• 제목/요약/키워드: wet strength agent

검색결과 46건 처리시간 0.028초

MDPPA/HMM처리 면직물의 고착방법에 따른 방염성과 물성의 변화 (Effect of Fixation Methods on the Flame Retardant and Performance Properties of MDPPA/HMM treated Cotton)

  • 지주원;오경화
    • 한국의류학회지
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    • 제24권1호
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    • pp.15-23
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    • 2000
  • Effect of fixation methods on the flame retardant(FR) and performance properties of MDPPA/HMM treated cotton fabrics were studied. Combination of three different fixation methods - premercerization, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of cotton with MDPPA/HMM. As a result, an increase in internal volume of cotton fiber by pre-mercerization and addition of swelling agent, and wet fixation increased %add-on of FR agent improving FR efficiency and wash fastness. Tensile strength of MDPPA/HMM treated cotton fabrics by wet fixation and swelling agent were slightly decreased, but that of premercerized cotton was improved. Wet fixated fabric showed lower bending rigidity and better compressional properties which improved fabric hand. Retention of swelling ability of cotton treated with MDPPA/HMM improved moisture absorption properties.

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농산물 저온유통용 내수 골판지 상자의 제조 (제1보) -섬유의 종류, 습윤지력증강제 및 방습제 첨가에 따른 골판지 원지의 물리적 특성 - (Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(I) - Effects of Fiber Types, Wet Strength Agents and a Moisture-Proof Chemical on the Physical Properties of Base Papers for Corrugated Board Boxes -)

  • 조중연;민춘기;신준섭
    • 펄프종이기술
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    • 제35권2호
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    • pp.26-32
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    • 2003
  • For the purpose of manufacturing water-resistant corrugated board boxes for agricultural products in the cold chain system, the effects of fiber types, wet strength agents and a moisture-proof chemical on the properties of the base papers were investigated first. PAE(polyamide amine epichlorohydrin) showed better performance than MF(melamine formalde-hyde) over broad stock pH ranges, which was prefered as wet strength agent for the paper grade. When short fibers(AOCC, KOCC) were mixed with long fiber(UKP) in certain ratios, some physical properties of the paper made with mixed fibers were similar to those of the paper made with UKP only. Paper containing AOCC showed the biggest increase in water resistance when PAE was added to the stock. Synergistic effects in moisture-proof and some mechanical properties of paper were appeared when PAR was added internally, together with the coating of a moisture proof chemical on the sheets.

습윤 지력증강제로서 GPAM Emulsion의 특성 (Properties of GPAM Emulsion for a Wet Strength Agent)

  • 김봉용;손동진;김학상
    • 펄프종이기술
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    • 제39권3호
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    • pp.36-40
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    • 2007
  • It has been problematic to repulp the dry broke treated with permanent wet strength agents like PAE, UF and MF. Solution type GPAM has the benefit of easy repulping but it has problems of cocross-linking and tends to gel. Therefore, the product concentration must be lower than 10% to reduce the gel generation problem. We developed emulsion type GPAM by an inverse emulsion technology to resolve both the repulping problem with permanent wet strength agents and the stability problem of GPAM solution products.

폐목질 자원을 이용한 옥상녹화용 식생기반재의 물리 및 화학적 특성에 관한 연구 (A Study on Physical and Chemical Properties of Vegetation Foundation for Rooftop Greening Using Wood Waste)

  • 김대영;김미미
    • Journal of the Korean Wood Science and Technology
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    • 제36권1호
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    • pp.79-87
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    • 2008
  • 경제가 성장함에 따라 도시 곳곳에 인공구조물이 건설되면서 녹지공간이 줄어들고 있다. 녹지공간의 축소는 도시의 열섬현상, 지구온난화 등을 가중시키고 삶의 질을 저하시키는 등의 문제를 가져왔다. 최근 이러한 문제를 해결하기 위해 건물의 옥상과 같이 버려진 공간을 이용한 옥상녹화에 관한 연구가 많이 이루어지고 있다. 옥상녹화 시 가장 중요한 문제로 대두되는 것은 건물에 미치는 토양의 하중으로 건물에 부하되는 하중을 줄이기 위해 경량성 녹화소재가 필요하게 되었다. 본 연구에서는 경량성 소재인 폐목재칩과 폐지 슬러리를 이용하여 녹화용 식생기반재를 제작하였다. 폐목재칩과 폐지 슬러리의 사용은 자원을 재활용한다는 의미에서도 의의를 가진다. 폐목재칩과 폐지 슬러리를 60 : 40으로 혼합하고 습윤지력증강제의 처리를 달리하였고, 보수력을 위해 표면사이즈제를 처리하여 각 처리 조건에 따라 물리적 특성과 화학적 특성을 평가하였다. 실험결과 15%의 습윤지력증강제를 첨가한 식생기반재가 습윤 시 최대의 강도를 보였고, 표면사이즈제를 도포하지 않은 식생기반재에서는 도포한 것에 비해 높은 수분증발량을 보여 표면사이즈제가 보수력을 높이는데 효과적임을 알 수 있었다. 흡수 시 두께변화는 1 mm 이하로 그 변화가 적어 치수안정성이 우수한 소재임을 알 수 있었다. 식생기반재의 pH는 7.6~8.25로 중성에서 약 알카리성으로 나타났다.

콘크리트 표면처리 방법이 콘크리트 표면 금속용사 피막의 부착강도에 미치는 영향에 관한 실험적 연구 (An Experimental Study on the Effect of Concrete Surface Treatment Methods on the Bond Strength of Metal Spray Coating)

  • 박진호;김상열;이한승
    • 대한건축학회논문집:구조계
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    • 제36권1호
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    • pp.147-154
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    • 2020
  • The exterior finishing of reinforced concrete buildings is one of the important factors to prevent durability and prevent natural environment or disaster such as temperature, snow, wind, rain from the outside as well as external design of buildings. Finishing methods can be divided into wet and dry methods. The wet method using paint is relatively easy to construct, but it requires repair and reinforcement every 1 to 5 years and requires a lot of LCC for maintenance. Finishing method using panel has good durability, but it is difficult to install and expensive. Therefore, in this paper, we evaluate the bond strength for the application of the metal spray method in order to overcome the problems of existing methods. Experimental results show that the sandblast + surface roughness agent(S-R(Y)) has a roughness of 41.16 ㎛ and the bond strength is about 3.19 MPa, which is the highest bond strength. In addition, the grinding + surface roughness agent(G-R(Y)) application showed roughness of about 36.59 ㎛ and secured the bond strength performance of 2.94 MPa.

건조수축 해석을 통한 종이의 벌크 및 강직성 향상 (Improvement of Paper Bulk and Stiffness by Using Drying Shrinkage Analysis)

  • 이진호;박종문
    • 펄프종이기술
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    • 제43권4호
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    • pp.49-58
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    • 2011
  • The maximum drying shrinkage velocity was proposed to verify bulk and stiffness improvement mechanism during drying according to papermaking parameters. It was based on the wet-web shrinkage behavior without the restraint of wet-web during drying, so intact drying impact could be measured. Bulking agent reduced the drying shrinkage and the maximum drying shrinkage velocity, so paper bulk increased and paper strength decreased. When adding cationic starch to stock with the bulking agent for strengthening, the bulk was increased further with additional decreasing of the drying shrinkage and the maximum drying shrinkage velocity. Paper strength also increased except tensile stiffness index with decreasing the drying shrinkage and the maximum drying shrinkage velocity. When using additional strength additives for strengthening of fiber interfaces extended by bulking agent and cationic starch, amphoteric strength additive increased paper stiffness without loss of paper bulk. It was considered that the added amphoteric strength additives were cross-linked to the stretched cationic starch and this cross-linking increased elasticity of fiber-polymer-fiber interfaces without changing the drying behavior. Paper bulk could be increased with decreasing the maximum drying shrinkage velocity. The drying shrinkage of paper also could be controlled by fiber-to-fiber bonding interfaces by the bulking agent. In this case, paper strength including stiffness was decreased by reducing fiber-to-fiber bonding but it could be improved by strengthening fiber-to-fiber interfaces with polymer complex without loss of bulk.

재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제2보) - 개질 PET의 내수특성 평가 - (Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephthalate and its Sizing Efficiency (Part 2) - Sizing efficiency of modified PET -)

  • 박재석;김형진
    • 펄프종이기술
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    • 제42권2호
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    • pp.95-101
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    • 2010
  • For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

Cure Characteristics, Mechanical Properties and Abrasion Resistance of Silica Filled Natural Rubber Vulcanizate

  • Lee, Hae Gil;Park, Chan Young
    • Elastomers and Composites
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    • 제50권3호
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    • pp.159-166
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    • 2015
  • Silica which is used for reinforcing filler in tire industry is widely known as eco-friendly material exerting $CO_2$ reduction effect through decrease of rolling resistance and improvement of wet grip. Generally silica is classified as a highly polar filler because it contains a large number of silanol (Si-OH) group on its surface. And also silica gives a lower reinforcing effect than carbon black due to its poorer rubber-filler interaction. Therefore silica is treated with silane coupling agent or activator, then following the conventional rubber blend method, vulcanized sheets were prepared using a hot press, and cure characteristics, mechanical properties and abrasion resistance of the test specimens were investigated. It was found that with an increase in the silane coupling agent content the tensile strength, 300% modulus and abrasion resistance increased while Mooney viscosity decreased and crosslink density slightly increased with an increase of activator.

급속경화에 의한 콘크리트 강도의 조기 판정에 관한 실험적 연구 (An Experimental Study on the Early Prediction of Concrete Strength by Accelerating Agent)

  • 김창교;최창식;이리형
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1989년도 가을 학술발표회 논문집
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    • pp.9-13
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    • 1989
  • The purpose of this paper is to propose a method predetermining the 28-days strength of concrete. In this paper, it was predicted by regression analysis of the relation between 7-days and 28-days strength of fresh concrete and the strength of concrete early cured at $70^{\circ}C$ for rour hours after wet screening and addition of accelerating agent. It is concluded that the formula predeterming the 28-days strength of concrete using 25M/M rubbles from Sam-Cheok and sands from Yon-Gok, by the strength of concrete early cured for 4 hours is Y=-11.45 + 3.686X, where the coefficient of determination of regression-expression is r2=0.938, S=17.94(kg/$\textrm{cm}^2$).

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Silane Coupling Agent 첨가에 의한 MDF Cement Composite의 수분안정성 연구 (The Study of Water Stability of MDF Cement Composite by Addition of Silane Coupling Agent)

  • 노준석;김진태;박춘근;오복진;최상홀
    • 한국세라믹학회지
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    • 제35권5호
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    • pp.421-428
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    • 1998
  • 순수 HAC/PVA 계 및 epoxy 수지와 urethane이 첨가된 HAC/PVA 계 MDF 시멘트 복합재료에 서로 다른 관능기를 갖는 3종류의 silane coupling agent를 첨가하여 강도 및 수분안정성에 대한 영향을 살펴보고 기공율 분석을 통해 미세구조와 강도의 관계를 살펴보았다. Silane의 관능기에 따라 각각의 MDF 시멘트 복합재료의 강도 및 수분안정성 향상에 대한 효과가 다른 것을 알 수 있었다. 순수 PVA 메트릭스의 경우에 대해서는 vinyl 기를 갖는 silane이 효과적인 영향을 나타내었으며 epoxy수지가 첨가된 MDF 시멘트에 대해서는 epoxy-methoxy 기를 갖는 silane이, 그리고 urethane이 첨가된 MDF 시멘트에 대해서는 diamine 기의 silane이 효과적이었다. Silane의 첨가량에 따라서는 urethane이 첨가된 MDF 시멘트 복합재료의 경우, diamine 기의 silane이 많이 첨가될수록 수분안정성이 향상되었으며 특히 2wt%의 silane을 첨가하고 wqrm press를 이용하여 성형하였을 때 건조 강도는 약 20% 향상되었으며 습윤강도는 40~70%까지 크게 향상되었다. 이는 기공율과 밀접한 관계가 있음을 알 수 있었다. Epoxy 수지가 첨가된 MDF 시멘트의 경우에서도 2wt%의 silane 첨가까지는 그 첨갈향이 많아질수록 강도가 향상되는 것을 알 수 있었지만 과량의 silane(4wt%)이 첨가될 경우에서는 오히려 특성저하가 나타났다.

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