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A Study over Catalytic Behavior Octane Enhancer, TAME Synthesis with Ion Exchange Resin Catalysts (이온교환수지 촉매를 이용한 옥탄가 향상제인 TAME 합성반응의 연구)

  • Park, Jin-Hwa
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.832-842
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    • 1996
  • TAME synthesis was studied in a fixed bed reactor with 3 different types of exchanged resins i.e, Amberlyst-15, Amberlyst-15(wet) and Amberlyst XN-1010. Amberlyst-15 has highest activity, presumably due to the higher reaction participation of the inner active sites of gel shape microparticular resin structure. The optimum reaction conditions for TAME synthesis were found as follows ; reaction temperature of $135^{\circ}C$, molar ratio(MeOH/I.A.A) of 1.0~4.0 and W/F of 2.0~4.0 gr.-cat. hr/gr.-mole. The cross-linking bond of styrene divinyl benzene was observed at $2{\theta}=20$ in XRD pattern. The DSC analysis showed that the thermal stability was in order of Amberlyst-15>Amberlyst-15(wet)>Amberlyst XN-1010. The apparent activation energies of TAME synthesis reaction with Amberlyst-15, Amberlyst-15(wet) and Amberlyst XN-1010 were 12.36, 12.46 and 14.72 kcal/mole, respectively.

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How do the work environment and work safety differ between the dry and wet kitchen foodservice facilities?

  • Chang, Hye-Ja;Kim, Jeong-Won;Ju, Se-Young;Go, Eun-Sun
    • Nutrition Research and Practice
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    • v.6 no.4
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    • pp.366-374
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    • 2012
  • In order to create a worker-friendly environment for institutional foodservice, facilities operating with a dry kitchen system have been recommended. This study was designed to compare the work safety and work environment of foodservice between wet and dry kitchen systems. Data were obtained using questionnaires with a target group of 303 staff at 57 foodservice operations. Dry kitchen facilities were constructed after 2006, which had a higher construction cost and more finishing floors with anti-slip tiles, and in which employees more wore non-slip footwear than wet kitchen (76.7%). The kitchen temperature and muscular pain were the most frequently reported employees' discomfort factors in the two systems, and, in the wet kitchen, "noise of kitchen" was also frequently reported as a discomfort. Dietitian and employees rated the less slippery and slip related incidents in dry kitchens than those of wet kitchen. Fryer area, ware-washing area, and plate waste table were the slippery areas and the causes were different between the functional areas. The risk for current leakage was rated significantly higher in wet kitchens by dietitians. In addition, the ware-washing area was found to be where employees felt the highest risk of electrical shock. Muscular pain (72.2%), arthritis (39.1%), hard-of-hearing (46.6%) and psychological stress (47.0%) were experienced by employees more than once a month, particularly in the wet kitchen. In conclusion, the dry kitchen system was found to be more efficient for food and work safety because of its superior design and well managed practices.

Study on the Effect of Toxic Gas Filter Effect of Wet Towel during Fire (화재 시 젖은 수건의 유독가스 필터 효과에 관한 연구)

  • Sim, Jaeung;Cho, Nam-Wook
    • Fire Science and Engineering
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    • v.32 no.5
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    • pp.52-56
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    • 2018
  • The damage caused by fires is fatal as opposed to the damage caused by heat, and toxic gas generated by fires can be protected against by using a wet towel. In this study, we quantified the filtration effect of gas generated by an actual fire using a wet towel. In order to confirm the filtration effect of the wet towel on three harmful gases ($CO_2$, HCl, HCN), gases passed through a filter using FT-IR were analyzed in realtime. HCl and HCN, which are gases, were filtered by a wet towel, and the detection time of each gas was delayed. Therefore, it was confirmed that evacuation time can be secured by using a wet towel in the case of toxic gas, especially water-soluble gases in an actual fire.

The Role of Charge and Retention in Effective Wet end Management

  • Rantala, T.;Nokelainen J.;Ojala, T;Dr. Taina Sopenlehto
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.06a
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    • pp.1-10
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    • 2000
  • The development of paper machines, increasing machine speeds with new, mostly low basis weight and/or high ash content paper grades, as well as the fact that several trends regarding process items have increased the sensitivity of papermaking. At the same time, papermakers are looking for flexibility in the production line. We can say that with all PMs the biggest benefits with the lowest capital spending can be achieved by focusing on improved wet end management. In order to manage wet end chemistry on a paper machine, our goal is to control sub-process through which we can influence the operation of the entire wet end with maximum effect. Key measurements and controls are-white water consistency control which is the most effective way to control retention - charge demand measurement and control which takes care of concentration of the anionic material entering to PM -ash measurements and controls which are deeply related to retention and paper quality This paper presents and concentrates to two of these key controls ; retention and charge. The purpose of charge control is to give the process control the tools to react to changes caused by amount of dissolved and colloida material incoming to wet end system. It is called coagulation or fixing control. Retention control is then taking care of retention aid flow to the process by responding any changes seen in white water consistency. It is called flocculation control. Each of these solutions separately , and even more effectively all together, stabilize the wet end operations and so greatly improve the produced paper quality and machine runnability. Practical results will be presented and they are referring to the latest mill cases. We have developed the first wet end measuring system in the late 1980s and control solutions based on this modern measuring technology were completely updated in 1990s. This paper introduces the principle, operation , and results of our unique wet end analyzers (retention and charge ) which are at the level of automation solutions as a part of paper machine quality control Especially our newest member of the platform , on-line charge analyzer has reached and set new standards to the on-line charge monitoring.

The Role of Charge and Retention in Effective Wet End Management

  • Rantala, T.;Nokelainen, J.;Ojala, T.;Sopenlehto, Taina
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.5
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    • pp.44-53
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    • 2000
  • The development of paper machines, increasing machine speeds with new, mostly low basis weight and/or high ash content paper grades, as well as the fact that several trends regarding process items have increased the sensitivity of papermaking. At the same time, papermakers are looking for flexibility in the production line. We can say that with all PMs, the biggest benefits with the lowest capital spending can be achieved by focusing on improved wet end management. In order to manage wet end chemistry on a paper machine, our goal is to control subprocesses through which we can influence the operation of the entire wet end with maximum effect. Key measurements and controls are - white water consistency control which is the most effective way to control retention. - charge demand measurement and control which takes care of concentration of the anionic material entering to PM. - ash measurements and controls which are deeply related to retention and paper quality. This paper presents and concentrates to two of these key controls: retention and charge. The purpose of charge control is to give the process control the tools to react to changes caused by amount of dissolved and colloidal material incoming to wet end system. It is called coagulation or fixing control. Retention control is then taking care of retention aid flow to the process by responding any changes seen in white water consistency. It is called flocculation control. Each of these solutions separately, and even more effectively all together, stabilize the wet end operations and so greatly improve the produced paper quality and machine runnability. Practical results will be presented and they are referring to the latest mill cases. We have developed the first wet end measuring system in the late 1980s and control solutions based on this modern measuring technology were completely updated in 1990s. This paper introduces the principle, operation, and results of our unique wet end analyzers (retention and charge) which are at the level of automation solutions as a part of paper machine quality control. Especially our newest member of the platform, on-line charge analyzer has reached and set new standards to the on-line charge monitoring.

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Amount of bacteria over time according to the use of antibacterial and wet wipes behavior (항균티슈와 물티슈 사용에 따른 시간별 세균 수 변화의 차이)

  • Han, Su-Min;Kim, Eun-Ji;Seomoon, Hye-Ji;Lim, Su-Min;Han, Ji-Young;Koong, Hwasoo
    • Journal of Korean Dental Hygiene Science
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    • v.5 no.1
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    • pp.21-27
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    • 2022
  • Background: This study was conducted to analyze the time for re-detection of bacteria after surface disinfection using wet wipes, isopropyl alcohol, and benzalkonium chloride antibacterial tissue and provide standards for re-execution of surface disinfection with wet and antibacterial tissues. Methods: Seven laptops were wiped with wet tissue and isopropyl alcohol and benzalkonium chloride antibacterial tissues. Test areas were rubbed with a sterile cotton swab at baseline and after 30, 60, and 120 min. After plating on a tryptic soy agar medium, the number of colonies was counted by culturing at 36.5℃ for 24 h. Results: The average number of bacterial colonies was 5.85 ± 4.33 before isopropyl alcohol wiping and nil after wiping. The average number of bacterial colonies was 12.28 ± 14.67 benzalkonium chloride wiping and nil after wiping. Before wiping with wet wipes, the average number of bacterial colonies on laptop surfaces was 3.42 ± 5.22. Bacteria decreased after wiping with wet wipes but increased again over time. Conclusions: Wet wipes can temporarily reduce bacteria but are unsuitable for removing bacteria.

An Instance of Selecting Retention Chemicals Based on Simultaneous Analysis of Retention, Drainage and Formation of RDA (Retention and Drainage Analyzer) Sheets (보류, 탈수, 지합을 종합적으로 고려한 Retention and Drainage Analyzer (RDA) 활용 보류향상제의 선정사례)

  • Jeon, Chang-Hoon;Ryu, Jeong-Yong;Song, Bong-Keun;Seo, Young-Bum;Chung, Sung-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.7-13
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    • 2010
  • KOptimization and control of wet-end process provide a key solution to improve paper quality and production efficiency at the same time. Wet-end of paper machine is to determine three important influencing factors of papermaking i.e., retention, drainage and formation. Good formation of paper could be made at the cost of deteriorated retention or drainage. In the same manner increase of retention aid could cause the bad formation of paper. It is very important to find a proper retention chemical which may satisfy one of three factors without the sacrifice of other two. Laboratory scale analyzing or screening chemical additives of wet-end was reported in this study based on RDA sheet molding. Different from the conventional test method, simultaneous consideration of three important wet-end properties could be made by RDA and consequently more reliable prediction of actual paper machine wet-end could be expected.

Analysis of Water-quality Improvement Efficiency of Constructed Wetland Using NPS-WET Model (NPS-WET 모형을 이용한 인공습지의 수질정화효과 분석)

  • Rhee, Han-Pil;Jung, Kwang-Wook;Lee, Bok-Soo;Ham, Jong-Hwa;Son, Yeong-Kwon
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.320-331
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    • 2012
  • A combination system of catch canal and constructed wetland was designed and suggested to improve water quality in gagricultural region of lower Dong-jin river basin. In order to evaluate an water quality improvement efficiency of the designed combination system, the NPS-WET model was applied in this study. Simulation result of the NPS-WET shown that the nutrient load removal rate of constructed wetland was BOD, T-N, T-P and SS was 30.7~39.0%, 46~60%, 40.7~57.0% and 68.2~74.7%, respectively. Nutrients reduction of constructed wetland was higher in growing season than winter season because vital activity of microorganism, macrophyte and algae was augmented with high air and water temperature. Effluents from constructed wetland can affect water-quality of catch canal drains, especially, water-quality on junction point to Dong-jin river. Water-quality improvement in low-flowed catch canal (Un-san) was more significant than in high-flowed catch canal (Won-pyeong). In conclusion, a feasible design of constructed wetland is necessary to treat large quantity of receiving water. The NPS-WET is useful tool for assessing water-quality improvement efficiency using constructed wetland.

Change of Dimensional Stability and Dip Elongation of Handsheets Depending on Wet Pressing (습부압착에 따른 수초지의 치수안정성과 침지신장성의 변화)

  • Park, Chang-Soon;Lee, Jin-Ho;Kil, Jung-Ha;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.31-39
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    • 2011
  • One of the main drawbacks of wood fibers based composite materials are their tendency to swell due to moisture uptake in wet and moist environments. The main contribution to the hygroexpansion usually comes from the hydrophilic wood fibers. Recent trend toward the high speed printing, copying, and precision converting precesses demands a high level of dimensional stability under various environmental conditions. The purpose of this study was to investigate the dimensional stability of softwood bleached kraft pulp handsheets depending on wet pressing conditions. By increasing the number of wet pressing, dimensional stability was decreased because of increased fiber-to-fiber bonding. Hygroexpansion of handsheets had a linear relationship with the relative bonded area and equilibrium moisture contents. Dip elongation was decreased when the number of wet pressing was increased because of increased fiber-to-fiber bonding to resist low load in water.

Development of Dry/Wet Algorithm for 2-Dimensional Flow Analysis (2차원 흐름해석을 위한 마름/젖음 알고리듬의 개발)

  • Kim, Sang-Ho;Han, Kun-Yeun;Choi, Seung-Yong;Oh, Hyun-Uk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.624-628
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    • 2008
  • Two-dimensional flow analysis is a way to provide good estimates for complex flow features in flow around islands and obstructions, flow at confluence and flow in braided channel. One of difficult problems to develop a two-dimensional hydraulic model is to analyze dry and wet area in river channel. Dry/wet problem can be encountered in river and coastal engineering problems, such as flood propagation, dam break analysis, tidal processes and so on. The objective of this study is to develop an accurate and robust two-dimensional finite element method with dry/wet technique in complex natural rivers. The dry/wet technique with Deforming Grid Method was developed in this study. The Deforming Grid Method was used to construct new mesh by eliminating of dry nodes and elements. The eliminated nodes and elements were decided by considering of the rising/descending velocity of water surface elevation. Several numerical simulations were carried out to examine the performance of the Deforming Grid Method for the purpose of validation and verification of the model in rectangular and trapezoidal channel with partly dry side. The application results of the model were displayed reasonable flow distribution.

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