7
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    • 2004
  • The year of 2003 was characterized as a cool humid year. Low temperature and frequent rains were continued during March to July, resulting in 1.6 times higher rainfalls and 32% less sunshine period compared to the average yean Due to 2003's climatic condition, rice blast, and bacterial leaf blight occurred severely. Higher rainfalls caused severe epidemic of phytophthora disease and, in case of red-pepper, 55% of cultivation acreage was devastated by the disease over the country. Besides, crop diseases which become severe under cool-humid conditions, such as gray mold, sclerotinia rot, downy mildew, increased significantly compared to the previous year. In fruit trees, brown spot of apple, and pear scab occurred severely causing much yield loss.

A Study on Mechanical Properties Changes to Improve the Confidence of Remaining Life Evaluation for the Weldment of Power Plant Boiler Tube(SA213-T12) (발전설비 보일러 튜브 용접부의 잔여수명평가 신뢰성 향상을 위한 기계적 물성 변화 연구(SA213-T12))

  • Oh, Byungjin;Jang, Joong Soon
    • Journal of Welding and Joining
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    • v.32 no.3
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    • pp.102-107
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    • 2014
  • Boiler equipment in power plant is always being operated in harsh conditions and severely exposed to the extreme environment of high temperature. Therefore periodically the state of devices should be checked, diagnosed, and analyzed to ensure the reliability of the equipment. Traditionally, such a diagnosis is based one or two physical properties of the sample taken from the equipment like hardness, microstructure, etc.. However, to enhance the confidence of the diagnosis, it is necessary to synthesize those properties together. This paper is to propose such a synthetic procedure for SA213-T12(1Cr-0.5Mo) which was developed to be used in $565^{\circ}C$ below condition. Creep test and accelerated degradation test were performed simultaneously, and the physical properties such as microstructure, tensile strength, yield strength, hardness, and indentation properties were measured. This paper proposes a method of determining the remaining life by quantitative comparison. It will provide the basis of evaluating life assessment more objective and reliable.

The Optimum Operating Condition for Reduction of Fuel Consumption -In the Case of Training Ship Pusan 402- (연료 절감을 위한 최적운전 조건 -신습선 부산 402호의경우-)

  • Kim, Yeong-Sik;Kim, Sam-Kon;Yoon, Suck-Hun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.22 no.1
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    • pp.29-33
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    • 1986
  • This paper aims at finding out the optimum operating condition to reduce fuel consumption for the training ship Pusan 402 with controllable pitch propeller. For this purpose, this paper examints the variation of ship speed and fuel consumption in accordance with the change of engine revolution and propeller pitch. The results obtained are as follows: 1. When engine revolution is constant, the ship speed sluggishly increases according to the increase of propeller pitch but fuel consumption extremely increases. The higher revolution the engine is, the more remarkable this tendency is. 2. As the engine revolution becomes lower, the fuel consumption per mile decreases. Howt.er = the fuel consumption under the same engine revolution differs according to the propeller pitch. 3. Specific fuel consumption is uniformed about 180g/ps.h at any case of load. 4. Among the various operating conditions which yield the same ship speed, fuel consumption lowers in the case of lower engine revolution and larger propeller pitch.

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FEM Analysis on Temperature Distribution and Thermal Stress of a Brake Drum for Large Commercial Vehicle (대형 상용차용 브레이크 드럼의 온도 분포 및 열응력에 관한 유한요소 해석)

  • Kim, Ho-Kyung;Lee, Young-In;Joo, Se-Min
    • Journal of the Korean Society of Safety
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    • v.21 no.6 s.78
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    • pp.7-13
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    • 2006
  • A transient heat transfer and thermal stress analysis for a brake drum of commercial vehicles have been performed by ANSYS code in the cases of single braking and the repeated braking condition. The temperature and thermal stress distributions in the brake drum under various braking conditions were obtained using a two-dimensional axisymmetric model. In case of deceleration of 0.3G with an initial vehicle speed of 60km/h, the maximum temperature in the drum was $87.6^{\circ}C$ after braking application. The maximum stress of 78.7MPa in the drum occurred at the intersection between the flange and hat under a condition in which repeated 15 cycles braking with an initial vehicle speed of 60km/h and a deceleration of 0.3G is applied to according to KS R1129. The maximum stress value is much lower than the yield strength of drum material(FC250).

Numerical Analysis of Extrusion Processes of Particle Filled Plastic Materials Subject to Slip at the Wall (미끄럼현상을 갖는 입자충전 플라스틱재료의 압출공정 수치해석)

  • 김시조;권태헌
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2585-2596
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    • 1994
  • Many particle filled materials like Poweder/Binder mixtures for poweder injection moldings, have complicated rheological behaviors such as an yield stress and slip phenomena. In the present study, numerical simulation programs via a finite element method and a finite difference method were developed for the quasi-three-dimensional flows and the two-dimensional flow models, respectively, with the slip phenomena taken into account in terms of a slip velocity. In order to qualitatively understand the slip effects, typical numerical results such as vector plots, pressure contours in the cross-channel plane, and isovelocity controus for the down-channel direction were discussed with respect to various slip coefficients. Slip velocities along the boudary surfaces were also investigated to find the effects of the slip coefficient and processing conditions on the overall flow behavior. Based on extensive numerical calculations varying the slip coefficients, pressure gradient, aspect ratio, and power law index, the screw characteristics of the extrusion process were studied in particular with comparisons between the slip model and non-slip model.