• Title/Summary/Keyword: wet-dry cycle

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Disintegration process and micro mechanism of mudstone under dry-wet cycles

  • Ji Chen;Ruyu Huang;Xinyu Luo;Xin Liao;Qiang Tang
    • Geomechanics and Engineering
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    • v.36 no.1
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    • pp.9-18
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    • 2024
  • With the rapid development of highways and railways, series of traffic safety issues emerged because of mudstone disintegration. To research on the mechanism and further guarantee the stability and safety of transportation infrastructure built on or near mudstone formations, the mudstone disintegration test of mudstone was carried out based on mudstone and sandy mudstone. The element types, cementation characteristics and pore characteristics of the tested specimens were studied by means of Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and Image Pro Plus (IPP). The disintegration index of mudstone was approximately 1%, and even some specimens were difficult to be calculated, while the disintegration index of sandy mudstone is approximately 8.7%. According to the results, the two mudstones belong to grade II and III disintegration respectively, of which the sandy stone presents more extensive disintegration than mudstone. This phenomenon was distinguished that, the clay minerals of mudstone are approximately 25% more abundant than those of sandy mudstone, and the unit pore area is 20 ㎛2 larger, which result in different microstructure and water absorption capacities. In the liquid phase, the ions in the mudstone specimens were exchanged and combined with water molecules in the environment during the whole disintegration process. This results in continuous spalling and fragmentation of clay minerals, the emergence of secondary fractures, and the deepening of primary fractures.

Development of the Vacuum Drying Process for the PWR Spent Nuclear Fuel Dry Storage (경수로 사용후핵연료 건식저장을 위한 진공건조공정 개발)

  • Baeg, Chang-Yeal;Cho, Chun-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.4
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    • pp.435-443
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    • 2016
  • This paper describes the development of a dry operation process for PWR spent nuclear fuel, which is currently stored in the domestic NPP's storage pool, using a dual purpose metal cask. Domestic NNPs have had experience with wet type transportation of PWR spent nuclear fuel between neighboring NPPs since the early 1990s, but no experience with dry type operation. For this reason, we developed a specific operation process and also confirmed the safety of the major cask components and its spent nuclear fuel during the dual purpose metal cask operation process. We also describe the short term operation process that was established to be completed within 21 hours and propose the allowable working time for each step (15 hours for wet process, 3 hours for drain process and 3 hours for vacuum drying process).

Life cycle impact assessment of the environmental infrastructures in operation phase: Case of an industrial waste incineration plant

  • Kim, Hyeong-Woo;Kim, Kyeong-Ho;Park, Hung-Suck
    • Environmental Engineering Research
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    • v.22 no.3
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    • pp.266-276
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    • 2017
  • A life cycle impact assessment was applied in an industrial waste incineration plant to evaluate the direct and indirect environmental impacts based on toxicity and non-toxicity categories. The detailed life cycle inventory of material and energy inputs and emission outputs was compiled based on the realistic data collected from a local industrial waste incineration plant, and the Korean life cycle inventory and ecoinvent database. The functional unit was the treatment of 1 tonne of industrial waste by incineration and the system boundary included the incineration plant and landfilling of ash. The result on the variation of the impact by the unit processes showed that the direct impact was decreased by 79.3, 71.6, and 90.1% for the processes in a semi dry reactor, bag filter, and wet scrubber, respectively. Considering the final impact produced from stack, the toxicity categories comprised 91.7% of the total impact. Among the toxicity impact categories, the impact in the eco-toxicity category was most significant. A separate estimation of the impact due to direct and indirect emissions showed that the direct impact was 97.7% of the total impact. The steam recovered from the waste heat of the incineration plant resulted in a negative environmental burden.

A Status of Technology and Policy of Nuclear Spent Fuel Treatment in Advanced Nuclear Program Countries and Relevant Research Works in Korea (선진 원자력발전국의 사용후핵연료 처리기술 및 정책현황과 우리나라의 관련연구 현황)

  • You, Gil-Sung;Choung, Won-Myung;Ku, Jeong-Hoe;Cho, Il-Je;Kook, Dong-Hak;Kwon, Kie-Chan;Lee, Won-Kyung;Lee, Eun-Pyo;Hong, Dong-Hee;Yoon, Ji-Sup;Park, Seong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.4
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    • pp.339-350
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    • 2007
  • Status on the spent nuclear fuel management policy and R&D plan of the major countries is surveyed. Also the prospect of the future R&D plan is suggested. Recently so-called fuel cycle nations, which have the reprocess policy of the spent fuel, announced new spent fuel management policy based on the advanced fuel cycle technology. The policy is focused to transmute highly radioactive material and material having a very long half-life, and to recycle the Pu and U contained in the spent fuel. In this way the radio-foxily of the spent fuel as well as the amount of the high level waste to be eventually disposed can greatly be reduced. Most of countries selected the wet process as a primary option for the treatment of the spent fuel since the advanced wet process, which is based on the existing PUREX process, looks more feasible as compared with the dry process. The wet process, however, is much more sensitive in terms of proliferation-resistance compared with the dry process. The pure Pu can easily be obtained by simply modifying the process. On the other hand the pure Pu can not be extracted in the dry process based on the high temperature molten salt process such as a pyroprocess. Even though the pyroprocess technology is very premature, it has a great merit. Thus it is necessary for Korea to have a long term strategy for pursuing a spent fuel treatment technology with a proliferation resistance and a great merit for the GEN-IV fuel cycles. Pyroprocess is one of the best candidates to satisfy these purposes.

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A Study on the Material Circulation System of Ecovillage - Focused on the Cristalwaters Ecovillage in Australia - (생태마을의 물질순환체계에 관한 연구 - 호주 크리스탈워터스 생태마을을 중심으로 -)

  • Choi, Young-Ho;Shim, Woo-Gab
    • KIEAE Journal
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    • v.4 no.2
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    • pp.49-56
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    • 2004
  • This study intends to propose the fundamentals of 'Ecovillage' design by researching into the cycle system of material of 'Crystalwaters' which is having been in charge of a leading role of GEN since 1996 (GEN was formed in 1996) as Ecovillage in Australia. First, to secure the water resources, we can store up rain and the water of valley, and dam. Second, we are able to use the natural filter apparatus, do tree-planting of roof to gain better quality of water. Third, it is to save the energy as supplying water. For it, we make the best of a gravity that is one of the cycle principle of water. Forth, to build a Dam can make a site of scenic beauty, do the role of recreation place and provide against emergencies (a fire, drought) as well as make a mild climate. Fifth, it can reduce the environment load because of sewage and garbage as making it compost. This is possible by treating biologically using composting apparatus of the dry or wet process. Sixth, it is to reduce the environmental pollution as to discharge seperating a recycable waste, an organic matter being able to make it compost. Finally, first of all, environmentally friendly inhabitant consciousness from lifestyle and production style plays an importent part for water cycle and the ecological cycle of waste and sewage.

On the Characteristics of Probability and Periodicity for the Daily Precipitaty Occureonce in Korea (우리나라 일별 강수발생의 확률과 주기성의 특성)

  • Moon, Sung-Euii;Kim, Baek-Jo;Ha, Chang-Hwan
    • Journal of Environmental Science International
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    • v.6 no.2
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    • pp.95-106
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    • 1997
  • The characteristics on the transtion probabilities and periodicity for the daily precipitation occurrence in Korean peninsula are investigated by applying the Markov chain properties to daily precipitation occurrence. In order to examine the responses of Markov Chain properties to the applied period and their magnitudes, three cases (Case A: 1956~ 1985 at 14 stations, Case B: 1965~ 1994 at 14 stations, and Case C: 1985~ 1994 at 63 stations) are considered In this study. The transition probabilities from wet day to wet day for all cases are about 0.50 and in summer, especially July, are higher. In addition, considering them in each station we can find that they are the highest at Ullung-do and lowest at Inchon for all cases. The annual equilibrium probabilities of a wet day appear 0.31 In Case A, 0.30 Case B, and 0. 29 Case C, respectively. This may explain that as the data-period used becomes shorter, the higher the equilibrium probability is. The seasonal distributions of equilibrium probabilities are appeared the lowest(0.23~0.28) in winter and the highest(more than 0.39) in spring and monthly in .truly and in October, repectively. The annual mean wet duration for all cases is 2.04 days in Case A, 1.99 Case B, and 1.89 Case C, repectively. The weather cycle obtained from the annual mean wet and dry duration is 6.54~6.59 days, which are closely associated with the movement of synoptic systems. And the statistical tests show that the transitions of daily precipitation occurrence for all cases may have two-state first Markov chain property, being the stationarity in time and heterogeneity in space.

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Shift in Weed Occurrence Accompanied Type of Direct - seeded Rice Fields (벼 직파재배(直播栽培) 유형별(類型別) 잡초발생(雜草發生)의 변화(變化))

  • Choi, C.D.;Won, J.G.;Lee, W.H.;Choi, B.S.
    • Korean Journal of Weed Science
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    • v.17 no.2
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    • pp.139-146
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    • 1997
  • The experiment was conducted at Gyeongbuk Provincial Rural Development Administration in 1996 to obtain basic information on weed ecology and effective weed control in direct-seeded rice fields under different seeding types and seeding times. A large number of upland weeds such as Echinochloa crus-galli, Digitaria sanguinalis, Capsella bursa-pastoris and Stetaria viridis etc occurred at early growth stage, while Eleocharis kuroguwai, Aneilema keisak and Cyperus serotinus dominated at late stage in dry seeded rice field. In wet seeded rice field, the dominance of E. crus-galli was lower and the occurrence of M. vaginalis and A. keisak were higher than in dry seeded field. Amount of weed occurrence in dry seeded field was 1.8 to 2.4 times greater than in wet seeded field and it increased with delaying seeding time. Increasing rate of weed occurrence through whole life cycle was the highest at 20 days after seeding (DAS) to 40 DAS, regardless of seeding types and seeding times. Simpson index in wet seeded field was higher than in dry seeded field and it gradually increased as growing of dominant species. For F-value test, it was recognized as statistical significant in seeding types, seeding times and interaction of two factors.

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Effect of Change in Wet/Dry Time of PEMFC Membrane Durability Test Protocol Using Oxygen as Cathode Gas (Cathode 산소 공급조건에서 고분자막 내구평가 프로토콜의 가습/건조 시간 변화의 영향)

  • Lim, Daehyeon;Oh, Sohyeong;Jung, Sunggi;Jeong, Jihong;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.16-20
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    • 2021
  • Since the durability evaluation for improving the durability of PEMFC polymer membranes is very important for the development of PEMFC, research and development of the polymer membrane durability evaluation protocol (AST) continues. Recently, DOE's polymer membrane chemical/mechanical durability evaluation AST was developed and applied to Nafion XL for review. In order to shorten the evaluation time, oxygen was used as a cathode gas instead of air, and it was finished in 144 hours. Since DOE AST has a large number of voltage changes with 45 seconds of humidification and 30 seconds of drying, the degradation of the electrode has more influence on the MEA durability. Therefore, one cycle time was lengthened with 60sec of wet/300sec of dry, and the drying time was made longer than the humidification time to further deteriorate the polymer membrane, and it was finished in 240 hours. It was confirmed that the DOE AST for evaluation of the durability of the polymer membrane was accompanied by electrode degradation.

The Silver Cycle and Fluxes in the Ocean

  • Ju, Se-Jong
    • Journal of the korean society of oceanography
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    • v.32 no.3
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    • pp.156-161
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    • 1997
  • The biogeochemical cycle of silver has rarely been reviewed, even though the silver ion (Ag$^{\times}$) is extremly toxic to some organisms. Its concentration is still rising sharply because of increased anthropogenic activity, specifically the discharge from the film industry (mainly, silver thiosulfate: Ag (S$_2$O$_3$)${^3-}_2$). Recently, a number of researchers have quantified the major fluxes and reservoirs of silver in the open ocean, bays, and estuaries. A review of the available information for Ag cycling in the open ocean shows that the riverine input (from human activity and weathering processes: 7${\times}$10$^6$ kg/yr and 5${\times}$10$^6$ kg/yr, respectively) is the dominant source of Ag to estuarine and coastal regions. Most of the silver (90% of riverine input silver) is removed in coastal sediments by the physical-chemical character of silver due to its high partitioning with particulate matter. On the other hand, in the open ocean the atmospheric input (wet and dry deposition: 1.48${\times}$10$^6$ kg/yr and 1.94${\times}$ 10$^5$ kg/yr, respectively) becomes more important as a source of silver than riverine input. The residence time of silver calculated from available data is 1250 yrs in the deep ocean below 500 m, but only 3 yrs in the surface ocean.

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A study on the engineering optimization for the commercial scale coal gasification plant (상용급 석탄가스화플랜트 최적설계에 관한 연구)

  • Kim, Byeong-Hyeon;Min, Jong-Sun;Kim, Jae-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.131.1-131.1
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    • 2010
  • This study was conducted for engineering optimization for the gasification process which is the key factor for success of Taean IGCC gasification plant which has been driven forward under the government support in order to expand to supply new and renewable energy and diminish the burden of the responsibility for the reduction of the green house gas emission. The gasification process consists of coal milling and drying, pressurization and feeding, gasification, quenching and HP syngas cooling, slag removal system, dry flyash removal system, wet scrubbing system, and primary water treatment system. The configuration optimization is essential for the high efficiency and the cost saving. For this purpose, it was designed to have syngas cooler to recover the sensible heat as much as possible from the hot syngas produced from the gasifier which is the dry-feeding and entrained bed slagging type and also applied with the oxygen combustion and the first stage cylindrical upward gas flow. The pressure condition inside of the gasifier is around 40~45Mpg and the temperature condition is up to $1500{\sim}1700^{\circ}C$. It was designed for about 70% out of fly ash to be drained out throughout the quenching water in the bottom part of the gasifier as a type of molten slag flowing down on the membrane wall and finally become a byproduct over the slag removal system. The flyash removal system to capture solid particulates is applied with HPHT ceramic candle filter to stand up against the high pressure and temperature. When it comes to the residual tiny particles after the flyash removal system, wet scurbbing system is applied to finally clean up the solids. The washed-up syngas through the wet scrubber will keep around $130{\sim}135^{\circ}C$, 40~42Mpg and 250 ppmv of hydrochloric acid(HCl) and hydrofluoric acid(HF) at maximum and it is turned over to the gas treatment system for removing toxic gases out of the syngas to comply with the conditions requested from the gas turbine. The result of this study will be utilized to the detailed engineering, procurement and manufacturing of equipments, and construction for the Taean IGCC plant and furthermore it is the baseline technology applicable for the poly-generation such as coal gasification(SNG) and liquefaction(CTL) to reinforce national energy security and create new business models.

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