• Title/Summary/Keyword: yield conditions

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Estimation of Failure Probability Using Boundary Conditions of Failure Pressure Model for Buried Pipelines (파손압력모델의 경계조건을 이용한 매설배관의 파손확률 평가)

  • Lee, Ouk-Sub;Kim, Eui-Sang;Kim, Dong-Hyeok
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.310-315
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    • 2003
  • This paper presents the effect of boundary condition of failure pressure model for buried pipelines on failure prediction by using a failure probability model. The first order Taylor series expansion of the limit state function is used in order to estimate the probability of failure associated with various corrosion defects for long exposure periods in years. A failure pressure model based on a failure function composed of failure pressure and operation pressure is adopted for the assessment of pipeline failure. The effects of random variables such as defect depth, pipe diameter, defect length, fluid pressure, corrosion rate, material yield stress, material ultimate tensile strength and pipe thickness on the failure probability of the buried pipelines are systematically studied by using a failure probability model for the corrosion pipeline.

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Performance Analysis of R744 (Carbon Dioxide) Transcritical Refrigeration System Using Internal Heat Exchanger (내부 열교환기를 이용한 R744용 초임계 냉동사이클의 성능 분석)

  • Son, Chang-Hyo;Oh, Hoo-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.4
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    • pp.459-465
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    • 2009
  • This paper considers the influence of internal heat exchangers to the efficiency of a refrigerating system. These internal heat exchangers(liquid-suction or suction-line heat exchangers) can, in some cases, yield improved system performance while in other cases they degrade system performance. A steady state mathematical model is used to analysis the performance characteristics of refrigeration system with internal heat exchanger. The influence of operating conditions, such as gas cooler pressure and evaporation temperatures, superheat in the evaporator and temperature of gas cooler outlet, to optimal dimensions of the heat exchanger is also analyzed in the paper. The main results were summarized as follows : the mass flowrate of R744, inner diameter tube and length of internal heat exchanger, and effectiveness have an effect on the cooling capacity, compressor work and RCI(Relative capacity index) of this system. With a thorough grasp of these effect, it is necessary to design the R744 compression refrigeration cycle using internal heat exchanger.

Surface polishing of Micro channel using Magneto-Rheological fluid (MR유체를 이용한 미세 채널구조물의 표면연마)

  • 이승환;김욱배;민병권;이상조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1873-1876
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    • 2003
  • Magneto-rheological polishing is a new technology used in precision polishing. It utilizes magneto-rheological fluid. nonmagnetic polishing abrasive, aqueous carrier fluids in magnetic field to remove material from a part surface. Silicon micro channel as work piece is fixed in the slurry which is made of MR fluid and CeO$_2$(10 vol%) abrasive particles. And permanent magnet rotate in the slurry to transfers magnetic force to abrasive particles by increasing yield strength of MR fluid. so, the obtained bottom surface roughness of micro channel by experiment reduced to Ra 0.010 $\mu\textrm{m}$ Rmax 0.103 $\mu\textrm{m}$ and finwall surface roughness of micro channel reduced to Ra 0.018 $\mu\textrm{m}$ Rmax 0.468 $\mu\textrm{m}$. At optimum conditions of variables, the workpiece as silicon micro channel have about 24 times smaller surface roughness than before polishing.

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Story of Johnsongrass Mosaic (Poty)virus in Australia

  • Oh, Hae-Young
    • Journal of Life Science
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    • v.12 no.2
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    • pp.61-74
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    • 2002
  • One of the major aims in studying plant viruses is to minimise the development of symptoms in infected plants. With the advent of in vitro transcript mediated research on plant viruses, substantial progress has been made. This article describes the biology of a plant specific RNA virus, Johnsongrass mosaic virus (JGMV), important to Australian sorghum and corn agriculture and, in particular, at a molecular level which of the RNA sequences in its genome that make it possible for the virus to move from cell to cell, and eventually spread systemically throughout the entire plant. The JGMV has caused considerable yield losses in maize and sorghum over a number of years in Australia. Incidents where 100% of the crop has been infected are on record. The use of this virus is convenient under laboratory conditions because it can be readily transmitted by mechanical inoculation with infected leaf sap, which obviates the need for maintaining aphid colonies. The JGMV is a single stranded positive sense RNA virus.

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Studies on the Characteristics of Humic Acid and its Utilizations (I) (土炭 흄酸의 性狀 및 應用에 關한 硏究 (I) 흄酸의 溶出 및 그 條件에 따른 흄酸性狀의 變異)

  • Kim, Won-Taik
    • Journal of the Korean Chemical Society
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    • v.12 no.4
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    • pp.155-159
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    • 1968
  • On the extraction of humic acid from peat, the optimum conditions were studied and the effects of them on the characteristics of humic acid were also examined by means of infrared spectroscopy. 1. Pretreatment of peat with diluted 6-8% HCl solution for 5 hrs. prior to extraction with alcohol-benzol azeotropic mixture have resulted the better yield of humic acid. The water soluble Na-humates were obtained by the subsequent extraction with one hundred times quantity of caustic soda solutieon for 1hr. at 90 $^{\circ}C$. Thus the pure humic acids have been yielded approximately 40% (by wt.) from the raw peat. 2. In characteristics of humic acid, the chemical structure, mainly the contents of such functional groups as -COOH, -OH (phenol type), $-CH_2CO-$, $-CH_2{\cdot}O{\cdot}CH_2-$ and aromatic rings were varied according to the concentration of alkaline solution, temperature and time when the humic acids were extracted with alkali.

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Oxidation of Aromatic Aldehydes with Tetrabutylammonium Fluoride:Competition with the Cannizzaro Reaction

  • Chung, Kyoo-Hyun;Lee, Jae Hak;Chi, Dae Yoon;Moon, Byung-Chul;Lim, Choong Hwan;Kim, Jin Pil
    • Bulletin of the Korean Chemical Society
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    • v.27 no.8
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    • pp.1203-1205
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    • 2006
  • During the synthesis of 4-fluorobenzaldehyde via the SNAr reaction of 4-nitrobenzaldehyde with TBAF, it was found that an equivalent amount of TBAF could oxidize benzaldehyde to benzoic acid. The reaction of 4-nitrobenzaldehyde with tetrabutylammonium fluoride (TBAF) gave 4-nitrobenzoic acid in high yield. Depending on the reaction conditions, other aromatic aldehydes produced acids with fewer amounts of alcohols. However, this type of oxidation has limited practical applications. Nevertheless, the mechanism is quite different from the Cannizzaro reaction because the amounts of the acid salt and alcohol formed were different.

Studies Towards Intramolecular Formal Iron-Catalyzed [4+2] Cycloaddition of Acetylenic Dienes (Fe(0) 촉매를 이용한 Acetylenic Dienes 의 분자내 [4+2] 고리화 첨가반응에 관한 연구)

  • Byeon, Sang Yong
    • Journal of the Korean Chemical Society
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    • v.38 no.1
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    • pp.61-68
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    • 1994
  • The intramolecular formal iron-catalyzed [4+2] cycloaddition reaction of acetylenic dienes to produce bicyclic products has been investigated. These reactions proceeded, competing via intramolecular carbocyclization and bimolecular cycloaddition. However, the iron-catalyzed bicyclic carbocyclization of 4,4-dimethyl-3-(tert-butyldimethylsiloxy)-1-phenyl-6,8-decadien-1-yne(11) yielded exclusively bicyclic diene product(yield 78.1%). From this result, we found that the substrate containing a dimethyl substitutent at the 4,4-position helped to promote the intramolecular reaction, which is stable to the iron catalyzed conditions.

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A Green Protocol for Catalytic Conversion of Epoxides to 1,2-Diacetoxy Esters with Phosphomolybdic Acid Alone or Its Supported on Silica Gel

  • Zeynizadeh, Behzad;Sadighnia, Leila
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2644-2648
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    • 2010
  • Catalytic conversion of structurally different epoxides to the corresponding 1,2-diacetoxy esters was carried out readily with phosphomolybdic acid alone or its supported on $SiO_2$. The reactions were carried out under solvolytic or solvent free conditions within 5-15 min at room temperature. The product 1,2-diacetates were obtained in high to excellent yields. Supporting of phosphomolybdic acid on $SiO_2$ showed the better catalytic activity than $Al_2O_3$. Conversion of optically pure R-(+)-styrene oxide to S-(+)-1,2-diacetoxy-1-phenylethane was carried with phosphomolybdic acid in high yield and stereospecificity.

Accuracy of Capacity Spectrum Method for Building Structures (건축 구조물에 대한 능력스펙트럼법의 정확성 연구)

  • Min, Kyung-Won;Lee, Sang-Hyun;Park, Min-Kyu;Lee, Young-Chul;Jung, Ran
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2003.04a
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    • pp.27-34
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    • 2003
  • Capacity Spectrum Method (CSM) defined in ATC-40 or FEMA-273 is a most widely used static inelastic analysis method to evaluate the performance level of the existing structures. In CSM, however, uncertainties and errors exist when lateral forces such as earthquake and wind loads are analyzed into equivalent static loads. This paper examines the accuracy of CSM for different structural parameters, such as natural frequency, yield strength and hardening ratio, and various soil conditions by comparing the estimated values to exact solutions obtained by time history analysis. Results indicate that the accuracy of CSM, in general, is influenced mostly by hardening ratio.

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Extraction of Oleoresin from Korean Red Pepper (고추 Oleoresin의 추출에 관한 연구)

  • 장성준;한성연;주제선
    • Journal of the East Asian Society of Dietary Life
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    • v.3 no.2
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    • pp.155-163
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    • 1993
  • This study was conducted to investigate the optimal condition of the extraction of red pepper oleoresin. The yield of oleoresin form red pepper was 24~28% when it was extracted by ethanol and methanol. and 8~10% by acetone, ethylene dichloride and n-hexane. But more than 60% of portion in alcohol extracts were moisture and sugars. Capsaicin and pigment were extracted more than 70% of those in red pepper when it was extracted by ethylene dichloride Those useful components were extracted most efficiently by mixed solvents of ethanol and ethylene dichloride at the ratio of 50:150. other extracting conditions were investigated in this studies, such as optimal extraction time was more than 3 hours, temperature was 55$^{\circ}C$ and particle size was finer than 250 mesh

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