• Title/Summary/Keyword: work of adhesion

Search Result 340, Processing Time 0.027 seconds

EFFECT OF CARBON FIBER SURFACE PROPERTIES ON FIBER-MATRIX ADHESION OF THE COMPOSITES

  • Kim Mun-Han;Park Su-Jin;Lee Jae-Rak;Choe Seon-Ung
    • Proceedings of the Korean Society For Composite Materials Conference
    • /
    • 1999.11a
    • /
    • pp.40-43
    • /
    • 1999
  • Electrochemical surface treatment of PAN-based carbon fibers in acidic electrolyte has been studied in increasing the surface functional groups on fiber surfaces for the improvement of fiber-matrix adhesion of the resulting composites. According to the FT-IR and XPS measurements, it reveals that the oxygen functional groups on fibers are largely influence on the composite mechanical behaviors, whereas the nitrogen functional groups are not affected in the system. In this work, a good correlation between surface functionality and mechanical properties is established.

  • PDF

Fundamental Studies on the Treatment of Particulate Organic Substances Contained in Wastewater by Flotation (부유선별법에 의한 폐수 함유 입자성 유기 물질 처리에 대한 기초 연구)

  • Yoo, Jung-Min;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
    • /
    • v.29 no.5
    • /
    • pp.674-680
    • /
    • 2013
  • Basic studies for the treatment of particulate organic substances contained in wastewater by flotation have been conducted. Four kinds of plastics were chosen as the possibly existing organic particles in wastewater and the Zisman plots for these substances were constructed by measuring the contact angle of liquids on their surfaces. The critical surface tensions for these organic substances were estimated based on the constructed Zisman plot and the floatability of organic substances were regarded to be related with their molecular structure. The existence of dissolved organic substances such as a surfactant was observed to affect the extent of flotation of particulate organics. In addition, the consideration of work of adhesion was thought to be better than adopting the critical surface tension as the analytical basis in the operational design of flotation process of organic particles.

Interfacial Evaluation of Plasma-Treated Biodegradable Poly(p-dioxanone) Fiber/Poly(L-lactide) Composites Using Micromechanical Technique and Dynamic Contact Angle Measurement (Micromechanical 시험법과 동적접촉각 측정을 이용한 플라즈마 처리된 생분해성 Poly(p-dioxanone) 섬유강화 Poly(L-lactide) 복합재료의 계면물성 평가)

  • Park, Joung-Man;Kim, Dae-Sik;Kim, Sung-Ryong
    • Journal of Adhesion and Interface
    • /
    • v.4 no.1
    • /
    • pp.18-27
    • /
    • 2003
  • Interfacial properties and microfailure degradation mechanisms of the oxygen-plasma treated biodegradable poly(p-dioxanone) (PPDO) fiber/poly(L-lactide) (PLLA)composites were investigated for the orthopedic applications as implant materials using micromechanical technique and surface wettability measurement. PPDO fiber reinforced PLLA composite can provide good mechanical performance for long hydrolysis time. The degree of degradation for PPDO fiber and PLLA matrix was measured by thermal analysis and optical observation. IFSS and work of adhesion, $W_a$ between PPDO fiber and PLLA matrix showed the maximum at the plasma treatment time, at 60 seconds. Work of adhesion was lineally proportional to the IFSS. PPDO fiber showed ductile microfailure modes at We initial state, whereas brittle microfailure modes appeared with elapsing hydrolysis time. Interfacial properties and microfailure degradation mechanisms can be important factors to control bioabsorbable composites performance because IFSS changes with hydrolytic degradation.

  • PDF

Synthesis and Surface Properties of Hierarchical SiO2 Coating Layers by Forming Au Nanoparticles (금 나노입자 형성을 이용한 계층구조 SiO2 코팅층의 제조 및 표면 특성)

  • Kim, Ji Yeong;Kim, Eun-Kyeong;Kim, Sang Sub
    • Korean Journal of Materials Research
    • /
    • v.23 no.1
    • /
    • pp.53-58
    • /
    • 2013
  • Superhydrophobic $SiO_2$ layers with a micro-nano hierarchical surface structure were prepared. $SiO_2$ layers deposited via an electrospray method combined with a sol-gel chemical route were rough on the microscale. Au particles were decorated on the surface of the microscale-rough $SiO_2$ layers by use of the photo-reduction process with different intensities ($0.11-1.9mW/cm^2$) and illumination times (60-240 sec) of ultraviolet light. With the aid of nanoscale Au nanoparticles, this consequently resulted in a micro-nano hierarchical surface structure. Subsequent fluorination treatment with a solution containing trichloro(1H,2H,2H,2H-perfluorooctyl)silane fluorinated the hierarchical $SiO_2$ layers. The change in surface roughness factor was in good agreement with that observed for the water contact angle, where the surface roughness factor developed as a measure needed to evaluate the degree of surface roughness. The resulting $SiO_2$ layers revealed excellent repellency toward various liquid droplets with different surface tensions ranging from 46 to 72.3 mN/m. Especially, the micro-nano hierarchical surface created at an illumination intensity of $0.11mW/cm^2$ and illumination time of 60 sec showed the largest water contact angle of $170^{\circ}$. Based on the Cassie-Baxter and Young-Dupre equations, the surface fraction and work of adhesion for the micronano hierarchical $SiO_2$ layers were evaluated. The work of adhesion was estimated to be less than $3{\times}10^{-3}N/m$ for all the liquid droplets. This exceptionally small work of adhesion is likely to be responsible for the strong repellency of the liquids to the micro-nano hierarchical $SiO_2$ layers.

The Effect of Plasma Treatment on Surface Properties and Adhesion Characteristics of semiconductive Silicone Rubber (반도전성 실리콘 고무의 표면 특성과 접착특성에 미치는 플라즈마 처리의 영향)

  • Hwang, Sun-Mook;Hong, Joo-Il;Hwang, Cheong-Ho;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.254-255
    • /
    • 2005
  • In this work, the effects of plasma treatment on surface properties of semi conductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy(XPS). The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths. As a result, semiconductive silicone rubber surfaces treated with plasma discharge led to and increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. these results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semi conductive silicone rubber.

  • PDF

Copper Electroplating on Mg Alloy in Pyrophosphate Solution

  • Van Phuong, Nguyen;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2016.11a
    • /
    • pp.124.1-124.1
    • /
    • 2016
  • In this work, uniform thickness and good adhesion of electrodeposited copper layer were achieved on AZ91 Mg alloy in alkaline noncyanide copper solution containing pyrophosphate ion by employing appropriate zincate pretreatment. Without zincate pretreatment, the electrodeposited copper layer on AZ91 Mg alloy was porous and showed poor adhesion which was explained by small number of nucleation sites of copper due to rapid dissolution of the magnesium substrate in the pyrophosphate solution. The zincate pretreatment was found as one of the most important steps that can form a conducting layer to cover AZ91 surface which decreased the dissolution rate of AZ91 Mg alloy about 40 times in the copper pyrophosphate solution. Electrodeposited copper layer on AZ91 Mg alloy after an appropriate zincate pretreatment showed good adhesion and uniform thickness with bright surface appearance, independent of the deposition time but the surface roughness of the electrodeposited copper layer increased with increasing Cu deposition time.

  • PDF

Wettability and Adhesion of Noble Metal (Au, Ag)-Glass Systems (귀금속(금, 은)-유리계의 젖음성과 부착성)

  • 김종희
    • Journal of the Korean Ceramic Society
    • /
    • v.32 no.4
    • /
    • pp.405-412
    • /
    • 1995
  • In order to estimate the wettability of the borosilicate glasses with different composition on the noble metals of gold and silver, the measurements of the contact angle between the solid and the liquid were made at various temperatures and holding times using the sessil-drop method. The wetting behavior and the adhesion of the phases were strongly influenced by the thermal or the physical characteristics of the materials. The dependence of wetting angle ($\theta$) on the holding time (t) could be represented by the relation of $\theta$=a.tb, whereby the wettability of the systems was quantitatively compared. Also with increasing content of borosilicate glass in the glass-gold matrix composite, the tensile strength was decreased whereas the elastic modulus was increased.

  • PDF

Improvement of Coating Adherence of Hot-dip Galvanized Sheet Steels (용융아연 도금강판의 도금밀착성 개선)

  • 김종상;배대철
    • Journal of the Korean institute of surface engineering
    • /
    • v.24 no.1
    • /
    • pp.18-24
    • /
    • 1991
  • In the present work the adhesion failure of a hot-dip galvanized coating has been studied as a function gas composition temperature of strip and of atmospheric gas in furnace. The adhesion failure of the hot-dip galvani-zed coating is classified as three mechanisms : carbon deposition, oxide film formation and alloy layer formation. The adhesion failure due to oxide film formation decreased markedly by increasing the gases temperature of direct fired furnace(DFF) in order to improve the reducing ability of steel strip. Optimum conditions of operating and manufacturing facilities for improving the coating adherence are suggested by analyzing the interface between steel substrate and coating layer.

  • PDF

Focus on anti-oxidative and free radical scavenging activity of Ganoderma lucidum

  • Lin, Zhi-Bin
    • Proceedings of the Korean Society of Applied Pharmacology
    • /
    • 2004.04a
    • /
    • pp.61-77
    • /
    • 2004
  • Present review is built on base of research work on Ganoderma lucidum in our laboratory. A great deal of experimental evidence has suggested that the pharmacological activities of Ganoderma lucidum(Lingzhi) are related to anti-oxidative and free radical scavenging activity. The anti-oxidative and free radical scavenging effects of polysaccharides and triterpenoids isolated from Ganoderma lucidum in different oxidative injury models including tert-butylhydroperoxide (tBOOH)- damaged mice peritoneal macrophages, alloxan-induced diabetes, experimental liver injury models induced by carbon tetrachloride (CC14), D-galactosamine (DGal) and Bacillus Calmette-Guerin(BCG) plus lipopolysaccharides(LPS) were investigated. It is also demonstrated that Lugu lingzhi, one of Ganoderma product, significantly inhibited LDL oxidation mediated by endothelial cells and decreased monocyte adhesion to endothelial cell (EC) induced by Oxidative low-density lipoprotein (ox-LDL) and advanced glycation endproducts(AGE). Lugulingzhi-treated serum could markedly inhibit the expression of intercellular cell adhesion molecule-l (ICAM-1) and vascular cell adhesion molecule-l (VCAM-1) induced by ox-LDL and AGE.

  • PDF