• Journal of the Korea Furniture Society
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• v.15 no.2
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• pp.1-17
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• 2004

This paper attempted to review measuring methods of formaldehyde emission from wood-based panel products. Methods included for the discussion were desiccator methods, extraction method, and various chamber methods. First, the procedures and testing conditions of 24-hour desiccator method was critically reviewed, and an improvement of this method was proposed to meet international standards. Two different small chamber methods ($20\ell$ and $1m^3$ chamber methods) were also compared in terms of their advantages and disadvantages. In addition, the regulation levels of formaldehyde emission of wood-based composite panels were compared for different countries. The selection of a reference method of measuring formaldehyde emission of wood panel products should consider the ease of conducting test and cost required. Results should be exchangeable for different methods.

• Journal of the Korean Wood Science and Technology
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• v.25 no.4
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• pp.29-38
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• 1997

The effect and control of wood property of reconstituted composite panels for improved board properties by wood-waste materials and development of combination method for heterogeneous materials have been of interest to the wood science researchers. The purpose of this study is to consider the properties in relation to hot pressing conditions and to develope the optimum hot pressing condition with waste wood and waste tire for the manufacturing of composite boards. The study of composite boards for recycling of wood and waste tire is nothing up to the present. Physical and mechanical properties such as specific gravity, moisture content, swelling coefficient, modulus of rupture and modulus of elasticity in bending test were studied. The condition of 3-stage press time for the lowest moisture content of composite board was $4{\rightarrow}3{\rightarrow}3$ minutes. Specific gravity of composite panels was affected mainly by the amount of rubber chip. Because of the low rigidity and high elasticity in rubber chip, it is considered the composite panel was adequate material in the place of compression load, but not bending load. Therefore, it was concluded that a use of rubber-based wood composite panel is proper to the interior materials such as floor a room than exterior materials. From the test results, the most optimum hot pressing conditions were $4{\rightarrow}3{\rightarrow}3$ minutes for 3-stage press time and $45{\rightarrow}20{\rightarrow}5kg/cm^2$ for 3-stage press pressure. The rubber-based wood composite panel was very excellent in elasticity by combination of rubber chip in comparison with existing other wood-based materials. Therefore, it was considered that rubber-based wood composites can be applicable to every interior materials such as floor a room and will be expected to effective reuse and recycle of waste tires and wood-waste materials, and will be contribute to protection of environment pollution in earth.

• Composites Research
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• v.28 no.2
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• pp.58-64
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• 2015

The purpose of this paper is to suggest the effective equivalent finite element model for the impact limiter of a nuclear spent fuel shipping cask made of sandwich composite panels. The sandwich composite panels were composed of a metallic facesheet and a core material made of urethane foam, balsa wood and red wood, respectively. The effective equivalent finite element model for the impact limiter was proposed by comparing the results of low-velocity impact test of sandwich panels. An explicit finite element analysis based on LS-DYNA 3D was done in this study. The results showed that the solid elements were recommended to model the facesheet and core of sandwich panels for impact limiter compared to combination modeling method, in which the layered shell element for facesheet and solid element for core material are used. In particular, the solid element for balsa and red wood core materials should be modeled by the element elimination approach.

• Journal of the Korean Wood Science and Technology
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• v.44 no.3
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• pp.424-429
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• 2016

In this study, the carbonized boards were manufactured from different types of wood-based panel and then their moisture absorption/desorption properties were investigated and compared. The carbonization temperature was maximum $600^{\circ}C$ with 2 h maintains. Test results showed higher absorption/desorption capacity on carbonized plywood than carbonized MDF, PB, and OSB, respectively. However, carbonized MDF, OSB, and plywood had similar absorption/desorption rate per hour. It means carbonized OSB and plywood can transfer moisture into deeper side and then possibly hold more amount of water. Based on SEM images, carbonized OSB and plywood showed more like wood structure, while carbonized MDF and PB had only wood fiber or/and chunk of wood fragments. Therefore, original wood structure may affect moisture absorption/desorption capacity. In order to manufacture high moisture absorbing/desorbing carbonized board, wood structure should be considered and then carbonized.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.E2
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• pp.57-65
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• 2007

In Korea, there is a general lack of information available on air emissions from industry. The reasons for this include the lack of regulatory requirements for emission monitoring, limited information on specific industries, and difficulties in monitoring certain sources. This paper presents the first detailed air pollutant emission factors from composite wood product manufacturing in Korea. This study introduced emission factors for wood-based panels such as plywood, particle board (PB), and medium density fiberboard (MDF). The emission factors of particulate matters (PM) and hazardous air pollutants (HAPs) from MDF were higher than that from other wood products. The concentration of total volatile organic compounds (TVOCs) for hot press from wood-based panels was higher than drying or gluing processes. Emissions data from NPIP were compared to the data from the suggested emission factors in this study and the US EPA's. The data from our emission factors were closer to the observed results than the data using the US EPA's emission factor.

• Journal of the Korean Wood Science and Technology
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• v.33 no.2 s.130
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• pp.29-39
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• 2005

Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

• Journal of the Korean Wood Science and Technology
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• v.38 no.4
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• pp.323-332
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• 2010

Petroleum-based adhesive resins have extensively been used for the production of wood panels. However, it is necessary to develop environmentally friendly adhesive resins due to the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the pertroleum-based adhesive resins. This study was conducted to formulate environmentally friendly adhesive resins using by rapeseed flour (RSF), which is the by-product of bio-diesel produced from rapeseed, for replacing petroleum-based adhesives with them. To formulate RSF-based adhesive resins, RSF was hydrolyzed in de-ionized water, 1% and 3% sodium hydroxide solutions. As a crosslinking agent, PF prepolymers were prepared with 1.8, 2.1 and 2.4 mol formaldehyde and 1 mol phenol (1.8-, 2.1- and 2.4-PF), and then mixed with RSF hydrolyzates to complete the formulation of RSF-based adhesive resins. The RSF-based adhesive resins were applied to fabricate 3-ply plywood panels. The solid content of RSF-based adhesive resins were ranged from 26.08% to 36.12% depending on the hydrolysis condition of RSF and PF prepolymer type with a high viscosity. The tensile shear strength and wood failure of plywood fabricated with RSF-based adhesive resins exceeded a minimum requirement of KS standard for ordinary plywood regardless of the hydrolysis condition of RSF and PF prepolymer type. Formaldehyde emissions of the plywood panels fabricated with 1.8-PF and RSF hydrolyzates were lower than that of E0 specified in the KS standard. Based on the results, RSF might be used as a raw material of environmentally friendly adhesives for the production of plywood panels, but further researches - the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure - are required to commercialize the RSF-based adhesives.

• Journal of the Korean Wood Science and Technology
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• v.47 no.2
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• pp.129-144
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• 2019

This study aimed at developing an accelerated collection method that reduces measurement and collection time by improving and complementing the desiccator method, which is mainly used for quality control in wood-based panels and furniture production sites. First, this study measured the formaldehyde emissions from the wood-based panels by grade using the desiccator method. Further, this study compared the desiccator method with the developed process and analyzed the correlation in optimal temperature, time, and exposed area. The results showed that the developed process resulted in relatively similar outcomes in comparison to the desiccator method when the temperature was $100^{\circ}C$, the time was 1 h, and two specimens were used, at which the correlation was high. To verify the developed process, this study commissioned Korea Conformity Laboratories with the standardized temperature, time, and the number of specimens to compare them with the specimen that was not used in the actual test. As a result, the correlation to the desiccator method was shown to be very high. However, the formaldehyde emission measured by the accelerated collection process was mostly higher than that measured by the desiccator method. The formaldehyde emission grades from several specimens were one level higher. However, from the perspectives of quality control, it was determined that the accelerated collection method developed in this study could be sufficiently used.

• Journal of the Korean Wood Science and Technology
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• v.29 no.3
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• pp.36-46
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• 2001

This study was to find a way of reusing wood and plastic wastes, which considered as a troublesome problem to be solved in this age of mass production and consumption, in manufacturing wood fiber-polypropylene fiber composite panel. And the feasibility of this composite panel as a substitute for existing headliner base panel of automobile was also discussed, especially based on physical and mechanical performance. Nonwoven web composite panels were made from wood fiber and polypropylene fiber formulations of 50 : 50, 60 : 40, and 70 : 30, based on oven-dry weight, with densities of 0.4, 0.5, 0.6, and 0.7 g/$cm^3$. At the same density levels, control fiberboards were also manufactured for performance comparison with the composite panels. Their physical and mechanical properties were tested according to ASTM D 1037-93. To elucidate thickness swelling mechanism of composite panel through the observation of morphological change of internal structures, the specimens before and after thickness swelling test by 24-hour immersion in water were used in scanning electron microscopy. Test results in this study showed that nonwoven web composite panel from wood fibers and polypropylene fibers had superior physical and mechanical properties to control fiberboard. In the physical properties of composite panel, dimensional stability improved as the content of polypropylene fiber increased, and the formulation of wood fiber and polypropylene fiber was considered to be a significant factor in the physical properties. Water absorption decreased but thickness swelling slightly increased with the increase of panel density. In the mechanical properties of composite panel, the bending modulus of rupture (MOR) and modulus of elasticity (MOE) appeared to improve with the increase of panel density under all the tested conditions of dry, heated, and wet. The formulation of wood fiber and polypropylene fiber was considered not to be a significant factor in the mechanical properties. All the bending MOR values under the dry, heated, and wet conditions met the requirements in the existing headliner base panel of resin felt.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.30-38
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• 2008

Petroleum-based resin adhesives have extensively been used for the production of wood panels. However, with the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the adhesive resins, it is necessary to be developed new adhesive systems. In this study, the potential of okara, which is a residue wasted from the production of tofu, for the development of bio-based adhesives was investigated. At first, the physical and chemical properties of okara were examined. After okara was hydrolyzed in acidic and/or alkaline solutions, okara-based adhesive resins were formulated with the mixtures of the okara hydrolyzates and phenol formaldehyde (PF) prepolymer. The adhesive resins were used for the fabrication of plywood panels, and then the adhesive strength and formaldehyde emission of the plywood panels were measured to examine the applicability of the resin adhesives for the production of plywood panels. The solids content and pH of the okara used in this study were around 20% and weak acidic state, respectively. In the analysis of its chemical composition, the content of carbohydrate was the highest, and followed by protein. The shear strengths of plywood fabricated with okara-based resin adhesives exceeded a minimum requirement of KS standard for ordinary plywood, but its wood failure did not reach the minimum requirement. In addition, the formaldehyde emissions of all plywood panels were higher than that of E1 specified in the KS standard. Based on these results, okara has the potential to be used as a raw material of environmentally friendly adhesive resin systems for the production of wood panels, but further researches - biological hydrolysis of okara and various formulations of PF prepolymer - are required to improve the adhesive strength and formaldehyde emission of okara-based resin adhesives.